• 한국화재소방학회논문지
• /
• 제27권5호
• /
• pp.70-74
• /
• 2013

인화점은 액체 용액의 폭발과 화재의 위험성을 특징짓는 가장 중요한 물성치 중 하나이다. 액체 혼합물의 최대인화점은 용액을 구성하는 개별 성분들의 인화점보다 높은 것을 의미한다. 본 연구에서는 2-pentanol+acetic acid 계의 인화점을 Seta flash 밀폐식 장치를 통해 측정하였다. 이 계는 최대인화점 현상을 나타내었다. 또한 인화점은 Raoult의 법칙을 이용하여 예측하였고, van Laar 식과 Wilson 식을 활용한 최적화 기법에 의해서도 예측하였다. 최적화 기법에 의한 예측 방법이 Rauolt의 법칙에 의한 예측 방법 보다 측정치를 잘 모사하였다.

• Advances in materials Research
• /
• 제9권2호
• /
• pp.115-131
• /
• 2020

Limit elastic speed analysis of Al/SiC-based functionally graded annular disk of uniform thickness has been carried out for two cases, namely: metal-rich and ceramic rich. In the present study, the unknown field variable for radial displacement is solved using variational method wherein the solution was obtained by Galerkin's error minimization principle. One of the objectives was to identify the variation of induced stress in a functionally graded disk of uniform thickness at limit elastic speed using modified rule of mixture by comparing the induced von-Mises stress with the yield stress along the disk radius, thereby locating the yield initiation. Furthermore, limit elastic speed has been reported for a combination of varying grading index (n) and aspect ratios (a/b).Results indicate, limit elastic speed increases with an increase in grading indices. In case of an increase in aspect ratio, limit elastic speed increases up to a critical value beyond which it recedes. Also, the objective was to look at the variation of yield stress corresponding to volume fraction variation within the disk which later helps in material tailoring. The study reveals the qualitative variation of yield stress for FG disk with volume fraction, resulting in the possibility of material tailoring from the processing standpoint, in practice.

• 한국수소및신에너지학회논문집
• /
• 제31권1호
• /
• pp.105-111
• /
• 2020

The organic Rankine cycle (ORC) and the Kalina cycle system (KCS) are being considered as the most feasible and promising ways to recover the low-grade finite heat sources. This paper presents a comparative exergetical performance analysis for ORC and Kalina cycle using ammonia-water mixture as the working fluid for the recovery of low-grade heat. Effects of the system parameters such as working fluid selection, turbine inlet pressure, and mass fraction of ammonia on the exergetical performance are parametrically investigated. KCS gives lower lower exergy destruction ratio at evaporator and higher second-law efficiency than ORC. The maximum exergy efficiency of ORC is higher than KCS.

• Bulletin of the Korean Chemical Society
• /
• 제24권3호
• /
• pp.345-349
• /
• 2003

The quantity, process and kinetics of di-(2-ethylhexyl)phthalate (DEHP) migration in the 30/70 and 40/60 poly(vinylchloride) (PVC)/DEHP blends were investigated using gas chromatograph. A thin and flexible PVC sheet was soaked in surrounding medium (SM) of water/ethanol mixture and acetonitrile with constant stirring to release DEHP. By observed concentration of DEHP in the SM, it is found that acetonitrile is more intense in DEHP migration than water/ethanol mixture. In addition the amount of extracted DEHP is proportional to the leaching temperature and added ratio of DEHP. The behavior of DEHP migration from flexible PVC sheets was described by the Ficks's law with $2.72-10.1\;{times}\;10^{-10}$ cm²/s of the diffusion coefficients.

• 한국지반공학회논문집
• /
• 제22권11호
• /
• pp.5-11
• /
• 2006

본 연구는 산업폐기물인 Bottom Ash의 재활용을 위한 목적으로 보통포틀랜드 시멘트와 Bottom Ash의 적정 혼합비를 산정 한 후 황토, 풍화토, Bentonite를 일정량 혼합하여 강도와 내구성에 대해 평가했고, 중금속 용출시험을 통해 환경적 영향을 검토했다. 그 결과 시멘트:Bottom Ash의 적정혼합비는 6:4이고, 황토, 풍화토, Bentonite는 6% 혼합하였을 경우 강도와 내구성에 가장 효과적 이였다. 또한 중금속 용출시험결과 지정 폐기물 기준에 훨씬 못 미치는 것으로 나타났다.

