• Title/Summary/Keyword: LOI

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Assessment of Flame Retardancy for Acrylonitrile Butadiene Styrene Containing Metal Powder and Flame Retardant (금속분말-난연제 함유 ABS의 난연 특성 평가)

  • Song, Young-Ho;Chung, Kook-Sam
    • Fire Science and Engineering
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    • v.21 no.2 s.66
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    • pp.30-35
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    • 2007
  • The flame retardancies by the addition of metal powder and flame retardant were evaluated to present as the fundamental data to decrease the fire hazard of polymers and life losses by suffocation and poisoning. For this study, the experiments of flame retardancy were conducted as follows : weight loss rate using thermogravimetric analysis, the measurement of the limiting oxygen index(LOI) and char yield. And smoke mass concentration and CO yield were measured. Acrylonitrile butadiene styrene containing metal powder and flame retardant reduced weight loss rate and increased LOI and char yield with the decreased smoke mass concentration and CO yield. It was found that the most effective complex was tricresyl phosphate-Mo complex.

Incombustibility of Polypropylene by Metal Addition Flame Retardant (폴리프로필렌의 금속첨가형 난연제에 의한 난연 특성)

  • Lee, Sang-Eun;Song, Young-Ho;Chung, Kook-Sam
    • Journal of the Korean Society of Safety
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    • v.20 no.4 s.72
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    • pp.40-45
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    • 2005
  • The principal actions of a flame retardant are to decrease or prevent the formation of volatile products and increase the formation of char layer. Use of flame retardant additives can decrease the overall fire hazard of the product containing them thus leading to an increase in overall fire safety. Although several flame retardants have been developed for use in polymers, many of these are known to increase the amount of smoke and toxic gases generated by them. This paper present a new flame retardant using metal addition flame retardant. For this study, the experiments of flame retardancy conducted are as follows : burning ratio, weight loss rate using TGA-DTA, the measurement of LOI and char yield. And smoke mass concentration and CO yield were measured. The metal addition flame retardant reduced burning ratio and weight loss rate, increased the LOI and yield of char formation with decreased smoke mass concentration and CO yield.

Flame-retardant Coating of Cotton Fabric via UV curing of DMEP

  • Jang, Jin-Ho;Kim, Young-Min;Jeong, Yong-Kyun;Nam, Young Sik
    • Textile Coloration and Finishing
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    • v.19 no.5
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    • pp.1-7
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    • 2007
  • A new UV-curable coating was carried out to impart the flame-retardant property to cotton fabric using Bis[2-(methacryloyloxy)ehtyl]phosphate(DMEP) and 2-hydroxy-2-methyl-1-phenyl-propan-l-one(HMPP) as a UV-curable monomer and a photoinitiator, respectively. The cotton fabrics were applied with various amounts of DMEP and HMPP via padding and UV irradiation, and the optimal concentrations of DMEP and HMPP in the formulation were 40%(w/w) and 7%omp respectively. A limiteed oxygen index(LOI) up to 28.9 was obtained for the UV-cured fabric, which may occur through a condensed phase mechanism as verified by the increased residue number with increased application level. The characterization of the UV-cured coating was made by IR analysis, thermo-gravimetric analysis, LOI test, and scanning electron microscopy.

Physical Properties of Synthetic PU Flame-Retardant Coatings Containing Triphosphorus Modified Polyesters (트리포스포러스 변성폴리에스테르 함유 PU 난연도료의 도막물성)

  • Park, Hong-Soo;Kang, Young-Gu;Kim, Ji-Hyun;Hahm, Hyun-Sik;Keun, Jang-Hyoun
    • Journal of the Korean Applied Science and Technology
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    • v.25 no.2
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    • pp.151-159
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    • 2008
  • The flame-retardant coatings were prepared by blending the synthesized triphosphorus modified polyester in the previous paper and hexamethylene diisocyanate-trimer and curing it at room temperature. The characterization of the films of the prepared coatings was performed. It was confirmed that no deterioration of physical properties of PU coatings was observed with the increasing phenylphosphonic acid (PPA) contents. Flame retardancy was tested by a $45^{\circ}$ Meckel burner method and LOI method. With the $45^{\circ}$ Meckel burner method, CATBTP-20C and CATBTP-30C that contain 20 wt% and 30 wt% of PPA, flame retarding component, respectively, showed the first grade flame retardancy with $2.8{\sim}3.9\;cm$ of char length ; and, with LOI method, they exhibited a good flame retardancy as a range of $30{\sim}32%$ of combustion values.

