• Title/Summary/Keyword: LOI method

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Application of Modified Polyesters Containing Phosphorus/Chlorine to PU Flame-Retardant Coatings (인과 염소 함유 변성폴리에스테르의 PU 난연도료에의 적용)

  • Park, Hong-Soo;Kim, Song-Hyoung;Hong, Seok-Young;Yoo, Gyu-Yeol;Ahn, Sung-Hwan;Hahm, Hyun-Sik;Kim, Seung-Jin;Kim, Young-Geun
    • Journal of the Korean Applied Science and Technology
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    • v.24 no.1
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    • pp.31-46
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    • 2007
  • This study was focused on the maximization of flame-retardancy of polyesters by a synergism of simultaneously introduced chlorine and phosphorus into polymer chains of modified polyesters. To prepare modified polyesters, reaction intermediates, TD-adduct (prepared from trimethylolpropane/2,4-dichlorobenzoic acid (2,4-DCBA)) and TMBO (prepared from tetramethylene bis(orthophosphate)), were prepared first, then condensation polymerization of the prepared intermediates, adipic acid, and 1,4-butanediol were carried out. In the condensation polymerization, the content of phosphorus was fixed to be 2%, and the content of 2,4-DCBA that provides chlorine component was varied to be 10, 20, and 30wt%, and we designated the prepared modified polyesters containing chlorine and phosphorus as ABTT-10C, -20C, -30C. Two-component PU flame-retardant coatings (ABTTC, ABTTC-10C, ABTTC-20C, ABTTC-30C) were prepared by the curing of synthesized ABTTs with a curing agent of allophanate/trimer at room temperature. To examine the film properties of the prepared PU flame-retardant coatings, film specimens were prepared with the prepared coatings. The film properties of ABTTC, ABTTC-10C and ABTTC-20C, which contain 0, 10 and 20wt% 2,4-DCBA, respectively, were proved to be good, whereas the film properties of ABTTC-30C, which contains 30wt% 2,4-DCBA, was proved to be a little bit poor. Two kinds of flame retardancy tests, $^{\circ}45Meckel$ burner method and LOI method were performed. With the $^{\circ}45Meckel$ burner method, three flame-retardant coatings except ABTTC showed less than 3.4cm of char length, and showed less than 2 seconds of afterflaming and afterglow. From this result, the prepared flame-retardant coatings were proved to have the 1st grade flame retardancy. With the LOI method, the LOI values of the coatings containing more than 10wt% 2,4-DCBA were higher than 30%, which means that the coatings possess good flame retardancy. From these results, it was found that synergistic effect in flame retardancy was taken place by the introduced phosphorus and chlorine.

Quantifying the effects of climate variability and human activities on runoff for Vugia - Thu Bon River Basin in Central of Viet Nam

