• Applied Chemistry for Engineering
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• v.9 no.5
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• pp.758-762
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• 1998

In preparing void latex particles by emulsion polymerization, the weight mean particle size of which is ranged $0.3{\mu}m{\sim}1.5{\mu}m$, reaction parameters were investigated in order to elucidate their effects on the size distribution and the solid content of emulsion polymer. Experimental results showed that the weight mean particle size of hydrophillic core polymer was reduced as the concentration of sodium dodecylbenzene sulfonate (SDS) increased. The size of void polymethyl-methacrylate-polystyrene composite latex particles became larger as the concentration of styrene monomer and the sodium persulfate increased. However, the size of void latex particles was reduced as the feeding rate of acrylic acid increased. The solid content of emulsion polymer was strongly dependent on the addition of stylene monomer. By increasing the concentration of styrene monomer the solid content of emulsion polymer increased linearly.

• Journal of the Korea Concrete Institute
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• v.14 no.3
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• pp.299-306
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• 2002

The purpose of this research was to develop a rapid setting cement latex modified concrete (RSLMC) for bridge deck repairing and overlaying. The main experimental variables were latex contents, antifoamer contents and water-cement ratioes. The workability, strength development and permeability were measured as responses. The results showed that latex content increased the slump and reduced the unit water required for same workability. The air contents were measured as 8.0∼9.0％ and 2.0∼3.0％ without antifoamer and with 1.6∼3.2％ of antifoamer, respectively. This resulted in the increment of compressive strength development by 10∼20 ％. The flexural strength of RSLMC increased greatly as the latex content increased, but not in compressive strength. The compressive strength and flexural strength developed enough for opening the overlayed RSLMC to the traffic after 3 hours of RSLMC placement. The permeability of RSLMC was evaluated as negligible due to its very low charge passed. Thus, RSLMC could be used at repairing or overlaying the concrete bridge deck at fast-track job sites.

• International Journal of Highway Engineering
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• v.3 no.3 s.9
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• pp.135-146
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• 2001

This study focused on the investigation of compressive and flexural strengths development, and bond strength of latex modified concrete in order to validate the feasibility of application into concrete bridge deck overlay. Pull-out bond test was used for evaluating the bond strength of latex modified concrete to substrate. The main experimental variables were latex-cement ratio, surface preparation and moisture levels. The compressive strength of latex modified concrete decreased slightly and the flexural strength increased as the latex content increased from 5% to 20%. This might be due to the flexibility latex filled in voids and interconnections of hydrated cement and aggregates by a film of latex particles, respectively. In general, increasing the amount of latex will produce concrete with increased tensile and flexural strength and lower modulus of elasticity. Significant improvements in bond strength between new and existing concrete were achieved through the modification of the new concrete bridge deck overlay by latex polymers. The effect of surface preparation on bond of latex modified concrete to conventional concrete were significant at the conditions by sand paper and wire brush. A better bond could be achieved by rough surface rather than smooth. The saturated condition of surface is the most appropriate moisture level among the considered followed by dry condition and wet condition.

• Journal of the Korea Concrete Institute
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• v.14 no.3
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• pp.315-320
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• 2002

The effects of slag content and polymer-binder ratio on the strength properties of the polymer-modified concretes using ground granulated blast-furnace slag and a styrene-butadiene rubber (SBR) latex are examined. As a result, the compressive, tensile and flexural strengths of the SBR-modified concretes using slag increase with increasing polymer-binder ratio and slag content, and maximized at a slag content of 40 ％. In particular, the SBR-modified concretes with a slag content of 40 ％ provide approximately two times higher tensile and flexural strengths than unmodified concretes. Such high strength development is attributed to the high tensile strength of SBR polymer and the improved bond between cement hydrates and aggregates because of the addition of SBR latex.

• Journal of the Korean Applied Science and Technology
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• v.27 no.3
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• pp.240-248
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• 2010

The blending effects of surfactants on the polystyrene emulsion polymerization were studied. The blending of Triton X-100 and SDS affects to the interfacial properties of the styrene monomer and water phases, and finally, the properties of the polystyrene latex particles. As the blending ratio of SDS/Triton X-100 increases, the interfacial tension and CMC of the blended surfactants were decreased and results in a reducing the size of the latex particles. It was found that the interfacial tension was reduced when the surfactant were blended. By increasing the SDS content, the interfacial tension was reduced, and, at a certain condition, the interfacial tension was reached to an extremely low value to form micro-emulsion and the nano-sized latex particles (80~110 nm).

