• Title/Summary/Keyword: Large-scale synthesis

Search Result 155, Processing Time 0.027 seconds

Robust Decentralized Stabilization of Uncertain Large-Scale Discrete-Time Systems with Delays (시간지연을 갖는 이산시간 대규모 시스템의 강인 제어기 설계)

  • Park, Ju-Hyeon
    • Journal of the Institute of Electronics Engineers of Korea SC
    • /
    • v.37 no.6
    • /
    • pp.7-14
    • /
    • 2000
  • This paper describes the synthesis of robust decentralized controllers for uncertain large-scale discrete-time systems with time-delays in subsystem interconnections. Based on the Lyapunov method, a sufficient condition for robust stability, is derived in terms of a linear matrix inequality (LMI). The solutions of the LMI can be easily obtained using various efficient convex optimization techniques. A numerical example is given to illustrate the proposed method.

  • PDF

Controlled Synthesis of Spherical Polystyrene Beads and Their Template-Assisted Manual Assembly

  • Yoon, Seo Young;Park, Yi-Seul;Lee, Jin Seok
    • Bulletin of the Korean Chemical Society
    • /
    • v.35 no.8
    • /
    • pp.2281-2284
    • /
    • 2014
  • Polystyrene beads (PS beads) with narrow size distribution were synthesized, and their diameter was controlled from 1.2 to $5{\mu}m$ by varying the injection rate of a styrene solution containing initiator and the concentration of reactant, such as initiator and capping material. The diameter of the PS beads increased with increasing in the injection rates and the initiator concentration or decreasing the capping material concentration. Then, we used the PS beads as building block, and organized them into a hexagonally close-packed monolayer on substrate with template-assisted manual assembly. We showed perfect hexagonally close-packed organization of the PS beads with various sizes in large-scale area. And we demonstrated the superiority of the dry manual assembly over the wet self-assembly in terms of simplicity, speed, perfect ordering, and large scale.

Understanding Role of Precursor (Crystal Violet) and its Polarity on MoS2 Growth; A First Principles Study

  • Ramzan, Muhammad Sufyan;Kim, Yong Hoon
    • Proceeding of EDISON Challenge
    • /
    • 2016.03a
    • /
    • pp.373-376
    • /
    • 2016
  • Transition metal dichalcogenides (TMDs) such as $MoS_2$ is the thinnest semiconductor, exhibits promising prospects in the applications of optoelectronics, catalysis and hydrogen storage devices. Uniform and high quality $MoS_2$ is highly desirable in large area for its applications on commercial scale and fundamental research. Many experimental techniques i.e CVD have been developed to successfully synthesis $MoS_2$ on large scale, here in this work atomistic detail to understand the growth mechanism is addressed which was greatly overlooked. Here based on first principles calculation we found that polarity of seeding promter (crystal violet considerd in this work) controls the growth mechanism. It is also found that molybdenum destroys the precursor while sulfur adsorption with precursor is favorable.

  • PDF

Synthesis and Characterization of DNA-Templated Nanostructures: Toward Molecular Electronics

  • Lee, Jeong-Gyu
    • Proceedings of the Korean Vacuum Society Conference
    • /
    • 2013.08a
    • /
    • pp.92.1-92.1
    • /
    • 2013
  • Molecular electronics has been the subject of intese research for many years because of the fundamental interest in molecular charge transport and potential applications, such as (bio)nanosensors and molecular memory devices. Molecular electronics requires a method for making reliable eletrical contacts to singlemolecules. To date, several approaches have been reported: scanning-probe microscopy, mechanical break junctions, nano patterning, and direct deposition of electrode on a self-assembled monolayers. However, most methods are laborious and difficult for large-scale application and more importantly, cannot control the number of moleucles in the junction. Recently, DNA has been used as a template for metallic nanostructures (e.g., Ag, Pd, and Au nanowires) through DNA metallization process. Furthermore, oligodeoxynucleotides have been tethered to organic molecules by using conventional organic reactions. Collectively, these techniques should provide an efficient route toward reliable and reproducible molecular electronic devices with large-scale fabrication. Therefore, I will present a paradigm for the fabrication of moleuclar electronic devices by using micrometer-sized DNA-singe organic molecule and DNA triblock structures.

  • PDF

A new and efficient synthesis of sulfonylurea (술포닐 우레아유도체의 용이하고 새로운 합성방법)

  • Youn, In-Kwon;Seo, S.U.
    • The Journal of Natural Sciences
    • /
    • v.12 no.1
    • /
    • pp.81-84
    • /
    • 2002
  • We developed new process for the large scale preparation of pyrazole sulfonyl urea and pyrazole sulfonyl urea carboalkoxyl benzene sulfonyl urea 1) in high yields and convenience. As compound with know procedure this procedure have found to be far large scale preparation. During the preparation we obtains two new sulfonyl urea 5a and 5b in 70% and 74% ( purified by crystallization).