  • Lan, Pham Thi Huong;Thai, Nguyen Canh;Quang, Tran Viet;Long, Ngo Le
    • Proceedings of the Korea Water Resources Association Conference
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    • 2015.05a
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    • pp.233-233
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    • 2015
  • Vu Gia - Thu Bon basin is located in central Vietnam between Truong Son mountain range on the border with Lao in the west and the East Sea in the east. The basin occupies about 10,350 km2 or roughly 90% of the Quang Nam Province and includes Da Nang, a very large city with about 876,000 inhabitants. Total annual rainfall ranges from about 2,000 mm in central and downstream areas to more than 4,000 mm in southern mountainous areas. Rainfall during the monsoon season accounts for 65 to 80% of total annual rainfall. The highest amount of rainfall occurs in October and November which accounts for 40 to 50% of the annual rainfall. Rainfall in the dry season represents about 20 to 35% of the total annual rainfall. The low rainfall season usually occurs from February to April, accounting for only 3 to 5% of the total annual rainfall. The mean annual flow volume in the basin is $19.1{\times}109m 3$. Similar to the distribution of rainfall, annual flows are distinguished by two distinct seasons (the flood season and the low-flow season). The flood season commonly starts in the mid-September and ends in early January. Flows during the flood season account for 62 to 69% of the total annual water volume, while flows in the dry season comprise 22 to 38% of total annual run-off. The water volume gauged in November, the highest flow month, accounts for 26 to 31% of the total annual run-off while the driest period is April with flows of 2 to 3% of the total annual run-off. There are some hydropower projects in the Vu Gia - Thu Bon basin as the cascade of Song Bung 2, Song Bung 4, and Song Bung 5, the A Vuong project currently under construction, the Dak Mi 1 and Dak Mi 4 projects on the Khai tributary, and the Song Con project on the Con River. Both the Khai tributary and the Song Con join the Bung River downstream of SB5, although the Dak Mi 4 project involves an inter-basin diversion to Thu Bon. Much attention has recently been focused on the effects that climate variability and human activities have had on runoff. In this study, data from the Vu Gia - Thu Bon River Basin in the central of Viet Nam were analyzed to investigate changes in annual runoff during the period of 1977-2010. The nonparametric Mann-Kendall test and the Mann-Kendall-Sneyers test were used to identify trend and step change point in the annual runoff. It was found that the basin had a significant increasing trend in annual runoff. The hydrologic sensitivity analysis method was employed to evaluate the effects of climate variability and human activities on mean annual runoff for the human-induced period based on precipitation and potential evapotranspiration. This study quantitatively distinguishes the effects between climate variability and human activities on runoff, which can do duty for a reference for regional water resources assessment and management.

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Synthesis and Flame Retardant Improvement of PU Coatings Containing Trichloro Modified Polyester/IPDI-Isocyanurate

  • Kim, Ji-Hyun;Keun, Jang-Hyoun;Jung, Choong-Ho;Kim, Seung-Jin;Kim, Young-Geun;Kim, Seong-Kil;Park, Hong-Soo
    • Journal of the Korean Applied Science and Technology
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    • v.25 no.3
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    • pp.332-340
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    • 2008
  • Two component polyurethane (PU) flame retardant coatings were prepared by blending trichloro modified polyesters (TCMPs) and isophorone diisocyanate isocyanurate. TCMPs were synthesized by polycondensation of trichlorobenzoic acid (TCBA), a flame retardant component, with adipic acid, 1,4 butanediol, and trimethylolpropane. The content of TCBA was varied in 10, 20, and 30 wt% for the reaction. Theses new flame retardant coatings showed various properties comparable to other non flame retardant coatings. Moreover, we carried out the combustion test and the flammability test for our flame retardant coatings. The results of vertical burning test for the coatings containing more than 20 wt% of TCBA were determined as no burn. The results of flammability test for the coatings with 20 wt% and 30 wt% of TCBA contents indicated the limiting oxygen index (LOI) values of 26% and 29% respectively, which implied relatively good flame retardancy.

Study on the Physical Properties and Flame Retardancy of Tencel FR/Cotton Complex Knit Fabrics (Tencel FR/Cotton 복합원단의 물리적 특성 및 난연성에 관한 연구)

  • Kim, Hyun-Ah;Kim, Hyun-Chel
    • Journal of the Korean Society of Clothing and Textiles
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    • v.36 no.7
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    • pp.703-713
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    • 2012
  • This study analyzed the physical properties and flame retardancy of Tencel FR/Cotton complex knit fabrics in order to satisfy two aspects of eco-friendliness and functionality. The flame retardant (FR) treatment of complex knit fabrics was applied by a pad-dry-cure method for additional functionality. Tensile strength, extension, bursting strength, LOI, and flame retardancy were measured by the KS (Korean Standard) K manual. The hand value knit fabrics were measured by KES-FB system. Subsequently, tensile strength and extension of wale and tensile strength of course increased in tandem with the Tencel FR yarn content. Tencel FR/Cotton complex knit fabrics were suitable for summer-weight and for baby clothes through the KES-FB system measurements. The bursting strength of Tencel FR/Cotton complex knit fabrics decreased as the contents of the Tencel FR increased; in addition, LOI increased as the contents of Tencel FR increased. This was due to the Tencel FR flame resistance function; however, the tensile strength decreased. The optimum fiber content of Tencel FR/cotton content was 1:1. The optimum conditions of flame retardant treatment were a treatment temperature $130^{\circ}C$ and the concentration of finishing agent and assistance binder (AR4260) was 35% and 1%, respectively.

