• 제목/요약/키워드: LI14

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반응성 기포개방제를 이용한 개방기포형 경질우레탄폼 (Open-Cell Rigid Polyurethane Foam Using Reactive Cell Opening Agents)

  • 안원술
    • 한국산학기술학회논문지
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    • 제14권5호
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    • pp.2524-2528
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    • 2013
  • 일반적인 독립기포형 경질폴리우레탄 폼을 만들기 위한 formulation으로부터 개방기포형 경질 우레탄 폼을 얻기 위하여 반응성 기포개방제로서 1-butanol 및 12HSA (12-hydroxystearic acid)의 금속염인 Li-12HSA를 첨가제로 사용하여 만들어진 샘플의 물성과 기포개방 특성에 관한 연구를 진행하였다. 4.0 phr의1-butanol을 단독으로 사용할 때에 비하여 2 phr의 Li-12HSA를 복합하여 사용할 때의 기포개방율은 10.5%에서 98.0%로 현저한 개선효과를 나타내었다. 연구의 결과로서, 반응에 의하여 부피가 큰 막대형 분자를 우레탄 측쇄로 도입함으로서 독립기포형 경질 우레탄 폼의 기포크기나 밀도, 및 열전도율 등의 큰 변화없이 완전 개방기포형 경질 우레탄 폼을 얻을 수 있음을 보여주었다.

Comprehensive Bioinformation Analysis of the MRNA Profile of Fascin Knockdown in Esophageal Squamous Cell Carcinoma

  • Wu, Bing-Li;Luo, Lie-Wei;Li, Chun-Quan;Xie, Jian-Jun;Du, Ze-Peng;Wu, Jian-Yi;Zhang, Pi-Xian;Xu, Li-Yan;Li, En-Min
    • Asian Pacific Journal of Cancer Prevention
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    • 제14권12호
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    • pp.7221-7227
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    • 2013
  • Background: Fascin, an actin-bundling protein forming actin bundles including filopodia and stress fibers, is overexpressed in multiple human epithelial cancers including esophageal squamous cell carcinoma (ESCC). Previously we conducted a microarray experiment to analyze fascin knockdown by RNAi in ESCC. Method: In this study, the differentially expressed genes from mRNA expression profilomg of fascin knockdown were analyzed by multiple bioinformatics methods for a comprehensive understanding of the role of fascin. Results: Gene Ontology enrichment found terms associated with cytoskeleton organization, including cell adhesion, actin filament binding and actin cytoskeleton, which might be related to fascin function. Except GO categories, the differentially expressed genes were annotated by 45 functional categories from the Functional Annotation Chart of DAVID. Subpathway analysis showed thirty-nine pathways were disturbed by the differentially expressed genes, providing more detailed information than traditional pathway enrichment analysis. Two subpathways derivated from regulation of the actin cytoskeleton were shown. Promoter analysis results indicated distinguishing sequence patterns and transcription factors in response to the co-expression of downregulated or upregulated differentially expressed genes. MNB1A, c-ETS, GATA2 and Prrx2 potentially regulate the transcription of the downregulated gene set, while Arnt-Ahr, ZNF42, Ubx and TCF11-MafG might co-regulate the upregulated genes. Conclusions: This multiple bioinformatic analysis helps provide a comprehensive understanding of the roles of fascin after its knockdown in ESCC.

Relationship Between Nutrient Intake and Bone Mineral Density in 20∼30 Year-old Korean Women