• Journal of the Korean Graphic Arts Communication Society
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• v.22 no.1
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• pp.19-28
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• 2004

A piece of coating color or base paper picked during printing is called coating pick. Loosely bonded materials of coating color or broken piece of fiber could be adhered to the blanket or would be mixed with ink during printing. Because the coating pick can make troubles in printing press such as piling, hickey and collecting, the coating pick of a paper has been one of the most serious problems in printing. In this paper, two influential factors to the coating pick in the printing, those are latex content and ash content of the coating color, are studied. The surface resistance of coating paper is directly proportional to the latex content, otherwise inversely proportional to the ash content. We propose a different way to evaluate the picking and used a homemade pick test device.

• Proceedings of the Korea Concrete Institute Conference
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• 2006.11a
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• pp.841-844
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• 2006

Recently, tunnels being constructed in korea with the increased construction of highways, high-speed railways and hydro structure. shotcrete and spray is one of the major processes in that construction. So general Shotcrete and spray has many problems on strength property, environmental pollution and human body noxiousness as the use of accelerater. However, In this paper using HES-LMS(High Early Strength Latex Modified Spray) without accelerater can solve problems which are mentioned above. problems that the hish early cement has can be solved by modifying material with latex. Therefore HES-LMS mortar is Classify by High performance and High ability. Analysis according to the variables such as W/C, Latex content and sand content is conducted. Studied about mechanical characteristic of material such as each parameter characteristic, and rebound characteristic is completed.

• Elastomers and Composites
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• v.33 no.3
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• pp.149-158
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• 1998

SBR latex, polyurethane latex and epoxy latex were separately mixed with polyvinyl acetate emulsion. The various physical properties were examined for the mixtures. Epoxy mixtures gave a transparent film. Both polyurethane and SBR mixtures showed opaque film with high viscosity. In SBR and polyurethane increase in hardness was dependent on the evaporation rate of water, but in epoxy it was dependent on the degrees of crosslink. Epoxy's showed excellent water-resistance. SBR showed a good flexural strength and impact strength. When vinyl acetate emulsion was mixed with less than 10% latex paper tube showed the ductile fracture, but over latex content 20%, it showed the brittle fracture.

• Polymer(Korea)
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• v.35 no.5
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• pp.451-457
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• 2011

The effect of latex particle size on rheological and electrical properties of latex-blended polystyrene (PS)/multi-walled carbon nanotube (MWCNT) nanocomposites was investigated. Mono-dispersed PS particles synthesized either by emulsifier-free emulsion polymerization or by dispersion polymerization were mixed with MWCNTs under ultrasonication, and freeze-dried to prepare the nanocomposites. As the MWCNT content increased, storage modulus, complex viscosity and electrical conductivity were substantially increased. The increase of storage modulus and complex viscosity was higher for larger PS particles. The effect of particle size on electrical properties was different depending on MWCNT content. With lower MWCNT content, the nanocomposite prepared by smaller PS particles showed higher electrical conductivity, but the opposite result was given as the content increased.

• International Journal of Highway Engineering
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• v.16 no.5
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• pp.73-82
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• 2014

PURPOSES : The purpose of this study is to determine the optimum addition rate of SBR latex through the evaluation of durability and strength of SBR latex applied soil pavement. Formerly used materials such as fly ash and cement in soil pavement had resulted in decreased durability due to micro crack by heat of hydration and shrinkage crack in winter. However, that agglutinated polymers help adhesion to aggregate increased comes up with preventing the crack opening when the number of capillary tubes of SBR latex get decreased in the hydration process of cement. Therefore, in this study, it is suggested that the evaluation of the field applicability of soil pavement be conducted through the performance lab test in terms of strength increment, adhesion improvement, and crack resistance based on SBR latex addition rate. METHODS : In order to evaluate the field applicability of soil pavement, SBR latex was added 0 to 3% by 1% increment, with fixed cement contents of 3% and 5%. The resistance of shear failure and crack of soil pavement were evaluated by performing the uniaxial compressive strength test and indirect tensile strength test at -20 and $20^{\circ}C$, respectively. RESULTSCONCLUSIONS : It was found out that from both tests, resistance of shear failure and crack were improved with increment of curing time, and especially more than 2% of SBR latex addition rate and 5% cement content gave better results.