Nano

SKKU Advanced Institute of Nano Technology (성균관대학교 성균나노과학기술원)
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Acid-Base Bifunctional Metal-Organic Frameworks: Green Synthesis and Application in One-Pot Glucose to 5-HMF Conversion

  • Zhang, Yunlei (Institute of Green Chemistry and Chemical Technology School of Chemistry and Chemical Engineering Jiangsu University) ;
  • Jin, Pei (Institute of Green Chemistry and Chemical Technology School of Chemistry and Chemical Engineering Jiangsu University) ;
  • Meng, Minjia (Institute of Green Chemistry and Chemical Technology School of Chemistry and Chemical Engineering Jiangsu University) ;
  • Gao, Lin (Key Laboratory of Preparation and Applications of Environmental Friendly Materials Jilin Normal University, Ministry of Education) ;
  • Liu, Meng (Institute of Green Chemistry and Chemical Technology School of Chemistry and Chemical Engineering Jiangsu University) ;
  • Yan, Yongsheng (Institute of Green Chemistry and Chemical Technology School of Chemistry and Chemical Engineering Jiangsu University)
  • Received : 2018.07.09
  • Accepted : 2018.10.11
  • Published : 2018.11.30
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Abstract

The direct synthesis of metal-organic frameworks (MOFs) with acidic and basic active sites is challenging due to the introduction of functional groups by post-functionalization method often jeopardize the framework integrity. Herein, we report the direct synthesis of acid-base bifunctional MOFs with tuning acid-base strength. Employing modulated hydrothermal (MHT) approach, microporous MOFs named $UiO-66-NH_2$ was prepared. Through the ring-opening reaction of 1,3-propanesultone with amino group, $UiO-66-NH_2-SO_3H-type$ catalysts can be obtained. The synthesized catalysts were well characterized and their catalytic performances were evaluated in one-pot glucose to 5-HMF conversion. Results revealed the acid-base bi-functional catalyst possessed high activity and excellent stability. This work provides a general and economically viable approach for the large-scale synthesis of acid-base bi-functional MOFs for their potential use in catalysis field.

Keywords

Acknowledgement

Supported by : National Natural Science Foundation of China, Natural Science Foundation of Jiangsu Province

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