• Title/Summary/Keyword: Lattice defect

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Design Sensitivity in Quasi-One-Dimensional Silicon-Based Photonic Crystalline Waveguides

  • Kinoshita, Takeshi;Shimizu, Akira;Iida, Yukio;Omura, Yasuhisa
    • JSTS:Journal of Semiconductor Technology and Science
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    • v.3 no.1
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    • pp.55-61
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    • 2003
  • This paper describes how the optical properties of a quasi-one-dimensional photonic crystalline waveguide having a periodic air cavity are influenced by various structural parameters; the electromagnetic fields are simulated using the finite-difference time-domain method. The simulations considered four design parameters: cavity size, defect size, lattice constant, and number of cavity. The parameter sensitivity of the photonic bandgap property of the waveguide having air cavities is examined. A couple of significant design guidelines are obtained. We show that the quasi-one-dimensional photonic crystalline waveguide has significant unrealized potential.

Analysis of the effect on the whisker growth as grain size of plating and base metal (Plating 및 Base metal의 Grain size에 따른 Whisker 성장 영향 분석)

  • Kim, Su-Jin;Chang, Mi-Soon;Kwack, Kae-Dal
    • Proceedings of the KSME Conference
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    • 2008.11a
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    • pp.1337-1342
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    • 2008
  • The whisker grows at the plating of a lead frame so that it causes the serious problem like the short. To prove this case, many people have studied the cause and influence of the tin whisker growth. This study explains the grain size affects the growth of the whisker in the lead frame. By these studies about the whisker, the whisker growth is discovered by stresses generated by the intermetallic compound and CTE mismatch in both plating and base metal. The stresses or lattice defect generated in the plating process changes grain structure of plating. Consequently, these various stresses are stabilized by forming unspecified whiskers through lots of grain boundaries. Because the grain boundary is the path of the whisker growth, the smaller grain size exists, the more whiskers grow.

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Solid Solution and Defect Structure of LiCrO2 in the Pseudo-binary Systems : Li2Cr2O4-MgAl2O4 (의사이성분계, Li2Cr2O4-MgCr2O4와 Li2Cr2O4-MgAl2O4에서의 LiCrO2 고용체 형성과 결합구조)

  • 정영서;오근호;김호기
    • Journal of the Korean Ceramic Society
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    • v.25 no.1
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    • pp.35-41
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    • 1988
  • In the system of Li2O-MgO-Al2O3-Cr2O3, the crystalline solid solution of LiCrO2 along the pseudo-binary join between rocksalt structure(LiCrO2) and spinel structure(MgCr2O4 or MgAl2O4) have been investigated by x-ray diffraction techniques. In this study, order-disorder phase transition of LiCrO2 was observed and the unit cell of the disordered LiCrO2 structure has been established. It has been found that LiCrO2 makes a solid solution over a wide range with MgAl2O4, while not with MgCr2O4. This difference was explained as being due to the ability of oxygen lattice distortion which depended on the relative sizes and chemical bonding characteristics of the substituted ions.

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Growth and Characteristic Infrared Raman Spectra of Potassium Lithium Niobate Single Crystals

  • Youbao Wan;Yoo, Sang-Im
    • Proceedings of the Korea Crystallographic Association Conference
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    • 2002.11a
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    • pp.15-15
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    • 2002
  • Homogeneous and crack-free potassium lithium niobate (K₃Li/sub 2-x/Nb/sub 5+x/O/sub 15/, 0<x<0.5, KLN) single crystals were successfully grown by the Czochralski technique. The KLN single crystals of several different compositions were employed for the investigation of the lattice vibration spectra using infrared Raman spectroscopy. The characteristic Raman spectra of the [NbO/sub 6/]/sup 7-/ octahedral ions were strikingly influenced by the Li ion content. The symmetric stretch vibrational modes V₁, V₂ are broadened, and the symmetric bend vibration mode V/sub 5/ is broadened and even split into three peaks with increasing the Li content, supporting that the bend vibration modes of the [NbO/sub 6/]/sup 7-/ octahedrons are obviously perturbed by Li ions in the C site. Enhanced Raman peak intensities after the post annealing at 900℃ and for 24 h evidenced that a residual stress in as-grown crystals was negligible and only a defect concentration might be reduced.

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Synthesis of Semiconducting $KTaO_3$ Thin films (KTaO3 Thin Film의 Semiconducting 합성)

  • Koo, Ja-Yl;Ohm, Woo-Yong;Ahn, Chang-Hwan;Bae, Hyung-Jin
    • Proceedings of the IEEK Conference
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    • 2006.06a
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    • pp.981-982
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    • 2006
  • In this study, the synthesis and semiconducting properties of cation and defect-doped KTaO3 film is reported. KTaO3is an important material for optoelectronic and tunable microwave applications. It is an incipient ferroelectric with a cubic structure that becomes ferroelectric when doped with Nb. the films were grown on (001) MgO single crystal substrates using pulsed-laser deposition. Semiconducting behavior is achieved by inducing oxygen vacancies in the KTaO3 lattice via growth in a hydrogen atmosphere. The resistivity of semiconducting KTaO3:Ca films was as low as 10cm, and n-type semiconducting behavior was indicated. Hall mobility and carrier concentration were 0.27 cm2/Vs and 3.21018cm-3.