Preparation and Characterization of PU Flame-Retardant Coatings Using Modified Polyester Containing Phosphorus/Chlorine and HDI-Trimer (인과 염소 함유 변성폴리에스터와 HDI-Trimer에 의한 PU 난연도료의 제조 및 도막특성화)

  • Park, Hong-Soo;Kim, Song-Hyoung;Hong, Seok-Young;Yoo, Gyu-Yeol;Ahn, Sung-Hwan;Hahm, Hyun-Sik
    • Journal of the Korean Applied Science and Technology
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    • v.23 no.4
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    • pp.328-339
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    • 2006
  • The PU flame-retardant coatings (TTBAH, ATBAH-10C, -20C, and -30C) were prepared using the synthesized ATBAs and HDI-trimer as curing agent at room temperature. The physical properties of PU flame-retardant coatings with chlorine and phosphorus were inferior to those with phosphorus only and the properties were getting worse with increasing chlorine content. Flame retardancy was tested with three methods. With the vertical method, complete combustion time of ATBAHs were $259^{\sim}347$ seconds, which means that the prepared coatings are good flame-retardant. With the $45^{\circ}$ Meckel burner method, char lengths of the three prepared coatings were less than 2.9 cm, which indicates that the prepared coatings are first grade. With the limiting oxygen index (LOI) method, the LOI values of the three prepared coatings were in the range of $30^{\sim}35%$, which proves good flame retardancy of the prepared coatings. from the result of flame retardancy tests of the specimens that contain the same amounts of flame retarding compounds. it was found that the coatings containing both phosphorus and chlorine show higher flame retardancy than the coatings containing only phosphorus. This indicates that there exists, some synergy effect between coexisting phosphorus and chlorine.

Investigating Foreign Direct Investment Attractive Factors of Korean Direct Investment into Vietnam

  • TA, Van Loi;LE, Quoc Hoi;NGUYEN, Thi Lien Huong;PHAN, Thuy Thao;DO, Anh Duc
    • The Journal of Asian Finance, Economics and Business
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    • v.7 no.6
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    • pp.117-125
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    • 2020
  • This paper aims to investigate FDI attractive factors, which are important to formulate policies to attract Korean direct investment into Vietnam. Based on the literature review and the results of interview with 27 Korean investors in Vietnam, we determined the model of variables attracting Korea's FDI into Vietnam. It is used to assess the impact of attractive factors belonging to three groups of variables to support investment decision; they are macroeconomics variables (including market size factor, labor cost factor, and market openness factor), policies variables (including monetary policy factor and tax rate gap factor), and microeconomics variables (geographic advantage factor representative by location). This research also utilized a relatively new quantitative research method based on the Autoregressive Distributed Lag model (ARDL) with the time data chain from 1995 to 2017 of Korean FDI into Vietnam. It analyzes long-term relationships between dependent variables and independent variables. The result of this study indicates that there are three positive factors (low wages, trade openness and government policy) explaining the FDI flows in the long term. The result also shows that incentive tax policy has had a positive impact on Korean FDI, which has satisfied the aim of seeking efficiency of Korean investors.

Application of Isocyanate and Modified Polyester Containing Phosphorous and Chlorine to Crosslinked PU Flame-Retardant Coatings (인과 염소 함유 변성폴리에스터/이소시아네이트 가교 폴리머의 PU 난연도료에의 적용)