  • PDF

Synthesis of nanometric tungsten powders by solid state combustion method (고상연소반응법에 의한 나노텅스텐분말의 합성)

  • H.H. Nersisyan
    • Proceedings of the Materials Research Society of Korea Conference
    • /
    • 2003.11a
    • /
    • pp.93-93
    • /
    • 2003
  • Tungsten and tungsten heavy alloys have widespread application as radiation shielding devices and heavy duty electrical contacts. High density and good room temperature mechanical properties have generated interest in evaluating tungsten and tungsten alloys as kinetic energy penetrators against armor. Nowdays ultra fine-grained tungsten powders are in great interest because higly dense structures can be obtained at low temperature, pressure and lower sintering time. Several physical md chemical methods are available for the synthesis of nanometric metal Powders: ball milling, laser abalation, vapor condensation, chemical precipitation, metallic wire explosion i.e. However production rates of the above mentioned methods are low and further efforts are needed to find out large-scale synthesis methods. From this point of view solid state combustion method ( known as SHS) represents undoubted interest.

  • PDF

Logic circuit design for high-speed computing of dynamic response in real-time hybrid simulation using FPGA-based system

  • Igarashi, Akira
    • Smart Structures and Systems
    • /
    • v.14 no.6
    • /
    • pp.1131-1150
    • /
    • 2014
  • One of the issues in extending the range of applicable problems of real-time hybrid simulation is the computation speed of the simulator when large-scale computational models with a large number of DOF are used. In this study, functionality of real-time dynamic simulation of MDOF systems is achieved by creating a logic circuit that performs the step-by-step numerical time integration of the equations of motion of the system. The designed logic circuit can be implemented to an FPGA-based system; FPGA (Field Programmable Gate Array) allows large-scale parallel computing by implementing a number of arithmetic operators within the device. The operator splitting method is used as the numerical time integration scheme. The logic circuit consists of blocks of circuits that perform numerical arithmetic operations that appear in the integration scheme, including addition and multiplication of floating-point numbers, registers to store the intermediate data, and data busses connecting these elements to transmit various information including the floating-point numerical data among them. Case study on several types of linear and nonlinear MDOF system models shows that use of resource sharing in logic synthesis is crucial for effective application of FPGA to real-time dynamic simulation of structural response with time step interval of 1 ms.

Acid-Base Bifunctional Metal-Organic Frameworks: Green Synthesis and Application in One-Pot Glucose to 5-HMF Conversion

  • Zhang, Yunlei;Jin, Pei;Meng, Minjia;Gao, Lin;Liu, Meng;Yan, Yongsheng
    • Nano
    • /
    • v.13 no.11
    • /
    • pp.1850132.1-1850132.14
    • /
    • 2018
  • The direct synthesis of metal-organic frameworks (MOFs) with acidic and basic active sites is challenging due to the introduction of functional groups by post-functionalization method often jeopardize the framework integrity. Herein, we report the direct synthesis of acid-base bifunctional MOFs with tuning acid-base strength. Employing modulated hydrothermal (MHT) approach, microporous MOFs named $UiO-66-NH_2$ was prepared. Through the ring-opening reaction of 1,3-propanesultone with amino group, $UiO-66-NH_2-SO_3H-type$ catalysts can be obtained. The synthesized catalysts were well characterized and their catalytic performances were evaluated in one-pot glucose to 5-HMF conversion. Results revealed the acid-base bi-functional catalyst possessed high activity and excellent stability. This work provides a general and economically viable approach for the large-scale synthesis of acid-base bi-functional MOFs for their potential use in catalysis field.

On the Principles and Applications of Wave Field Synthesis (WFS의 원리와 활용에 관하여)

  • Yoo, Jae-Hyoun;Shim, Hwan;Chung, Hyun-Joo;Sung, Koeng-Mo;Kang, Kyeong-Ok
    • The Journal of the Acoustical Society of Korea
    • /
    • v.28 no.8
    • /
    • pp.688-696
    • /
    • 2009
  • There are many studies on Wave Field Synthesis(WFS) which provides better presence and spaciousness than conventional discrete multichannel audio reproduction methods. However, it has several problems such as the listener-enclosing loudspeaker array and pre-authorized object-based source signal, so it is not widely used except in large-scale listening rooms. This paper presents a method which utilizes the merit of WFS in small listening rooms such as a living room.