Foaming Properties and Flame Retardancy of the Foams Based on NBR/GTR Compounds (니트릴고무/타이어고무분말(GTR)를 이용한 발포체의 발포 및 난연 특성에 관한 연구)

  • Moon, Sung-Chul;Jo, Byung-Wook;Choi, Jae-Kon
    • Elastomers and Composites
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    • v.37 no.3
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    • pp.159-169
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    • 2002
  • The improvement of flame retardancy of the foams based on NBR/GTR compounds was conducted by formulating various materials i.e. NBR, GTR, inorganic and phosphorus containing flame retardants, foaming agent, cross-linking agent and activator. The foaming properties, morphology, smoke density and flame retardancy of the specimens were investigated using SEM, LOI tester, smoke density control system and cone calorimeter. The phosphorus containing flame retardant reduces heat release rate, increases the limiting oxygen index and a char formation. The inorganic flame retardant increases the limiting oxygen index and reduces heat release rate with an increased CO yield by char formation, and smoke suppressing effect. The formed char seemed to intercept the oxygen transport and heat transfer into the core area. When the composition ratios of the compounds of NBR/GTR were $100{\sim}80/0{\sim}20 wt.%$, and the ratios of the rubbers/flame retardants were $1/1.55{\sim}3.60 wt.%$, we could developed foams with low heat release rate, high limiting oxygen index($28.0{\sim}39.3$), closed or semi-closed cell of uniformity and reasonable expandability($225{\sim}250 %$).

Properties of Carbon-Rich Particles and Purified Ash Obtained from Countercurrent Column Flotation (부유분리법에 의해 분리한 고순도 정제석탄회와 고탄소 석탄회의 특성)

  • 이정언;안영철;김성찬;구재현;나성수;신진혁;이재근
    • Resources Recycling
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    • v.8 no.4
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    • pp.11-19
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    • 1999
  • Fly ash generated from (he pulverized coal power plant have caused the serious ocean pollution due to the disposal in the ash pond, the life reduction of a power plant and the waste of re-utilizable resource The research to reuse the unburned carbon and mineral composing of the ash has been progressed. In this study. the physical and chemical characteristics of high grade ash and unburned carbon particles obtained from countercurrent column flotation are investigated. The cleaned ash of the less 0,5% loss on Ignition(LOI) in carbon content is a spherical sphere and 39.8${\mu}m$ in size of MMD(Mass Median Diameter). 2.22 $m^2/g$ of specific area. The morphology of high LOI carbon particles is a amorphousness, 76.6 ${\mu}m$ of particle size and 15.2 $m^2/g$ of specific The high grade cleaned ash and the high LOI ash have some difference in the light of physical. chemical and morphological characteristics

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The Impact of Nakdong Estuarine Barrage on Distribution of Biogenic Silica (BSi) in Surface Sediment (하구둑이 낙동강 하구 표층 퇴적물 생규소(BSi) 분포에 미치는 영향)

