• Title/Summary/Keyword: Laser induced fluorescence

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Hydroxyl Radical Measurements in the Flame Using LIF (레이저유도 형광법을 이용한 화염내 OH 농도분포 계측)

  • Lee, Byeong-Jun;Gil, Yong-Seok;Jeong, Seok-Ho
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.20 no.2
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    • pp.710-719
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    • 1996
  • Laser applied combustion diagnostic techniques-laser induced fluorescence (LIF) and coherent anti-Stokes Ramann spectroscopy (CARS)-are demonstrated. The profiles of hydroxyl radical (OH) and temperature in the counterflow burner are measured and compared with the numerical results. OH radical is excited on the Q$_1$(6) line of the $A^2$$\sum^+$$\leftarrow$$X^2{\prod}$(1, 0) band transition (281.1 nm) and LIF signal is measured at the the bands of (0, 0) and (1, 1) transition (306~326 nm). Absolute OH radical is obtained by using the laser absorption technique. The quenching effects are considered. Temperature is measured using broadband CARS system. Two dimensional OH radical profile is also obtained. The profiles of OH radical and temperature are found to agree well with those of numerical calculation.

Spray Visualization Using Laser Diagnostics (레이저 계측법을 이용한 분무 가시화)

  • Yoon Youngbin;Koh Hyeonseok;Kim Dongjun;Khil Taeock
    • Journal of the Korean Society of Visualization
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    • v.3 no.2
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    • pp.3-13
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    • 2005
  • The optical patterantor provides the high resolution and quantitative information of the spray. Fuel distribution and Sauter Mean Diameter (SMD) can be measured from fluorescence and Mie-scat-tering images. To correct the attenuation of the laser beam and signal in dense spray region, the method to find the geometric mean of the signal intensities obtained from two cameras was evaluated and verified in a solid-cone spray. In high pressure environment, the increased number density of the droplets cause multiple scattering. The optical patternation technique using a laser beam instead of a laser sheet was applied to minimize the multiple scattering problem. The pattern of a coaxial spray was changed from hollow-cone to solid-cone shape, and the spray angle was reduced as the ambient pressure increased from 0.1 to 4.0 MPa.

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Nanometer-Scale Surface Analysis of Polymers Using Laser Ablation Spectroscopy (레이저 애벌레이션 분광을 이용한 고분자 표면의 나노미터 스케일 표면 분석)

  • Kim, Min-Kyu
    • Proceedings of the KIEE Conference
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    • 2001.07c
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    • pp.1334-1336
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    • 2001
  • In this study, laser ablation atomic fluorescence (LAAF) spectroscopy has been applied for a nanometer-scale surface analysis of Na-doped polymethyl methacrylate (PMMA). LAAF spectroscopy is a new sensitive element detection technique which involves atomizing of a sample by the laser ablation and detection of ablated plume by laser-induced fluorescence (LIF) spectroscopy. Using this technique in the detection of Na atoms with Na-doped PMMA, a detection limit is obtained as 36 fg for single laser shot. Further, the depth distribution in the sample is measured with a very high spatial resolution using a two-layer PMMA sample by observing the shot-by-shot LIF intensity from the Na atoms.

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Measurements of Temperature and Flow Fields with Sub-Millimeter Spatial Resolution Using Two-Color Laser Induced Fluorescence (LIF) and Micro-Particle Image Velocimetry (PIV)

  • Kim Hyun Jung
    • Journal of Mechanical Science and Technology
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    • v.19 no.2
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    • pp.716-727
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    • 2005
  • Comprehensive measurements for velocity and temperature fields have been conducted. A Micro PIV 2-color LIF system have been setup to measure the buoyancy driven fields in a 1-mm heated channel with low Grashof-Prandtl numbers [$86]. Fluorescence microscopy is combined with an MPIV system to obtain enough intensity images and clear pictures from nano-scale fluorescence particles. The spatial resolution of the Micro PIV system is $75{\mu}m\;by\;67{\mu}m$ and error due to Brownian motion is estimated $1.05\%$. Temperature measurements have achieved the $4.7\;{\mu}m$ spatial resolution with relatively large data uncertainties the present experiment. The measurement uncertainties have been decreased down to less than ${\pm}1.0^{\circ}C$ when measurement resolution is equivalent to $76\;{\mu}m$. Measured velocity and temperature fields will be compared with numerical results to examine the feasibility of development as a diagnostic technique.

The Study of Optimum Design of Y-Channel Micro-Mixer by Using LIF Conforcal Microscope (LIF Conforcal Microscope을 이용한 Y-channel 마이크로믹서의 최적설계 연구)

  • Kim, Sang-Woo;Hyun, Seok-Ho;Shin, Tae-Seok;Lee, Do-Hyung
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.33 no.5
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    • pp.311-317
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    • 2009
  • Due to extremely small device size and velocity scale, mixing in microchannel take place very slowly by way of molecular diffusion transport. Mixing enhancement becomes a central issue in microfluidics for biomedical and chemical applications. In this work, The optimization results and validation through experiment and fabrication. In this efficient micromixer design, it is essential to evaluate mixing efficiency with good precision. Mixing efficiency for Y-channel micromixer is measured by fluorescence intensity using LIF(Laser Induced Fluorescence) Confocal Microscope. The Y-channel micromixers are fabricated with polydimethylsiloxane(PDMS). Nile Blue A is injected into the micromixer as a fluorescence dye for measuring of fluorescence intensity by He/Ne laser. Throughout the experiments and computer simulation, accurate mixing efficiency evaluation process for a PDMS Y-channel micromixer is established.

