• Title/Summary/Keyword: LI14

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Electrochemical Properties and Crystal Structure of $Li_{1+x}Mn_2O_4$($0\leqx\leq0.075$) Synthesized at Solid State Method (고상법에 의한 $Li_{1+x}Mn_2O_4$ ($0\leqx\leq0.075$) 의 결정구조와 전기화학적 특성)

  • 박종광;고건문;임성훈;황종선;한병성
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.14 no.5
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    • pp.383-390
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    • 2001
  • We have investigated the L $i_{1+x}$M $n_2$ $O_4$system as a cathode material for lithium rechargeable batteries. To improve the cycle performance of spinel LiM $n_2$ $O_4$ as the cathode of 4V class lithium secondary batteries, spinel phase L $i_{1+x}$M $n_2$ $O_4$(x=0, 0.025, 0.05, 0.075) was prepared at 75$0^{\circ}C$ for 48h. The preparation of L $i_{1+x}$M $n_2$ $O_4$ from L $i_2$ $O_3$ and Mn $O_2$ under air is studied. The compounds were synthesized by using solid-state reaction. Structural refinements were carried out with a Rietveld-refinement program. Electrochemical properties were examined using the Li/L $i_{1+x}$M $n_2$ $O_4$ cells. The capacity of L $i_{1+x}$M $n_2$ $O_4$ decreases with increases lithium content, while the cycle life improves. The initial discharge capacity are 118mAh/g and 116mAh/g for LiM $n_2$ $O_4$ decreases with increases lithium content, while the cycle life improves. The initial discharge capacity are 118mAh/g and 116mAh/g for LiM $n_2$ $O_4$ and L $i_{1.025}$M $n_2$ $O_4$, respectively.pectively.

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Update for Building Layers of Digital Map Using LiDAR Data and Aerial Images (LiDAR자료와 항공영상을 이용한 수치지형도 건물레이어 갱신)

  • Yoo, Hwan-Hee;Goo, Sin-Hoi;Kim, Seong-Sam
    • Journal of Korean Society for Geospatial Information Science
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    • v.14 no.2 s.36
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    • pp.43-53
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    • 2006
  • As NGIS project has been implemented in 1995 and effectiveness of geospatial information increased, Digital maps serve several purpose in administrative, living, and the variety of industrial fields. But, Digital maps have difficulties in application of managing urban facilities due to many differences with real world information caused by high update cost and long generation period. This paper suggests an update method of building layers of digital map in urban area; first, we verify the filtered building information using digital areal imagery and LiDAR data which is high-accurate and also can be faster and more economical in 3D information acquisition, and finally update building layers by comparing with the existed digital map. Future research will concentrate on automatic removal of the small and the tree regions, discrimination of buildings and vegetation for generating and updating building layers using LiDAR data.

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Study on Optimization of Li-ion Battery Pack Design by RSM (RSM 방법에 의한 리튬이온 배터리 팩의 최적 설계)

  • Joo, Kangwo;Jang, Kyungmin;Kim, Kwang sun
    • Journal of the Semiconductor & Display Technology
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    • v.14 no.1
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    • pp.39-43
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    • 2015
  • This paper is to derive information about the optimal shape of the pack has a minimum temperature range of a Li-ion battery equipped with a module. We selected the shape of the pack in order to reduce the temperature deviation between the batteries as a variable. And we derived the experimental points with a minimum of DOE by D-optimal. We analyzed the temperature and the flow within the battery pack by using a numerical analysis verified in previous studies. We derive the equation for the temperature variation in the objective function using the RSM and performed optimization. As a result, it was confirmed that with the variation in the $1.706e-4^{\circ}C$ when to apply an optimized shape.

An Evaluation on the Weldability of Al-Li Alloys by Varestraint Testing Method (Varestraint Test법에 의한 Al-Li합금의 용접성 평가)

  • 김형태;이창배;신현식;서창제
    • Journal of Welding and Joining
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    • v.14 no.6
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    • pp.48-57
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    • 1996
  • The weldability of high purity aluminum-lithium binary alloys has been investigated using the Varestraint test. Autogenous GTAW (gas-tungsten-arc-welds) were run along specimens of different lithium concentration using three sets of welding parameters. Welding voltage was held constant at 10 volts. Welding current (70∼100 amps) and travel speed (23∼33 cm/min) were the parameter varied. Hot-tearing susceptibility varied with lithium content and exhibited a steep peak at 2.6 weight percent lithium. Depth of penetration increased with increasing heat input and lithium concentration. The susceptibility is influenced by the wettability of dendrites by the interdendritic eutectic liquid as well as the time available for back-Siting by eutectic liquid. The welding condition of welding current 70A and travel speed 23 cm/min was showed good resistance to cracking in aluminum-lithium alloys. Suggestions for improving weld cracking resistance are also provided.