  • Shin, Yoon-Jin;Kwun, In-Sook;Woon, Young-Jun;Kim, Yang-Ha
    • Preventive Nutrition and Food Science
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    • 제14권3호
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    • pp.208-213
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    • 2009
  • The achievement of maximal peak bone mineral density (BMD) in early life is one of the most important strategies for the prevention of osteoporosis, which is affected by nutritional status. However, it has been reported that young Korean women do not consume the optimal levels of nutrients because of the frequent practice of body weight reduction. Therefore, this study was conducted to investigate the relationship between nutrient intakes and BMD in young Korean women. Bone mineral density was measured at the lumbar spine by dual-energy X-ray absorptiometry. Information on health status, lifestyle and physical activity was obtained by questionnaire. Dietary intake was ascertained from a 3-day dietary record. The study sample included 112 Korean women aged 20$\sim$39 yr. In accordance with the energy intake of subjects, individuals who had an energy intake that was greater than 80% of the Korean Dietary Reference Intake (KDRI) were assigned to the control group (Control), while those who had an energy intake lower than 80% of the KDRI were assigned to the low intake group (LI). The intake of all nutrients in the LI group was significantly lower than that of the Control. Control subjects also showed nutrient intakes higher than the KDRI, except for Ca and folate. However, LI subjects showed intakes of energy, fiber, Ca, Fe, K, Zn, vitamin A, vitamin B1, vitamin B2 and folate that were lower than the KDRI. The BMD of the lumbar spine in LI subjects was significantly lower than that of the Control subjects. These results suggested that lower nutrient intake has a negative impact on BMD in young women.

RSM 법에 의한Li2O-Al2O3-SiO2 (LAS) 유리의 소결 거동과 결정화에 대한 연구 (A Study of Sintering Behavior and Crystallization in Li2O-Al2O3-SiO2 (LAS) Glass System by RSM)

  • 이규호;김영석;정영준;김태호;서진호;류봉기
    • 한국세라믹학회지
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    • 제44권8호
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    • pp.451-456
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    • 2007
  • This paper presents results and observations obtained from a study of sintering behavior and crystallization in $Li_2O-Al_2O_3-SiO_2$ (LAS) Glass by screen printing method. The variable experimental conditions were determined carefully by Thermal-Mechanical Analyzer (TMA), Differential Thermal Analyzer (DTA) for setting the optimum transparent sintering conditions in LAS glass system, $10.5Li_2O-14.7Al_2O_3-58.1SiO_2-16.7B_2O_3(wt%)$, such as glass-ceramics which usually have low crystallization temperatures. Crystallization glasses generated during sintering was observed from diffraction patterns by X-Ray Diffraction (XRD), transmittance by UV-Vis spectrometer. Finally, the optimum sintering condition of LAS glass and the relation between factors and results in several sintering conditions were given by using Response Surface Methodology (RSM). From this study, we confirmed that crystallization interrupted densification during glass powder sintering. Furthermore, we observed that main effect of factors in glass powder sintering with concurrent crystallization depended on experimental conditions from main effects plot by MINTAB-14.

Ti:LiN$bO_3$ 광변조기 소자의 패키징 및 전기.광학적 특성 (The study of the packaging for Ti:LiN$bO_3$optical modulator device and its electrical and optical characteristics)

  • 윤형도;김성구;이한영;윤대원
    • 전자공학회논문지D
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    • 제35D권6호
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    • pp.72-78
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    • 1998
  • Ti:LiNbO$_3$ 광도파로위에 CPW 전극 구조를한 광변조기 내부칩을 제작한 후 일련공정에 따라 패키징 작업을 하였고 소자의 전기적특성과 광학적특성을 측정하였다. 광변조기 패키징을 위하여 페룰, 보조용 LN블럭 및 글래스, 진동 및 흡수용패드, 알루미나피더의 부분품을 사용하였으며 피그테일링, Au 와이어본딩, 에폭싱, SMA커넥팅, 실링 작업을 수행하였다. 전기적 특성에서 S/sub 21/은 -3 dB 점에서 9.8GHz의 값을, S/sub 11/은 14.4 GHz 대에서 -8.9 dB 값을 나타내었다. 광학적 특성은 제작된 광도파로가 1550nm 파장대에서 단일모드를 만족하였고, 패키지후 소자의 삽입손실은 실온에서 4.3 dB 이였으며, 소자를 온도감압챔버에 넣은후 5∼45℃까지 온도변화를 주었을 때 4.3∼6.4 dB의 삽입손실을 보였다. E-O bandwidth 응답은 3dB점에서 7.8GHz를 나타내어 10Gbps급 광통신시스템에 응용할수 있음을 확인하였다.

