• Title/Summary/Keyword: Laser Absorption Technique

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$CO_2$ Laser Absorption Measurement of $CH_3CH_2Br$ using Photoacoustic Method

  • Jang Soo Shin;Kyung Hoon Jung;Cheol Jung Kim
    • Bulletin of the Korean Chemical Society
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    • v.13 no.5
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    • pp.553-556
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    • 1992
  • The ${CO}_2$ laser absorption measurement of ${CH}_3{CH}_2Br$ utilizing photoacoustic (PA) technique was performed using a cw and a pulsed ${CO}_2$ lasers. The absorption profile in the ${CO}_2$ laser wavelength region (9-10 ${\mu}$m) and the macroscopic small signal absorption cross section at 10P(20) (10.59 ${\mu}$m, 944 $cm^{-1}$) laser line were measured using a cw ${CO}_2$ laser. The laser fluence dependence on infrared multiphoton absorption (IRMPA) was also studied with a pulsed TEA ${CO}_2$ laser at 10P(20) laser line. In view of monotonic increase of PA signal with the rise of laser fluence, it was suggested that the anharmonicity in pumped vibration mode did not restrict ir multiphoton absorption in ${CH}_3{CH}_2Br$ system as found in large molecular system.

Laser Induced Impedance Changes in Hollow Cathode Lamps

  • Byung Chul Cha;Jae Jung Lee;Ki Beom Lee;Hyo Jin Kim;Gae Ho Lee;Hasuck Kim
    • Bulletin of the Korean Chemical Society
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    • v.14 no.5
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    • pp.610-614
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    • 1993
  • Laser induced impedance changes in hollow cathode lamps containing sputtered metal atoms have been employed to measure the spectroscopic properties of metal. This technique, known as optogalvanic spectroscopy, has been shown to be a powerful and inexpensive technique for the investigation of atomic and molecular species. Characteristic optogalvanic signals from hollow cathode lamps (HCL) made of different metal species and induced with a pulsed dye laser were observed, and the dependence of the optogalvanic signal on the discharge current and wavelength of laser was measured. Based on the results obtained, the mechanisms involved in evoking the optogalvanic signals were consisted of single-photon absorption, multi-photon absorption, and photoionization. Moreover the current dependence of the optogalvanic signal indicates that the optogalvanic technique could be one of the most sensitive optical methods of detecting atomic species.

Species Concentration Measurement Technique Using Wavelength Modulation Absorption Spectroscopy (파장변조 광흡수 분광법을 이용한 농도 계측 기법)

  • Ahn, J.H.;Kim, Y.M.
    • Journal of ILASS-Korea
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    • v.9 no.4
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    • pp.67-76
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    • 2004
  • Diode laser absorption sensors are advantageous because they may provide fast, sensitive, absolute, and selective measurements of species concentration. These systems are very attractive for practical applications owing to its compactness, reasonable cost, robustness, and ease of use. In addition, diode lasers we fiber-optic compatible and thus enable simultaneous measurements of multiple species along a line-of-sight. Recent advances of room-temperature, near-IR and visible diode laser sources for telecommunication, optical data storage applications make it possible to be applied for combustion diagnostics based on diode laser absorption spectroscopy. Therefore, combined with fiber-optics and high sensitive detection strategies, compact and portable sensor systems are now appearing for variety of applications. The objectives of this research are to develop new gas sensing system and to verify feasibility of this system. Wavelength modulation spectroscopy has been demonstrated in these experiments and has a bright prospect to this diode laser system.

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Nanosecond Laser Flash Photolysis Study of 5-Styryl-1,3-dimethyluracil

  • Shim Sang Chul;Shin Eun Ju;Chae Kyu Ho
    • Bulletin of the Korean Chemical Society
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    • v.6 no.4
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    • pp.234-238
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    • 1985
  • The photoisomerization of 5-styryl-1,3-dimethyluracil is studied with nanosecond laser flash photolysis technique at room temperature. The laser flash photolysis of E-isomer produces the transient absorption spectrum regarded as the triplet-triplet absorption, but the transient absorption of Z-isomer does not show the typical decay curve, probably due to the facile photocyclization reaction during the laser flash photolysis. Using the energy transfer method on nanosecond laser spectroscopy, the energy of the lowest triplet state for E isomer is estimated to lie between 41.8 and 47 kcal/mol. The triplet lifetime for E-isomer obtained from the decay curve of the transient absorption is ca. 93ns. The $S_1 → T_1$ intersystem crossing of E-isomer on direct excitation is relatively inefficient at room temperature supporting the singlet mechanism for direct photoisomerization.