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Influence of Substrate Temperature of KLN Thin Film Deposited on Amorphoous Substrate (비정질 기판위에 증착한 KLN 박막의 기판온도에 의한 영향)

  • 박성근;최병진;홍영호;전병억;김진수;백민수
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.14 no.1
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    • pp.34-42
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    • 2001
  • The influences of substrate temperature were studied when fabricating KLN thin film on amorphous substrate using an rf-magnetron sputtering method. Investigating the vaporization temperature of the each element, the excess ratio of target and the optimum deposition conditions were effectively selected when thin filmizing a material which have elements with large difference fo vaporization temperature. In order to compensate K and Li which have lower vaporization temperatures than Nb, KLN target of composition excess with K of 60% and Li of 30% was used. KLN thin film fabricated on Corning 1737 glass substrate had single KLN phase above 58$0^{\circ}C$ of substrate temperature and crystallized to c-axis direction. The optimum conditions were rf power of 100W, process pressure of 150mTorr, and substrate temperature of $600^{\circ}C$.

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SEPARATION OF CsCl FROM LiCl-CsCl MOLTEN SALT BY COLD FINGER MELT CRYSTALLIZATION

  • Versey, Joshua R.;Phongikaroon, Supathorn;Simpson, Michael F.
    • Nuclear Engineering and Technology
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    • v.46 no.3
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    • pp.395-406
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    • 2014
  • This study provides a fundamental understanding of a cold finger melt crystallization technique by exploring the heat and mass transfer processes of cold finger separation. A series of experiments were performed using a simplified LiCl-CsCl system by varying initial CsCl concentrations (1, 3, 5, and 7.5 wt%), cold finger cooling rates (7.4, 9.8, 12.3, and 14.9 L/min), and separation times (5, 10, 15, and 30 min). Results showed a potential recycling rate of 0.36 g/min with a purity of 0.33 wt% CsCl in LiCl. A CsCl concentrated drip formation was found to decrease crystal purity especially for smaller crystal formations. Dimensionless heat and mass transfer correlations showed that separation production is primarily influenced by convective transfer controlled by cooling gas flow rate, where correlations are more accurate for slower cooling gas flow rates.

Evaluation of inundation damages based on the fluctuation of inundation height due to climate change in Haeundae Area (해운대 지역의 기후변화에 의한 해일고 변동에 따른 침수피해 평가)

  • MAENG, Da-Hye;JANG, Dong-Ho
    • Journal of The Geomorphological Association of Korea
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    • v.18 no.4
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    • pp.141-152
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    • 2011
  • The fluctuation of inundation height due to climate change and sea level rise is expected to cause the socio-economical damage in the coastal zone. To evaluate the inundation damage in Haeundae Beach Area, the inundation height was calculated using the observed data and the range of inundated area and buildings was estimated by applying to DEM data, which was constructed with airborne LiDAR data. The range of inundated area and buildings were estimated with 5 scenario of sea level rise in the condition of minimum and maximum inundation height. When the 181cm, the area of 7.19ha and 5 buildings were expected to be inundated. As 20cm in sea level rises at the minimum of the inundation height, the area of 8.90ha and 8buildings were expected to be inundated. As 30cm, 40cm, 50cm, 60cm in sea level rise, 9.98ha and 9 buildings, 11.11ha and 11buildings, 12.41ha and 11buildings, 14.18ha and 14buildings were expected to be inundated, respectively. When the 526 cm, the area of 32.35ha and 42buildings were expected to be inundated. As 20cm, 30cm, 40cm, 50cm, 60cm in sea level rise at the maximum of the inundation height, 38.94ha and 47buildings, 42.46ha and 52buildings, 45.76ha and 58buildings, 49.51ha and 66buildings, 52.53ha and 72buildings were expected to be inundated, respectively. The leisure and industry facilities, socio-economical installation, habitation are located near by the estimated inundation area, then the inundation damage is expected to be greater scale.

Extrafetal Transfer of $Li^{+}$ in Amniotic Fluid of Pregnant Rabbits (토끼에서 태자를 통하지 않은 양수내 $Li^{+}$의 이동)

