• Journal of the Korean GEO-environmental Society
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• v.5 no.1
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• pp.27-34
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• 2004

The reclaimed waste layer in a completed refuse small landfill site was stabilized by JSP(Jumbo Special Pattern System) method. There were some variations of landfill gases(LFGs) after the stabilization. This study investigated the landfill gases emitted from a open dumping landfill site. We measured concentration of landfill gases before and after the construction, and 28 months later. As a result, the concentrations of $H_2S$ and $NH_3$ gases before the construction were 123.51ppm and 171.54ppm, respectively. These values were higher than TWA(Time Weighted Average) values. But the concentrations of $H_2S$ and $NH_3$ gases after the construction were 55.59ppm and 20.51ppm, and they also decreased 9.04ppm and 11.82ppm in 28 months. $CH_4$ and other landfill gases after the construction were little or a little detected in the landfill site. Hence we found out that concentrations or classes of landfill gases causing some problems extremely decreased by way of the stabilization.

• Journal of the Korean GEO-environmental Society
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• v.6 no.4
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• pp.27-35
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• 2005

A case study of the assessment for environmental stabilization in open dumping landfill site was carried out physical composition, total solid, moisture, and landfill gas(LFG) analysis in landfill site. The result of physical ratio were represented combustibles 23.64% and incombustibles 76.36%, TS 77.69%, VS 74.24%, FS 25.75%. The biodegradable organic matters were almost degraded and the result of the landfill gas showed that the $CH_4$ gas were measured as 4.5%. As the result of the assessment on the open dumping landfill it appears that this landfill is stabled for the maturation phase and formation $CO_2$ concentration lower than 15%.

• Transactions of the Korean hydrogen and new energy society
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• v.27 no.5
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• pp.554-561
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• 2016

Depending on the Bio-gas sources, main component gases of $CH_4$ and $CO_2$ are shown to be variously present in amounts. For the anaerobic digester, The concentration of $CH_4$ and $CO_2$ in the gases are 60~70 and 30~35 vol%. For the landfill gas, $CH_4$ and $CO_2$ are 40~60 and 40~60 vol%. For the food wastes, $CH_4$ and $CO_2$ are 60~80 and 20~40 vol%, respectively. In this study, maximum conversion rates of $CO_2$ were obtained from the variety of concentrations of $CH_4$ and $CO_2$ by the catalysts of reforming reactions. Moreover, in order to get maximum producing amount of synthetic gas, experimental studies were performed to optimize the reaction variables. On the basis of $CH_4$, 243 ml, R [$CH_4/(O2+CO_2)$] value were varied from 0.8 to 1.35, in the study of $CH_4$ and $CO_2$ reforming reactions. It was shown that the optimal results were obtained for 1.35 of R value. And also, at $850^{\circ}C$ and 1 atm, the production rate of synthetic gas was 90% and the conversion rates of $CH_4$ and $CO_2$ were higher than 99% and 90%, respectively.

• Korean Journal of Organic Agriculture
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• v.28 no.4
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• pp.535-553
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• 2020

In this study, the characteristics of the waste sector CDM project were analyzed through cluster analysis of the waste sector CDM project and the analysis of the CDM investment cost in waste sector using CDM project data registered with UNFCCC since 2008 when EU ETS phase 2 began. As of September 2020, 772 cases of CDM projects in waste disposal and disposal are registered. Biogas technology is the largest, followed by livestock manure processing and biomass production technology. The results of the cluster analysis are summarized as follows: First, on average, projects utilizing AWMS technology are small in size and relatively low in investment costs. This is judged to be relatively low investment costs due to previously attracted foreign investment capital. Second, the average investment cost of CDM projects considered along with waste (No.13), the energy industry (No.1) and agriculture (No.15) was higher than those involving only waste. The analysis of the factors determining the investment cost of the waste sector CDM project showed that, as with cluster analysis, the AWMS technology, which is a livestock manure treatment technology, was lower in the investment cost than those that use other technologies. As a result of multiple regression analysis, the investment cost of the CDM project was analyzed lower in the order of biomass, AWMS, LFG and biogas. Also, the higher the investment cost for CDM projects linked to waste, energy and agriculture, and the better the investment environment, the higher the investment cost. Although no statistical feasibility was obtained, the larger the annual emission reduction, the lower the CDM investment cost.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.32 no.6B
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• pp.399-406
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• 2012

The objective of this research is to develop greenhouse gas generation models and estimation method of their parameters for solid waste landfills. Two models obtained by differentiating the Modified Gompertz and Logistic models were employed to evaluate two parameters of a first-order decay model, methane generation potential ($L_0$) and methane generation rate constant (k). The parameters were determined by the statistical comparison of predicted gas generation rate data using the two models and actual landfill gas collection data. The values of r-square obtained from regression analysis between two data showed that one model by differentiating the Modified Gompetz was 0.92 and the other model by differentiating the Logistic was 0.94. From this result, the estimation methods showed that $L_0$ and k values can be determined by regression analysis if landfill gas collection data are available. Also, new models based on two models obtained by differentiating the Modified Gompertz and Logistic models were developed to predict greenhouse gas generation from solid waste landfills that actual landfill generation data could not be available. They showed better prediction than LandGEM model. Frequency distribution of the ratio of Qcs (LFG collection system) to Q (prediction value) was used to evaluate the accuracy of the models. The new models showed higher accuracy than LandGEM model. Thus, it is concluded that the models developed in this research are suitable for the prediction of greenhouse gas generation from solid waste landfills.