  • Park, Hong-Soo;Kim, Song-Hyoung;Ahn, Sung-Hwan;Yoo, Gyu-Yeol;Hahm, Hyun-Sik
    • Journal of the Korean Applied Science and Technology
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    • v.24 no.2
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    • pp.124-139
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    • 2007
  • In order to obtain the maximum flame retardancy with the minimal deterioration of physical properties of PU flame-retardant coatings, chlorine and phosphorous functional groups were introduced into the pre-polymer of modified polyesters. In the first step, the tetramethylene bis(orthophosphate) (TBOP) and neohexanediol dichloroacetate (DCA-adduct) intermediates were synthesized. In the second step, 1,4-butanediol and adipic acid monomers were polymerized with the two kind of intermediates to obtain copolymer. The modified polyesters containing chlorine and phosphorous (ATBA-10C, -20C, and -30C) were synthesized by adjusting the contents of chlorine compound (dichloroacetic acid, 10, 20, 30 wt%) with fixed the content of phosphorous compound (2 wt%). The PU flame-retardant coatings (TTBAH -10C, -20C, and -30C) were prepared using the synthesized ATBAs and HDI-trimer as curing agent at room temperature. The physical properties of PU flame-retardant coatings with chlorine and phosphorous were inferior to those with phosphorous only and the properties were getting worse with increasing chlorine content. Flame retardancy was tested with three methods. With the vertical method, Complete combustion time of ATBAHs were $259^{\sim}347$ seconds, which means that the prepared coatings are good flame-retardant. With the $45^{\circ}$ Meckel burner method, char lengths of the three prepared coatings were less than 2.9 cm, which indicates that the prepared coatings are 1st grade flame retardancy. With the limiting oxygen index (LOI) method, the LOI values of the three prepared coatings were in the range of $30^{\sim}35%$, which proves good flame retardancy of the prepared coatings. From the results of flame retardancy tests of the specimens that contain the same amounts of flame retarding compounds, it was found that the coatings containing both phosphorous and chlorine show higher flame retardancy than the coatings containing phosphorous alone. This indicates that some synergy effect of flame retardancy exists between phosphorous and chlorine.

Geometrically nonlinear elastic analysis of space trusses

  • Tin-Loi, F.;Xia, S.H.
    • Structural Engineering and Mechanics
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    • v.7 no.4
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    • pp.345-360
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    • 1999
  • A general framework for the nonlinear geometric analysis of elastic space trusses is presented. Both total Lagrangian and finite incremental formulations are derived from the three key ingredients of statics, kinematics and constitutive law. Particular features of the general methodology include the preservation of static-kinematic duality through the concept of fictitious forces and deformations, and an exact description for arbitrarily large displacements, albeit small strain, that can be specialized to any order of geometrical nonlinearity. As for the numerical algorithm, we consider specifically the finite incremental case and suggest the use of a conventional, simple and flexible arc-length based method. Numerical examples are presented to illustrate and validate the accuracy of the approach.

A numerical model for masonry implemented in the framework of a discrete formulation

  • Nappi, A.;Tin-Loi, F.
    • Structural Engineering and Mechanics
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    • v.11 no.2
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    • pp.171-184
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    • 2001
  • A direct discrete formulation suitable for the nonlinear analysis of masonry structures is presented. The numerical approach requires a pair of dual meshes, one for describing displacement fields, one for imposing equilibrium. Forces and displacements are directly used (instead of having to resort to a model derived from a set of differential equations). Associated and nonassociated flow laws are dealt with within a complementarity framework. The main features of the method and of the relevant computer code are discussed. Numerical examples are presented, showing that the numerical approach is able to describe plastic strains, damage effects and crack patterns in masonry structures.

A New Approach to Solve the Rate Control Problem in Wired-cum-Wireless Networks

  • Loi Le Cong;Hwang Won-Joo
    • Journal of Korea Multimedia Society
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    • v.9 no.12
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    • pp.1636-1648
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    • 2006
  • In this paper, we propose a new optimization approach to the rate control problem in a wired-cum-wireless network. A primal-dual interior-point(PDIP) algorithm is used to find the solution of the rate optimization problem. We show a comparison between the dual-based(DB) algorithm and PDIP algorithm for solving the rate control problem in the wired-cum-wireless network. The PDIP algorithm performs much better than the DB algorithm. The PDIP can be considered as an attractive method to solve the rate control problem in network. We also present a numerical example and simulation to illustrate our conclusions.

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