• 한국화재소방학회논문지
• /
• 제29권2호
• /
• pp.39-43
• /
• 2015

인화점은 액체 혼합물의 화재와 폭발의 위험성을 특징짓는 주된 성질이다. 인화점은 가연성 액체에 불꽃이 가해졌을 때 점화가 발생하는 가장 낮은 온도로 정의된다. Seta flash 밀폐식 장치를 이용하여 이성분계 수용성 혼합물인 water-methanol계와 water-ethanol계의 인화점을 측정하였다. Wilson 식과 UNIQUAC 식과 같은 활동도 모델식을 활용한 방법을 이용하여 인화점을 계산하였다. 이 계산치와 라울의 법칙에 의한 계산치를 비교하였다. 그 결과, 활동도 계수 모델식에 의한 계산치가 라울의 법칙에 의한 계산치 보다 측정값에 보다 근접하였다.

• 한국세라믹학회지
• /
• 제28권8호
• /
• pp.626-634
• /
• 1991

The specimens for the corrosion test were made by hot-pressing of SiC power with 2 wt% Nl2O3 and 10wt% Al2O3 additions at 200$0^{\circ}C$ and 205$0^{\circ}C$. The specimens were corroded in 37 mole% NaCl and 63 mole% Na2SO4 salt mixture at 100$0^{\circ}C$ up to 60 min. SiO2 layer was formed on SiC and then this oxide layer was dissolved by Na2O ion in the salt mixture. The rate of corrosion of the specimen containing 10 wt% Al2O3 was slower than that of the specimen containing 2 wt% Al2O3. This is due to the presence of continuous grain boundary phase in the specimen containing 10 wt% Al2O3. The oxidation of SiC produced gas bubbles at the SiC-SiO2 interface. The rate of corrosion follows a linear rate law up to 50 min. and then was accelerated. This acceleration is due to the disruption oxide layer by the gas evolution at SiC-SiO2 interface. Pitting corrosion has found at open pores and grain boundaries.

• Nuclear Engineering and Technology
• /
• 제42권2호
• /
• pp.183-192
• /
• 2010

An electrochemical reduction of a mixture of metal oxides was conducted in a LiCl molten salt containing 3 wt% $Li_2O$ at $650^{\circ}C$. The oxide reduction was carried out by applying a current to an electrolysis cell, and the $Li_2O$ concentration was analyzed during each run. The concentration of $Li_2O$ in the electrolyte bulk phase gradually decreases according to Faraday's law due to a slow diffusion of the $O^{2-}$ ions. A hindrance effect of the unreduced metal oxides was observed for the reduction of the uranium oxide. Cs, Sr, and Ba of high heat-load fission products were diffused into and accumulated in the salt phase as predicted with thermodynamic consideration.

• 천문학회지
• /
• 제25권2호
• /
• pp.111-128
• /
• 1992

Infrared emissions from spherical dust, clouds are calculated using quasi-diffusion method. We have employed graphite-silicate mixture with power-law size distribution for the dust model. The grains are assumed to be heated and cooled by radiative processes only. The primary heating source is diffuse interstellar radiation field. hut the cases with an embedded source are also considered. Since graphite grains have higher temperature than silicate grains, the observed IR emission is mainly due to graphite grains, unless the fraction of graphite grains is negligibly small. The color temperature of Bok globules obtained from IRAS 60 and $100{\mu}m$ data are found to be consistent with the dust cloud with graphite-silicate mixture exposed to average interstellar radiation field. The color temperature is sensitive to the external radiation field, but rather insensitive to the size distribution of the grains. We found that the density distribution can be recovered outside the beam size using the inversion technique that assumes negligible optical depth. However, the information within the beam size is lost for if beam convolved intensity distributions are used in deriving density profile.

• 대한화학회지
• /
• 제9권4호
• /
• pp.215-221
• /
• 1965

벤젠-염화에틸렌 이성분 용액에다 significant liquid structure theory를 확장 적용시켰다. 라울의 법칙이 만족되는 온도 범위 안에서 적용되는 분배함수를 구하였다. 이 분배함수로 부터 계의 전체압, 부분압, 몰부피 그리고 혼합엔트로피와 같은 열역학적 양을 $293.15^{\circ},\;323.14{\circ}$ 및 $357.15^{\circ}K$에서 계산하였다. 이와 같이 구한 이론적인 계산치들은 실측치와 대단히 잘 맞었다.