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$Na_2O$-CaO-$SiO_2$ 계 유리의 내화학적 성질 향상에 관한 연구 (A Study on Improvement of Chemical Durability in the $Na_2O$-CaO-$SiO_2$ System Glass)

  • 김종옥;박원규;임대영;김문기
    • 자연과학논문집
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    • 제8권2호
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    • pp.111-118
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    • 1996
  • $Na_2O$-CaO-$SiO_2$ 계 유리의 화학적 내구성을 향상시키면서 작업점도의 변화를 최소화 하기 위하여, 기본 조성 유리를 선정한 후, 이 조성에 $B_2O_3$, ZnO 성분의 첨가량을 변화시키고 $Na_2O$, $Al_2O_3$, $Li_2O$ 성분을 변화시켜가면서 각 성분이 물성에 미치는 영향을 조사하여 최적 조성비를 얻는 것을 목적으로 하였다. 본 실험결과 $Na_2O$-CaO-$SiO_2$계 유리에서 연화점 변화를 최소화하고 화학적내구성을 극대화 시키는 최적조성(wt%)은 다음과 같았다.$B_2O_3$:3.36%, ZnO:2.88%, $Na_2O$:9.93%, $Al_2O_3$, $Li_2O$:0.19%, $SiO_2$:70.56%, CaO:11.22%, $K_2O$:0.14%

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화강토 지반 절취사면의 풍화특성에 관한 연구 (A Study of Characteristics on Weathering for Decomposed Granite Soils in Cutting Slope)

  • 이송;김주현
    • 한국철도학회:학술대회논문집
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    • 한국철도학회 2001년도 춘계학술대회 논문집
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    • pp.451-458
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    • 2001
  • The purpose of this study was to evaluate shear parameters on cutting slope of weathered granite soils by using small dynamic cone penetration test on the very moment of its cutting. The results were : On the relations among N$\_$c/, Li, and CEC, the condition of Li>6%, CEC>14(meq/100g) corresponds to that of N$\_$c/ values of 2∼30, and 3<CEC<14(meq/100g) to N$\_$c/=30∼50. Comparing the smallest penetration depth from two small dynamic cone penetration tests done at 5m below from the top of the slope on April 15th, October 31t. there was a l0cm difference. So we could find out the degree of weathering on the slope. And dividing the difference by 190 days (the whole testing time), we could know it's being weathered 0.052mm each day. The more N. value increases, the more shear parameters(internal friction angle ; $\phi$, cohesion : c) increase at a standard pressure($\sigma$>32㎪). So the condition of N$\_$c/=2∼50 corresponds to that of $\phi$=27∼50, c=12∼49㎪. From the above testing results, the N$\_$c/ values more correspond to $\phi$ values than c values. In conclusion, this study suggests that on small dynamic cone penetration test a penetration boundary line of 5 centimeters is decided at around Li=4%, CEC=3(meq/100g) which is classified as a strong weathering soil. It also shows that as Li increases CEC increases as well, while N$\_$c/ decreases.

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A promising new piezoelectric material -Langasite and its related compounds-

  • Kawanaka, Hiroyuki;Takeda, Hiroaki;Shimamura, Kiyoshi;Onozato, Norio;Fukuda, Tsuguo
    • 한국결정성장학회:학술대회논문집
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    • 한국결정성장학회 1997년도 Proceedings of the 12th KACG Technical Meeting and the 4th Korea-Japan EMGS (Electronic Materials Growth Symposium)
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    • pp.145-145
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    • 1997
  • Recent progress of electric technology requires new piezoelectric crystals having superior properties such as zero temperature coefficients and large electromechanical coupling factors. We have developed a series of new leading chandidates, La$_3$Ga5SiO14(langasite, LGS), La3Nb0.5Ga5.5O14(LNG), La3Ta0.5O14(LTG), to satisfy those requirements. High quality LGS, LNG and LTG single crystals, with dimensions of 2 inches in diameter, were successfully grown by the Czochralski method at a pulling rate of 1mm/h. Since no variation of chemical composition was observed when whole melt in a crucible was crystallized, congruency of these compositions was confirmed. Physical constants such as elastic constants, dielectric constants and piezoelectric constants were measured. Filters and oscillators made of grown LGS, LNG and LTG single crystals showed superior properties such as three times wider passband than that of quartz, low insertion loss and easy processing, Langasite family crystals were shown to be superior materials to other known materials such as quartz, LiTaO$_3$, $\alpha$-AlPO$_4$ and Li$_2$B$_4$O7.

