• 한국대기환경학회:학술대회논문집
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• 한국대기환경학회 2003년도 추계학술대회 논문집
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• pp.319-320
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• 2003

대기 중에서 HOx(OH, H $O_2$) 라디칼은 중요한 산화제로, 대류권내 광화학 반응에서 핵심적인 역할을 한다 이러한 OH 라디칼의 정확한 농도를 측정하는 것은 대기의 산화능력, 기후 변화 및 대기 중의 광화학 반응을 보다 정확히 이해하기 위해 필수적이다. 그러나 OH를 비롯한 HOx 라디컬의 농도 측정은 대기 내에 존재하는 양이 절대적으로 작고 (OH: $10^{6}$molecules $cm^{-3}$, H $O_2$: $10^{8}$molecules $cm^{-3}$), 반응성이 커서 수명이 짧기 때문에 측정에 많은 어려움이 따른다. (중략)

• 기계저널
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• 제33권12호
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• pp.1031-1042
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• 1993

연소현상에 대한 이해를 증가시키기 위하여 화염을 이용한 많은 실험적 연구가 이루어져 왔다. 특히 연소 모델의 개선과 증명을 위하여는 화염에서의 성분 농도 측정이 필수적이며, 최근에 들어 측정 가능해진 래디컬성분의 측정은 연소해석분야에 많은 진전을 가져왔다. OH, H 및 O는 연료의 분해 (decomposition) 및 연소 산화물생성 이외에도 CO와 NO 같은 공해물질의 형성등 연소과정에서 매우 중요한 래디컬들이며, 특히 화염영역에서의 OH의 전파(transport)는 화염의 점화 및 안정성 (stability)에도 큰 영향을 미친다. OH래디컬은 연소과정에서 가장 중요한 성분 중 하나이며, 또한 스펙트럼이 비교적 잘 알려져 있어 레이저 유도 형광의 적용이 용이하므로 화염에서의 OH농도 측정에 LIF(laser induced fluorescence) 또는 PLIF(planar laser induced fluorescence)가 널리 사용되고 있다. 따라서 LIF 및 PLIF의 원리 및 연소분야에서의 응용을 OH농도 측정을 중심으로 소개하고자 한다.

• International Journal of Fluid Machinery and Systems
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• 제2권2호
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• pp.121-126
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• 2009

The internal flow field in a centrifugal pump working at the several flow conditions has been measured by using the particle image velocimetry (PIV) technique with the laser induced fluorescence (LIF) particles and the refractive index matched (RIM) facilities. The impeller of the centrifugal pump has an outlet diameter in 100mm, and consists of six two-dimensional curvature backward swept blades of constant thickness. Measured results give reliable flow patterns in the pump. It is obvious that application of LIF particle and RIM are the key methods to obtain the right PIV measured results in pump internal flow.

• Bulletin of the Korean Chemical Society
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• 제28권9호
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• pp.1485-1488
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• 2007

Photodissociation dynamics of cyanamide (NH2CN) at 212 nm has been investigated by measuring rotationally resolved laser induced fluorescence spectra of CN fragments exclusively produced in the ground electronic state. From the spectra, rotational population distributions of CN as well as translational energy releases in the products were obtained. The measured average rotational energies of CN were 12.4 ± 0.5 and 11.6 ± 0.5 kJ/ mol for v'' = 0 and v'' = 1, respectively and the center of mass average translational energy release among products was 41.8 ± 6.4 kJ/mol. The observed energy partitioning was well represented by statistical prior calculations, from which it was suggested that the dissociation takes place on the ground electronic surface after rapid internal conversion.

• Bulletin of the Korean Chemical Society
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• 제27권12호
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• pp.1997-2001
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• 2006

The photodissociation dynamics of formic acid (HCOOH) at 206 nm have been investigated from rotationally resolved laser induced fluorescence spectra of OH ($^2\Pi$) fragments produced exclusively in the ground state. From the spectra, the rotational energy of the fragments was measured to be $820\;{\pm}\;50\;cm^{-1}$. The translational energy released in the products, which is 87% of the total available energy of the system, was also measured from analyses of the Doppler profiles. Joining these data with quantum chemical molecular orbital calculations, we have concluded that the dissociation should take place along the S1 surface with an exit channel barrier and also that the energy partitioning is determined at the exit channel.

• Bulletin of the Korean Chemical Society
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• 제17권5호
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• pp.461-463
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• 1996

The laser-induced fluorescence excitation spectrum of 7-amino-4-(trifluoromethyl)coumarin in a supersonic jet has been recorded in the 340-352 nm region. The electronic band origin was observed at 28622.8 cm-1. Vibrational assignments for the three fundamental low-frequency modes and eight combination bands have been made for the S1 electronic excited state. The out-of-plane vibrations of this molecule have been characterized from the low-frequency assignments of the spectrum. The periodic potential energy function for the CF3 torsion, which satisfactorily fits the observed data, were also determined to be V(Φ)=95X(1-cos3Φ)-32X(1-cos6Φ) where Φ is the torsional angle. The relatively low torsional barrier of 99 cm-1 in S1 state could be explained by the small steric interactions between the functional groups attached to a bicyclic ring.

• Bulletin of the Korean Chemical Society
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• 제5권6호
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• pp.253-259
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• 1984

An analytical applicability of the fluorescence detection with an optical multichannel analyzer to organic dyes was studied in this work. Continuous acquisition of spectra was possible with the use of a microcomputer. The maximum acquisition rate of a spetrum with 70-point average was about 3 seconds. Floppy discs were used to store data for later use in processing. Laser induced fluorescence detector in High Performance Liquid Chromatography was chosen for an application. Fluorescein below $10^{-15}g$ was detected satisfactorily using this system. With the help of microcomputer, three dimensional chromatograms of time-wavelength-intensity were obtained.

• 대한전기학회:학술대회논문집
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• 대한전기학회 1995년도 하계학술대회 논문집 C
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• pp.1307-1310
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• 1995

During measurement of atomic hydrogen in a silane plasma using two-photon excited laser induced fluoresecence, laser-induced dissociation of the gas was observed. This was investigated untill conditions for the input laser fluence were determined where the effect was negligible. A measurement of the atomic hydrogen distribution was then performed within the limits of these conditions. Absolute density determinations showed atomic hydrogen densities of around $3{\times}10^{17}m^{-3}$.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2009년도 제36회 동계학술대회 초록집
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• pp.282.2-282.2
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• 2009

• 한국원자력학회:학술대회논문집
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• 한국원자력학회 1998년도 추계학술발표회요약집
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• pp.303-303
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• 1998