• Title/Summary/Keyword: LIBS

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Hybrid Energy Storage Mechanism Through Solid Solution Chemistry for Advanced Secondary Batteries (고성능 이차 전지용 하이브리드 에너지 저장 메커니즘을 위한 고용체 화학)

  • Sion Ha;Kyeong-Ho Kim
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.37 no.1
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    • pp.11-25
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    • 2024
  • Lithium-ion batteries (LIBs) have attracted great attention as the common power source in energy storage fields of large-scale applications such as electrical vehicles (EVs), industries, power plants, and grid-scale energy storage systems (ESSs). Insertion, alloying, and conversion reactions are the main electrochemical energy storage mechanisms in LIBs, which determine their electrochemical properties and performances. The electrochemical reaction mechanisms are determined by several factors including crystal structure, components, and composition of electrode materials. This article reviews a new strategy to compensate for the intrinsic shortcomings of each reaction mechanism by introducing the material systems to form a single compound with different types of reaction mechanisms and to allow the simultaneous hybrid electrochemical reaction of two different mechanisms in a single solid solution phase.

Life Cycle Assessments of Long-term and Short-term Environmental Impacts for the Incineration of Spent Li-ion Batteries (LIBs) (전과정평가를 이용한 폐리튬이온전지의 소각에 대한 장/단기 환경영향 평가)

  • Jeong, Soo-Jeong;Lee, Ji-yong;Sohn, Jeong-soo;Hur, Tak
    • Applied Chemistry for Engineering
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    • v.17 no.2
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    • pp.163-169
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    • 2006
  • A Life Cycle Assessment (LCA) study was carried out to identify and improve the environmental aspects associated with the present incineration system of spent Li-ion batteries (LIBs) in Korea. The environmental impact associated with the landfill of the incineration ash was also assessed in this study, while so far it was excluded in most studies. It was found out that the $CO_{2}$ emission from the electricity generation as well as the incineration process and heavy metals emissions to air and water accounted for about 90% of total environmental impacts. In particular, the effect of the emission of heavy metals were dominant. In oder to improve the current incineration system environmentally, it is needed to incinerate the wastes like spent LIBs which contained relatively high portion of heavy metals separately from other combustible wastes. On the other hand, the effect of the landfill of ash after incineration was insignificant since the ash from the incineration process was chemically stable.

Effect of Methodologies for Laser-Induced Plasma Creation on Hydrogen Sensing (레이저 유도 플라스마 생성 방법이 수소 검출에 미치는 영향)

  • Jang, Jung-Ik;Kim, Ki-Bum
    • Transactions of the KSME C: Technology and Education
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    • v.3 no.4
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    • pp.291-297
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    • 2015
  • As promising future energy source, hydrogen has been drawing much attention; however, it is easily leaked from the small gap in any storage container due to its find molecule size. In this study, Laser induced breakdown spectroscopy(LIBS) was used for hydrogen leak detection, and feasibility of the scheme was evaluated based on different way for plasma generation. Laser power of 295 mW was required for generating plasma on metal surface to measure hydrogen atomic emission while approximately 2.5 times higher laser power was needed for plasma formation directly in the hydrogen gas stream. It was shown that peak to base ratio increased linearly with increasing the concentration of hydrogen. It can be concluded that LIBS is a viable technique for hydrogen sensing when the concentration of hydrogen is less than 5%.