• Title/Summary/Keyword: LCO

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Retrieval methodology for similar NPP LCO cases based on domain specific NLP

  • No Kyu Seong ;Jae Hee Lee ;Jong Beom Lee;Poong Hyun Seong
    • Nuclear Engineering and Technology
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    • v.55 no.2
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    • pp.421-431
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    • 2023
  • Nuclear power plants (NPPs) have technical specifications (Tech Specs) to ensure that the equipment and key operating parameters necessary for the safe operation of the power plant are maintained within limiting conditions for operation (LCO) determined by a safety analysis. The LCO of Tech Specs that identify the lowest functional capability of equipment required for safe operation for a facility must be complied for the safe operation of NPP. There have been previous studies to aid in compliance with LCO relevant to rule-based expert systems; however, there is an obvious limit to expert systems for implementing the rules for many situations related to LCO. Therefore, in this study, we present a retrieval methodology for similar LCO cases in determining whether LCO is met or not met. To reflect the natural language processing of NPP features, a domain dictionary was built, and the optimal term frequency-inverse document frequency variant was selected. The retrieval performance was improved by adding a Boolean retrieval model based on terms related to the LCO in addition to the vector space model. The developed domain dictionary and retrieval methodology are expected to be exceedingly useful in determining whether LCO is met.

Separation and Purification of 2,6-dimethylnaphthalene in the Light Cycle Oil(I) -Concentration of a mixture of dimethylnaphthalene isomers in the light cycle oil- (접촉분해경유에 함유된 2,6-dimethylnaphthalene의 분리, 정제(I) -접촉분해경유에 함유된 dimethylnaphthalene이성체 혼합물의 농축-)

  • Kim, Su-Jin;Kim, Sang-Chai;Kawasaki, Junjiro
    • Applied Chemistry for Engineering
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    • v.7 no.1
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    • pp.162-170
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    • 1996
  • Light cycle Oil(LCO) contains 2,6-dimethylnaphthalene (2,6-DMNA) which is used as the basic material for high performance engineering plastics and liquid crystal polymer. This study was experimentally investigated to concentrate a mixture of dimethylnaphthalene(DMNA) isomers in the LCO by extraction-distillation combination as a pretreatment for separation and purification of 2,6-DMNA in the LCO. Furthermore, concentration of a mixture of DMNA isomers in the LCO compared between distillation and extraction-distillation combination. The recovery of aromatics in the LCO was performed by batch cocurrent multistage extraction with dimethylsulfoxide and water mixture as solvent. The concentration of naphthalene group(carbon number 10-12) in the extracted mixture is higher than that in the LCO. The yield for naphthalene group increased with decreasing carbon number. The yield for a mixture of DMNA isomers obtained in 5 equilibrium extration runs was about 65%. the separation of individual components with extractedmixture was tested by batch distillation. Futhermore, for recovery of a mixture of DMNA isomers of high concentration, distillate containing DMNA was distilled. As a result, a mixture of DMNA isomers with high concentration such as 60wt% was recovered. The extraction-distillation combination was more effective than the distillation to concentration a mixture of DMNA isomer in the LCO.

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Resistance Modulation of $\textrm{LaCoO}_{3}$ by Ferroelectric Field Effect in $\textrm{LaCoO}_{3}/\textrm{Pb(Zr,Ti)O}_{3}/\textrm{(La,Sr)CoO}_{3}$ Heterostructures ($\textrm{LaCoO}_{3}/\textrm{Pb(Zr,Ti)O}_{3}/\textrm{(La,Sr)CoO}_{3}$다층구조에서의 강유전체 전계효과에 의한 LaCoO$_{3}$의 전항변조)