Tunable Diode Laser Absorption Spectroscopy for Environmental Monitoring (파장가변 다이오드 레이저 흡수 분광학을 사용한 대기환경분석)

  • Ju Sang-U;Kim Seong-Geun
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2003.11a
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    • pp.247-248
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    • 2003
  • Tunable diode laser absorption spectroscopy (TDLAS) has been widely used in environmental monitoring of gaseous species in the past decade. TDLAS is a direct measurement technique for pollutants such as NOx without any interference from other species. Because of its superior spectral purity (~0.001 ­$cm^{-1}$), absorption linewidths with resolvable rotational structure can be studied in the mid infrared region where strong fundamental vibrational transitions of molecules appear. (omitted)

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Gas Phase Optoacoustic Spectra and Raman Spectra of Some Chlorinated Pollutants

  • Joong-Gil Choi;Jin-soo Hwang;Paeng Ki-Jung;Gerald J. Diebold
    • Bulletin of the Korean Chemical Society
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    • v.14 no.1
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    • pp.127-131
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    • 1993
  • Laser optoacoustic technique has been employed to obtain the gas phase absorption spectra of 1-chloronaphthalene, 3-chlorobiphenyl, and 2,5,2'-trichlorobiphenyl in conjunction with a gas chromatograph and a Helmholtz resonator at the various $CO_2$ laser wavelengths. Raman spectra of 1-chloronaphthalene, 4-chlorobiphenyl, and 4,4'-dichlorobiphenyl in condensed phase have been also obtained. The optoacoustic measurement of the infrared absorption in gas phase has been shown to be of value in monitoring the environmental pollutants.

Hydroxyl Radical Measurements in the Flame Using LIF (레이저유도 형광법을 이용한 화염내 OH 농도분포 계측)

  • Lee, Byeong-Jun;Gil, Yong-Seok;Jeong, Seok-Ho
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.20 no.2
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    • pp.710-719
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    • 1996
  • Laser applied combustion diagnostic techniques-laser induced fluorescence (LIF) and coherent anti-Stokes Ramann spectroscopy (CARS)-are demonstrated. The profiles of hydroxyl radical (OH) and temperature in the counterflow burner are measured and compared with the numerical results. OH radical is excited on the Q$_1$(6) line of the $A^2$$\sum^+$$\leftarrow$$X^2{\prod}$(1, 0) band transition (281.1 nm) and LIF signal is measured at the the bands of (0, 0) and (1, 1) transition (306~326 nm). Absolute OH radical is obtained by using the laser absorption technique. The quenching effects are considered. Temperature is measured using broadband CARS system. Two dimensional OH radical profile is also obtained. The profiles of OH radical and temperature are found to agree well with those of numerical calculation.

Femtosecond Laser Lithography for Maskless PR Patterning (펨토초 레이저를 이용한 미세 PR 패터닝)

  • Sohn, Ik-Bu;Ko, Myeong-Jin;Kim, Young Seop;Noh, Young-Chul
    • Journal of the Korean Society for Precision Engineering
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    • v.26 no.6
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    • pp.36-40
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    • 2009
  • Development of maskless lithography techniques can provide a potential solution for the photomask cost issue. Furthermore, it could open a market for small scale manufacturing applications. Since femtosecond lasers have been found suitable for processing of a wide range of materials with sub-micrometer resolution, it is attractive to use this technique for maskless lithography. As a femtosecond laser has recently been developed, both of high power and high photon density are easily obtained. The high photon density results in photopolymerization of photoresist whose absorption spectrum is shorter than that of the femtosecond laser. The maskless lithography using the two-photon absorption (TPA) makes micro structures. In this paper, we present a femtosecond laser direct write lithography for submicron PR patterning, which show great potential for future application.

Special quality research about action output waveform change by gap (1.0mm and 1.6mm) difference of $CO_2$ laser for skin disease (피부질환을 위한 $CO_2$ 레이저의 공극차이에 따른 동작출력 변화에 관한 연구)

  • Kim, Whi-Young
    • Proceedings of the KIEE Conference
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    • 2007.04a
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    • pp.52-54
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    • 2007
  • Laser wave length can have evaporation effect by absorption because outer skin or tissue of focus is consisted of water almost though absorption of water occurs more than 90% almost in formation thickness of very thin floor. Can operate outer skin, steam by floor and correct incision of formation is available. Suture surgical operation is available to vein or lymph system and surgical operation region can dry and see as eye and radish bleeding surgical operation is available. Specially, stability of tube both end output about pulse by weight very, this research can cause various curative effect because can reduce bulk and control easily current wave style of medical laser using electric power conversion device of high frequency way. If introduce ZVS (Zero Voltage Switching) or ZVZCS (Zero Voltage and Zero Current Switching), is more profitable because can reduce switching damage. Because electric power department of proposed medical laser can do stable soft-switching in wide subordinate extent introducing ZVZCS technique by the first help and control department composes microcontroller, output current waveform user have free form make. Result that experiment because design and manufacture, brought result that improve of 20% than existing equipment, and will be bought to get into superior result if supplement as systematic late.

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The Characteristics of Ductile Cast Iron Heat-treated by $CO_2$Laser (구상흑연주철의 $CO_2$레이저 표면경화 특성)

  • 정원기;전병철;김재도
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 1997.04a
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    • pp.998-1002
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    • 1997
  • This study has been performed to predict beam absorption with analysis of temperature field by using a FEM in co /sab 2/ laser hardening and to invesrigate into some effects of power density and travel speed of laser beam on the microstructure and hardness of ductile cast iron treated by laser surface hardening technique. Optical micrograph has shown that large martensite and small amount of retained austenite appear in inside hardened zone. Hardness measurement has revealed that the range of maximum hardness value is Hv=415 .+-. 10. The power density increases and the travel speed decreases, the depth of hardened zone increases due to increase of input power density.

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