Comparison of Morphology of Deposits on SiC Filaments with LIF Image in Propane/Air Laminar Diffusion Flames in an Oxidizer Deficient Environment (산화제 결핍 상태의 프로판 층류 확산화염에서 LIF 이미지와 SiC 필라멘트 부착물의 형태 비교)

  • Shim, Sung-Hoon;Yoo, Chang-Jong;Shin, Hyun-Dong
    • Journal of the Korean Society of Combustion
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    • v.7 no.4
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    • pp.1-9
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    • 2002
  • The morphology of deposits on $15-{\mu}m$ thin SiC filaments has been investigated with SEM and compared with UV-excited laser induced broadband fluorescences in co-flowing, propane laminar diffusion flames in a reduced oxidizer environment. The homogeneous morphology of droplet-like deposits inner flame zone and the agglomeration of condensed-phase deposits and the transition to soots from grown up droplet-like precursors with approaching the flame surface can be observed in a barely sooting flame. The average size of the mature soots deposited in the luminous flame edge is scarcely dependent on their axial position in a confined flame under reduced oxidizer condition. A double structure of PAH fluorescence is observed in near-extinction flames with further decreasing of oxidizer. A comparison of the PAH fluorescence with the morphologies of deposits indicates that appearance of the "dark" hollow zone is caused by a decreased number density of developed liquid-phase large molecules and the outer weak fluorescence zone is caused by the diffusion of gas-phase small molecules.

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Uranium Fluorescence Analysis in the Raffinate Solution of Nuclear Fuel Conversion Process Using Time-resolved Laser-induced Fluorimetry (레이저 유발형광법을 이용한 변환공정 폐액중의 우라늄 형광분석)

  • Lee, Sang-Mock;Kim, Duk-Hyeon;Shin, Jang-Soo
    • Nuclear Engineering and Technology
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    • v.25 no.4
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    • pp.548-551
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    • 1993
  • A simple and new uranium analysis technique for raffinate solution of nuclear fuel conversion process was developed using a time-resolved laser-induced fluorimetry. The addition of 4 M-phosphoric acid more than 10 times in volume to the raffinate sample was found to be efficient for obtaining stable uranium fluorescence signal which was not influenced by many fluorescence quenchers. A calibration curve of a good linearity for the fluorescence intensity vs. the uranium concentration was obtained at the range of 3.0$\times$10$^{-6}$-6.0$\times$10$^{-5}$ M U $O_2$$^{2+}$ in the raffinate samples.

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Measurement on the Methotrexate in L-${\alpha}$-Phosphatidylcholine Media by Light Sacttering (L-${\alpha}$-Phosphatidylcholine 매질에서 빔산란에 의한 Methotrexate의 측정)

  • Kim, Ki-Jun;Lee, Joo-Youb
    • Journal of the Korean Applied Science and Technology
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    • v.30 no.2
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    • pp.251-257
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    • 2013
  • The influences of Methotrexate as fluorophor, scatterer, absorber in turbid material by light scattering were interpreted for the scattered fluorescence intensity and wavelength, it has been studied the molecular properties by laser induced fluorescence spectroscopy. It has been found that the effects of optical properties in scattering media by the optical parameters((${\mu}_s$, ${\mu}_a$, ${\mu}_t$). The value of scattering coefficient ${\mu}_s$ is large by means of the increasing particles of L-${\alpha}$-Phosphatidylcholine, it has been found that the slope decays exponentially as a function of depth from laser source to detector. It may also aid in designing the best model for oil chemistry, laser medicine and application of medical engineering.

An Improved Laser-Induced Fluorimetry for Assay of Uranium in Urine (레이저 유발형광법을 이용한 우라늄 작업자의 뇨 형광 분석)

  • Lee, Sang-Mok;Shin, Jang-Soo;Kim, Cheol-Jung
    • Nuclear Engineering and Technology
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    • v.25 no.2
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    • pp.255-258
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    • 1993
  • A method for analysis of trace uranium in urine sample was studied using a time-resolved $N_2$-laser-induced fluorimetry. The Fluran solution was found to be efficient to mask the chloride ions which are known to quench uranium fluorescence in the fluorimetric assay of uranium in urine. This improved method made the sample preparation much simpler than other conventional ones. The fluorescence intensities at 1% urine mixture with 10% Fluran aqueous solution showed good linearities in the concentration range of 10-500 ppb(before dilution).

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Laser-Induced Fluorescence Spectroscopy of the $S_1-S_0 (^1B_2-^1A_1)$ Transition of Dimethyldiazirine

  • 김택수;김상규;Choi, Young S.;곽일환
    • Bulletin of the Korean Chemical Society
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    • v.19 no.10
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    • pp.1042-1047
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    • 1998
  • The fluorescence excitation (FE) spectrum of the S1-S0 (1B2-1A1) transition of dimethyldiazirine cooled in supersonic jet expansions has been obtained. Dispersed fluorescence (DF) spectra have also been taken for some prominent features of the FE spectrum. Vibrational analyses of the FE and DF spectra with the help of an ab initio molecular orbital calculation lead to some new vibrational assignments and refined fundamental frequencies.