  • KIM, YUNJI;AN, SOONMO
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.22 no.4
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    • pp.172-186
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    • 2017
  • Current study is a part of the efforts to assess the estuarine barrage effects on the coastal ecosystem induced by the Si flux changes. Surface sediments from Seomjin and Nakdong estuary and sediment cores from Nakdong estuary was analysed to investigate the effect of estuarine barrage on the distribution of grain size, organic matter (loss on ignition: LOI) and biogenic silica (BSi). The samples of Seomjin estuary were collected in March, 2015 and those of Nakdong estuary were collected in November, 2014. Generally, the longitudinal distribution of grain size, LOI and BSi in Seomjin estuary, natural estuary, was gradually changed. However mud (silt and clay), LOI and BSi increased from station mid-estuary where tide reaches year-round. The distribution of grain size, LOI and BSi in Nakdong estuary, however, were entirely different between inside and outside of estuarine barrage. The mud percentage and LOI were low and consistent in inside of the barrage except R05, inside of right gate, yet those of outside of the barrage were higher and varied by adjacent sluices. Mud, LOI and BSi of ND1 and ND2 decreased immediately after the construction of Nakdong estuarine barrage due to disturbance of sediment and decrease of sediment supply. To exclude the physical effects by the barrage, BSi excess ($BSi_{exc}$) was calculated using regression equation of BSi-LOI and BSi-mud of Seomjin estuary. $BSi_{exc}$ of Seomjin estuary decreased gradually from upper estuary to lower estuary. $BSi_{exc}$ of Nakdong estuary were positive in inside of the barrage and negative in outside of the barrage. BSi retention and shift of species composition of diatom by the barrage would affect $BSi_{exc}$ distribution. Before the construction of Nakdong estuarine barrage, $BSi_{exc}$ of ND2 was negative and consistent owing to high mud sedimentation. After the construction, $BSi_{exc}$ of ND2, however, fluctuated due to continuous disturbance of sediment due to construction of Eulsuk bridge and East gate.

Characteristics of Through Transmission Pulsed Eddy Current Signals from layers (복합층에서 나타나는 투과형 펄스와전류 신호의 특성)

  • Choi, Dong-Myung;Shin, Young-Kil;Kweon, Young-Ho
    • Proceedings of the KIEE Conference
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    • 2008.04c
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    • pp.53-55
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    • 2008
  • 복합층에서 나타나는 투과형 펄스와전류(Pulsed Eddy Current; PEC) 탐상신호를 수치해석 방법을 사용하여 예측하고 분석하였다. 공기층이 없는 복합층에서 Ti-6Al-4V의 두께가 변하는 경우에는 Lift-off를 변화시켰을 때 나타나는 펄스와전류 신호특성과 LOI(Lift-off Intersection)가 형성되는 것을 관찰할 수 있었고, Aluminum의 두께가 변하는 경우에는 Aluminum만의 두께변화 시 발생하던 신호특성이 났다. 공기층이 있는 복합층에서는 Lift-off를 변화시켰을 때 나타나는 신호특성과 LOI가 형성되었고, 공기층이 증가하면 피크 값이 감소하는 것을 볼 수 있었다.

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Flame Retardancy of Cellulose Fabrics Treated with 3-(Hydroxyphenyl Phosphinyl) Propanoic Acid

  • Zhang, Lianping;Kim, Sam-Soo;Lee, Jae-Woong
    • Textile Coloration and Finishing
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    • v.20 no.5
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    • pp.1-6
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    • 2008
  • 3-(Hydroxyphenyl phosphinyl) propanoic acid (HPPA) has been one of the most commonly used durable flame retardant agents for polyethylene terephthalate (PET) for many years. We intended to explore the application of HPPA to cellulose fabrics as formaldehyde-free phosphorus based flame retardants (FRs) through green chemistry process. The flame retardancy of the flame-retardant treated cellulose fabrics were characterized by using inductively coupled plasma spectroscopy (ICP) and limiting oxygen index (LOI). Structural changes of the treated cellulose fabrics were carried out by thermogravimetric analysis (TGA) and Fourier transform infrared (FT-IR) spectroscopy. To enhance the flame retardancy of HPPA treated cellulose fibers, glycerol polyglycidyl ether (GPE), a crosslinking agent was employed. Both HPPA and GPE treated cotton fabric imparted an LOI value over 26.

Mission Design for a Lunar Orbiter Launched by KSLV-II (한국형발사체를 사용한 달궤도선의 임무 설계)

  • Song, Eun-Jung;Park, Chang-Su;Cho, Sang-Bum;Roh, Woong-Rae
    • Aerospace Engineering and Technology
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    • v.8 no.1
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    • pp.108-116
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    • 2009
  • This paper considers the trajectory design problem for a lunar orbiter when launched by KSLV-II. KSLV-II puts its kick motor stage and lunar orbiter into a low earth orbit, and then the kick motor stage performed the translunar injection. To simulate more realistic situations, TLI (Trans-Lunar Injection) and LOI (Lunar Orbit Injection) maneuvers are modeled as finite burns. The feasibility of the lunar mission by KSLV-II are confirmed by the numerical results that show the reasonable required-velocity and propellant usage.

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