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Characteristics of Molybdenum Nitride Diffusion Barrier for Copper Metallization (Cu 금속배선을 위한 Molybdenum Nitride 확산 방지막 특성)

  • Lee, Jeong-Yeop;Park, Jong-Wan
    • Korean Journal of Materials Research
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    • v.6 no.6
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    • pp.626-631
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    • 1996
  • Reactive dc magnetron sputtering 법을 이용하여 증착한 molybdenum mitride 박막의 Cu 확산 방지막 특성을 조사하였다. Cu 확산 방지막으로서 molybdenum nitride 박막의 열적안정성을 관찰하기 위하여 molybdenum nitride 박막 위에 Cu를 evaporation 법으로 증착하고 진공 열처리하였다. Cu/r-Mo2N/si 구조는 $600^{\circ}C$, 30분간 열처리 시까지 안정하였다. 확산 방지막의 파괴는 $650^{\circ}C$, 30분간 열처리 시부터 격자 확산(lattice diffusion)이나 입계(grain boundary)과 결함(defect)을 통한 확산에 의해 나타나기 시작하였고, 이 때 molybdenum silicide과 copper silicide의 형성에 기인된 것으로 생각되었다. 열처리 이후 Cu/r-Mo2N/Si 사이의 상호반응이 증가하였다. 이는 Rutherford backscattering spectrometry, Auger electron spectroscopy 그리고 Nomarski microscopy 등의 분석을 통해 조사되었다.

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Coulometric Titration Study on the Nonstoichiometry in Copper Doped Cobaltous Oxide ((${Co_{1-x}}{Cu_x}$)$_{1-\delta}$ O (전하적정법에 의한 (${Co_{1-x}}{Cu_x}$)$_{1-\delta}$ O의 산소 부정비량 측정)

  • ;Michael Schroeder;Manfred Martin
    • Journal of the Korean Ceramic Society
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    • v.37 no.8
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    • pp.799-804
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    • 2000
  • Coulometric titration experiments have been done for copper doped cobaltous oxide (Co1-xCux)1-$\delta$ O with various dopant concentrations. We present the obtained experimental data and compare our results to those of previous thermogravimetric investigation. The experimental data are fitted by theoretical calculations based on various defect models. For this modeling, we considered different types fo major defects like copper in substitutional and interstitial lattice sites as well as copper vacancy. We also introduced the copper evaporation effect during titration experiment into our consideration.

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Design Program of Deck Plate Slab System with Non-welding Truss Type Reinforced Bar (철근트러스 압접 데크플레이트 바닥 구조의 설계 프로그램)

  • Yoon, Myung-Ho;Oh, Sang-Hoon
    • Journal of The Korean Digital Architecture Interior Association
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    • v.8 no.1
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    • pp.57-64
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    • 2008
  • There are many problems in present truss-deck slab system for example welding defect, segregation, water leakage, rust and tarnish etc. These problems may be caused by spot welding thin galvanized steel plate and lattice bar. The TOX Joining Systems is to join metal sheets of different material and thickness with and without coating or painting without adding heat or a joining part. Newly developed TOX-deck slab system using non-welding joint is free from above mentioned problems. The objects of this study are suggestion of design strength of TOX joint by experimental and statistical analyses and development of window based program to design the TOX-deck slab system.

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Growth and optical properties of undoped and Co-doped CdS single crystals (CdS 및 $CdS:Co^{2+}$ 단결정의 성장과 광학적 특성)

  • Kim, N.O.;Bang, T.H.;Hyun, S.C.;Park, K.H.;Park, H.;Oh, S.K.
    • Proceedings of the KIEE Conference
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    • 2002.06a
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    • pp.94-97
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    • 2002
  • CdS and $CdS:Co^{2+}$ single crystals were grown by CTR method using iodine as transport material. The grown single crystals have defect chalcopyrite structure with direct band gap. The optical energy band gap was decreased according to add of Co-impurity. We can observed the Co-impurity optical absorption peaks assigned to the $Co^{2+}$ ion sited at the $T_d$ symmetry lattice and we consider that they were attributed to the electron transitions between energy levels of ions.

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The Studies on the Simultaneous Removals of NOx and SOx from Stationary Sources by using Perovskite type Catalysts (페로브스카이트형 촉매계를 이용한 고정원 배가스로부터의 NOx 와 SOx의 동시제거 기술에 관한 연구)

  • Lee, Byong-Yong;Choung, Suk-Jin
    • Proceedings of the KIEE Conference
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    • 1996.11a
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    • pp.475-479
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    • 1996
  • At present studies, we are going to suggest the new type of Perovskite derived catalysts which modify the defects of transition metals impregnated. Perovskite type catalyst is a typical mixed metal oxides, and there are "defect"s (from like that oxygen, cation, crystallic structure) were made by difference from composition, preparing method and so forth. And because this, its electro-magnetic character could be much changed. By using this phenomena, it could utilize the modification of adsorption/desorption characters as well as the catalytic activities in NOx reduction. Because perovskite type catalyst can exchange the metal of the each lattice site freely and it is possible to represent the peculiar.

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