• Journal of Energy Engineering
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• v.23 no.3
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• pp.125-131
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• 2014

In order to increase landfill gas (LFG) production with food waste leachate, this study was confirmed to be acidogenetic conditions for landfill site injection. Thereby, it was conducted for acidogenetic treatments to determine the decrease in viscosity and VFA production. After acidogenesis treatments, solubility of food waste leachate increased approximately 15%, and as a result, UASB and CSTR were similar by reactor type using the change of retention time. Based on the result of the change in viscosity by reactor type, efficiency of UASB showed approximately 11.38% of higher decrease in viscosity as $76.95{\pm}3.27%$ vs. CSTR. Also, VFA production showed the higher increase of 2.01 times (UASB) and 1.76 times (CSTR) respectively at the point of increasing retention time from 3 to 5 days. From the above results, efficiency of UASB in a reactor was relatively higher because large molecular lead to longer retention time than small molecular due to having screen effect in the fixed media.

• Journal of the Korea Organic Resources Recycling Association
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• v.14 no.2
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• pp.63-70
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• 2006

The purpose of this study was to develop the stability index of landfill sites to assess it's degree of stability. In order to develop the stability index, field data including leachate qualities, Landfill gas (LFG) composition and element composition of wastes from 50 closed landfills were collected. Three parameters-BOD/CODcr among leachate quality parameters, $CH_4$ among landfill gases, and C/N ratio from wastes-were found to be the best parameters for measuring the stability of landfill sites. The trend line of these parameters were used to Also, $CH_4$ from landfill gases and C/N ratio from wastes were found to be the best parameters. The trend lines of these parameters were used to develop the stability index of landfill sites. The equation for the index was as following; $I_{LS}=S_L+S_G+S_W$ $S_L=-\{4.892+16.587{\cdot}ln[BOD/COD_{Cr]\}$ $S_G=53.872-12.782{\cdot}ln[CH_4]$ $S_W=79.382-20.013{\cdot}ln[C/N]$ (The maximum score for $S_L$, $S_G$, and $S_W$ was 33.3.) where, $I_{LS}$ : The stability index of the landfill $S_L$ : The stability score of the leachate $S_G$ : The stability score of the landfill gas $S_W$ : The stability score of the waste.

• Journal of the Korea Organic Resources Recycling Association
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• v.19 no.3
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• pp.44-53
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• 2011

Siloxane, organo-silicon compound, is used in the various forms of products such as cosmetics and detergents due to its quality physical chemistry attributes. Siloxane included in landfill gas which is caused in the process of decomposing of such products after landfill has imposed negative impacts on the operation of landfill gas utility facilities. The objective of this study was to investigate the siloxane production characteristics depending on the features of various landfill site in Korea so that the analysis was made on the landfilling age and landfill waste by in terms of its concentration, structure and composition. As for the concentration of siloxane depending on time passage, 12 landfill sites were reviewed by landfilling age. As for production attributes change of siloxane by landfill wastes, the source of wastes, physical production ration and siloxane concentration were compared in 6 landfills. The average concentration of total-siloxane within LFG is $6.75mg/m^3$ and cyclic-siloxane out of it occupies over 93%. By element, D4 and D5 in order take the highest proportion regardless of total-siloxane concentration and landfilling age. Even though this study is not able to verify the different impact of each kind of wastes on the generation of siloxane, it is confirmed that total-siloxane and cyclic-siloxane decrease in line with the increase of landfilling age as it does in the first order decay model for landfill gas.

• Korean Chemical Engineering Research
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• v.57 no.6
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• pp.774-780
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• 2019

An efficient Pd-coated $La_{0.1}Sr_{0.9}Co_{0.2}Fe_{0.8}O_{3-{\delta}}$ (LSCF-1928) catalyst for total oxidation of methane under landfill gas at low tmeperature has been developed. Synergism was observed between Pd coating and LSCF-1928 substrate. When Pd coating on LSCF-1928, we used electroless plating method and conformed characteristic of catalyst through TPR(Temperature Programmed Reduction) analysis, XRD(X-ray Diffraction) analysis, SEM(Scanning Electron Microscope). The results demonstrated that the Pd coated LSCF-1928 catalysts showed higher performance than non-Pd LSCF-1928. Pd coated LSCF-1928 had low total oxidation temperature of methane (< $475^{\circ}C$) which is lower than total oxidation temperature of methane about non-Pd LSCF-1928 catalysts (= $475^{\circ}C$). Also, $O_2$ conversion rate was higher than non-Pd LSCF-1928 at same temperature.

• Journal of the Korean Institute of Gas
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• v.25 no.4
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• pp.36-42
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• 2021

When the landfill gas generated at the landfill site is released into the atmosphere, methane gas with a high global warming potential is emitted, which adversely affects climate change. When methane contained in landfill gas is used as fuel for internal combustion engines and burned to generate electricity, it is emitted into the atmosphere in the form of carbon dioxide, which can contribute to lowering the global warming potential. Therefore, in order to use the landfill gas as fuel for power generation using an internal combustion engine, it is important to increase the thermal efficiency of the engine. Thus, it is necessary to use a fuel supply system in which gas is injected using an electronically controlled injector at an intake port for each cylinder rather than a fuel supply technology using the conventional mixer technology. In order to use the electronically controlled gas injection method, it is important to accurately measure the mass flow rate according to the conditions of using landfill gas. For this, a study was conducted to measure the injection amount and calculate them in order for the intake port gas injection of landfill gas.