  • Kim, Young-Jae;Ho, Won-Kyung;Sung, Ho-Kyung
    • The Korean Journal of Physiology
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    • v.24 no.1
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    • pp.27-37
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    • 1990
  • The extrafetal transfer of $Li^{+}$ in amniotic fluid was studied in 45 pregnant rabbits. LiCl solution was administered either intravenously to mother or directly into the amniotic sac and monitored the appearance and disappearance of $Li^{+}$ in the amniotic fluid, then calculated the transfer rate of $Li^{+}$ of extrafetal origin. To study the transplacental $Li^{+}$ transfer, a solution of 150 mM LiCl was infused continuously via maternal vein (initial dose: 0.7 mmol/kg, maintaining dose: 0.03 mmol/kg/min) and the $Li^{+}$ concentration was measured in maternal blood and amniotic fluid after 60 and 120 minutes of infusion. Change in the volume of aminotic fluid was determined by Congo red dilution method at the same time. Effects of duration of gestation was not considered in this study. Extrafetal transport of $Li^{+}$ into the amniotic fluid was estimated by comparing the $Li^{+}$ concentration and volume of amniotic fluid determined before and after ligating the placental vessels. Extrafetal $Li^{+}$ transport from the amniotic fluid was determined by observing the time dependent disappearance of $Li^{+}$ and Congo red in amniotic fluid after injecting 0.5 ml solution of 15 mM or 90 mM LiCl and 50 mg/ml Congo red. Following are the results obtained: 1) During infusion of LiCl through maternal vein the ratio of the aminotic $Li^{+}$/maternal plasma $Li^{+}$ increased significantly along with the increment of fetal weight. 2) The volume of amniotic fluid of larger fetuses than 20.5 gm increased significantly during administration of LiCl while that of smaller fetuses did not change. 3) After umbilical cord ligation the $Li^{+}$ concentration of amniotic fluid of larger fetuses than 20.5 gm was decreased to $59.9{\pm}10.3%$ and $56.9{\pm}42.9%$ $(mean{\pm}S.D.)$ of those of control group after 60 and 120 minutes of LiCl infusion respectively. In amniotic fluid of smaller fetuses than 20.5 gm, there was no significant difference between control and ligation groups. 4) The disappearance rate of Congo red in the amniotic fluid was $45.2{\pm}8.2%/hr$. 5) The disappearance rate of $Li^{+}$ after intraamniotic injection of LiCl depended on the amount injected. On injecting $7.5\;{\mu}mol$ LiCl, $Li^{+}$ disappeared rapidly from the amniotic fluid and the rates after 60 min and 90 min were $97.0{\pm}2.8,\;98.5{\pm}2.0%$ respectively. On injecting $45\;{\mu}mol$ LiCl, the rates were $56.0{\pm}15.4,\;78.9{\pm}14.5%$ at 60 and 90 min. 6) From the above results it was concluded: a) $Li^{+}$ transfer into the amniotic fluid increased along with the fetal growth and one half of $Li^{+}$ influx is through the extrafetal route even after the maturation of fetal kidney. b) One half of the $Li^{+}$ transfer from the amniotic fluid was through swallowing of fetus, while the remaining half was transfered rapidly through amniotic membrane, which was concentration limited.

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The Kinematical Analysis of Li Xiaopeng Motion in Horse Vaulting (도마운동 Li Xiaopeng 동작의 운동학적 분석)

  • Park, Jong-Hoon;Yoon, Sang-Moon
    • Korean Journal of Applied Biomechanics
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    • v.13 no.3
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    • pp.81-98
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    • 2003
  • The purpose of this study is to closely examine kinematic characteristics by jump phase of Li Xiaopeng motion in horse vaulting and provide the training data. In doing so, as a result of analyzing kinematic variables through 3-dimensional cinematographic using the high-speed video camera to Li Xiaopeng motion first performed at the men's vault competition at the 14th Busan Asian Games, the following conclusion was obtained. 1. It was indicated that at the post-flight, the increase of flight time and height and twisting rotational velocity has a decisive effect on the increase of twist displacement. And Li Xiaopeng motion showed longer flight time and higher flight height than Ropez motion with the same twist displacement of entire movement. Also the rotational displacement of the trunk at peak of COG was much short of $360^{\circ}$(one rotation) but twist displacement showed $606^{\circ}$. Likewise, Li Xiaopeng motion was indicated to concentrate on twist movement in the early flight. 2. It was indicated that at the landing, Li Xiaopeng motion gets the hip to move back, the trunk to stand up and the horizontal velocity of COG to slow down. This is thought to be the performance of sufficient landing, resulting from large security of rotational displacement of airborne and twist displacement. 3. It was indicated that at the board contact, Li Xiaopeng motion made a rapid rotation uprighting the trunk to recover slowing velocity caused by jumping with the horse in the back, and has already twisted the trunk nearly close to $40^{\circ}$ at board contact. Under the premise that elasticity is generated without the change of the feet contacting the board, it will give an aid to the rotation and twist of pre-flight. Thus, in the round-oH phase, the tap of waist according to the fraction and extension of hip joint and arm push is thought to be very important. 4. It was indicated that at the pre-flight, Li Xiaopeng motion showed bigger movement than the techniques of precedented studies rushing to the horse, and overcomes the concern of relatively low power of jump through the rapid rotation of the trunk. Li Xiaopeng motion secured much twist distance, increased rotational distance with the trunk bent forward, resulting in the effect of rushing to the horse. 5. At horse contact, Li Xiaopeng motion makes a short-time contact, and maintains horse take-off angle close to vertical, contributing to the increase of post-flight time and height. This is thought to be resulted from rapid move toward movement direction along with the rotational velocity of trunk rapidly earned prior to horse contact, and little shave of rotation axis according to twist motion because of effective twist in the same direction.