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Sol-Gel 법에 의한 $Li_2O-Al_2O_3-TiO_2-SiO_2$ 계 다공성 결정화 유리의 제조 : (II) Sol-Gel 법에 의해 제조된 $Li_2O-Al_2O_3-TiO_2-SiO_2$ 계 괴상겔의 결정화 (Preparation of Glass-Ceramics in $Li_2O-Al_2O_3-TiO_2-SiO_2$ System by Sol-Gel Technique : (II) Crystallization of $Li_2O-Al_2O_3-TiO_2-SiO_2$ Monolithic Gel Prepared by Sol-Gel Method)

  • 조훈성;양중식
    • 한국세라믹학회지
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    • 제32권4호
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    • pp.507-515
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    • 1995
  • The monolithic dry gels of the Li2O-Al2O3-TiO2-SiO2 system were prepared by the sol-gel technique using metal alkoxides as starting materials to obtain monolithic glass-ceramics at low temperature without melting. Activation energy for the crystal growth of the gel with 6.05% TiO2, nucleating ageng, for the preparation of Li2O-Al2O3-TiO2-SiO2 system glass-ceramic was 101.14kcal/mol. As a result of the analysis of DTA & XRD, it was confirmed that the crytallization of Li2O-Al2O3-TiO2-SiO2 system glass-ceramic was the most efficient when 6.05% TiO2, nucleating agent, was added. $\beta$-eucryptite solid solution crystals and $\beta$-spodumene solid solution crystals were detected in the sample heat treated above 85$0^{\circ}C$. The sintered gel heat treated at 85$0^{\circ}C$ had the specific surface area of 185$m^2$/g, the pore volume of 0.19cc/g and the average pore radius of 20.8$\AA$. This shows that the sintered gel is also comparatively porous material. In temperature range of 25~85$0^{\circ}C$ thermal expansion coefficient of the specimen which was crystallized for 10hrs at 85$0^{\circ}C$ was 6.7$\times$10-7/$^{\circ}C$, which indicated that the crystallized specimen was turned out to be the glass-ceramic with low thermal expansion.

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Anti-wear performance and life evaluation of wheel bearing type greases

  • Kim Jung-Young;Chung Keun-Wo;Kim Young-Wun;Jo Won-Oh
    • 한국윤활학회:학술대회논문집
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    • 한국윤활학회 2004년도 학술대회지
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    • pp.111-116
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    • 2004
  • Li-complex and urea type greases (each 10 species) which were furnished by Chang-Am LS, analyzed anti-wear performance into fretting wear tester & four-bail wear tester. from the results of fretting wear test, the wear volume of Li-complex greases are $4.6\~8.9mg\;and\;8.3\~14.4mg$ with the test of urea greases. The anti-wear performance for 4-ball wear test of greases produced results around 0.5mm at the value of WSD. The grease life performance were evaluated by SKF-ROF Grease Tester and wheel bearing life tester. From the results of SKF-ROF tester, the life performance evaluated by whole working time produced results $50\~300hr$ with the Li-complex greases and 100-1000hr with the urea greases. That is to say, in spite of severe condition at the higher of $10^{\circ}C$ reaction temp, the life performance with Urea type greases are much superior to Li-complex type greases. Prior to wheel bearing life tester, the grease selected performance evaluation(=anti-wear test) are tested by wheel bearing tester. In this results, we can confirm results those are similar with SKF-ROF tester. In this study, we can draw two major conclusions, one is that Li-complex greases are superior to urea greases with anti-wear properties and the other is that urea greases are much superior to Li-complex greases with life performance.

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