  • Kim, Seon-Ung;Lee, Jae-Chan
    • Korean Journal of Materials Research
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    • v.7 no.12
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    • pp.1058-1062
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    • 1997
  • 강유전체 전계효과를 관찰하기 위해 LaCoO$_{3}$/Pb(Zr, Ti)O$_{3}$(La, Sr)CoO$_{3}$ 다층구조를 LcOo$_{3}$가 기판 위에 pulsed laser deposition(PLD)법으로 에피택셜하게 성장시켰다. 이러한 다층구조에서는 전도성 채널층으로 Si대신 반도성 LaCoO$_{3}$가 사용 되었다. LaCoO$_{3}$(LCO)의 비저항은 산소 분위기에 의하여 변화되었는데 특히 증착시 산소 분위기에 의존함을 보였다. LCO의 비저항은 0.1-100Ωcm범위에서 변화되었다. LCO층에 유도되는 강유전체 전계효과는 Pb(Zr, Ti)O$_{3}$(PZT)의 분극 상태에 따른 LCO의 저항 변화를 측정함으로써 관찰되었는데 1020$\AA$ 두께를 가진 LCO층에서는 4%의 저항 변화를 얻었으며 680$\AA$의 LCO에서는 9%의 증가된 저항 변화를 얻었다. DC 바이어스(-5V)를 가한 후에는 저항 변화가 45%까지 증가하였다. 이러한 결과는 적당한 비저항을 갖는 LCO를 사용한 LCO/PZT/LSCO다층구조가 강유전체 전계효과 트랜지스터로 사용될 수 있다는 가능성을 제시하고 있다.

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Accelerated Formation of Surface Films on the Degradation of LiCoO2 Cathode at High Temperature (표면 피막 형성이 LiCoO2 양극의 고온 열화에 미치는 영향)

  • Sung, Jong Hun;Hasan, Fuead;Yoo, Hyun Deog
    • Journal of the Korean Electrochemical Society
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    • v.23 no.3
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    • pp.57-65
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    • 2020
  • It is crucial to investigate the thermal degradation of lithium-ion batteries (LIBs) to understand the possible malfunction at high temperature. Herein, we investigated the effects of surface film formation on the thermal degradation of lithium cobalt oxide (LiCoO2, LCO) cathode that is one of representative cathode materials. Cycling test at 60℃ exhibited poorer cycleability compared with the cycling at 25℃. Cathodes after the initial 5 cycles at 60℃ (60-LCO) exhibited higher impedance compared to the cathode after initial 5 cycles at 25℃ (25-LCO), resulting in the lower rate capability upon subsequent cycling at 25℃, although the capacity values were similar at the lowest C-rate of 0.1C. In order to understand degradation of the LCO cathode at the high temperature, we analyzed the cathodes surface using X-ray photoelectron spectroscopy (XPS). Among various peaks, intensity of lithium hydroxide (LiOH) increased substantially after the operation at 60℃, and the C-C signal that represents the conductive agent was distinctly lower on 60-LCO compared to 25-LCO. These results pointed to an excessive formation of cathode-electrolyte interphase including LiOH at 60℃, leading to the increase in the resistance and the resultant degradation in the electrochemical performances.

An Analysis of the Limit Cycle Oscillation in Digital PID Controlled DC-DC Converters

  • Chang, Changyuan;Hong, Chao;Zhao, Xin;Wu, Cheng'en
    • Journal of Power Electronics
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    • v.17 no.3
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    • pp.686-694
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    • 2017
  • Due to the wide use of electronic products, digitally controlled DC-DC converters are attracting more and more attention in recent years. However, digital control strategies may introduce undesirable Limit Cycle Oscillation (LCO) due to quantization effects in the Analog-to-Digital Converter (ADC) and Digital Pulse Width Modulator (DPWM). This results in decreases in the quality of the output voltage and the efficiency of the system. Meanwhile, even if the resolution of the DPWM is finer than that of the ADC, LCO may still exist due to improper parameters of the digital compensator. In order to discover how LCO is generated, the state space averaging model is applied to derive equilibrium equations of a digital PID controlled DC-DC converter in this paper. Furthermore, the influences of the parameters of the digital PID compensator, and the resolutions of the ADC and DPWM on LCO are studied in detail. The amplitude together with the period of LCO as well as the corresponding PID parameters are obtained. Finally, MATLAB/Simulink simulations and FPGA verifications are carried out and no-LCO conditions are obtained.

Numerical Investigation on the Effect of Surface Tension Change of Liquefied $CO_2$ Droplets on their Ascending Speed (액화이산화탄소 유적의 수직 상승속도에 미치는 표면장력 변화의 영향에 대한 수치연구)

  • Cho, Yoon-Tae;Song, Mu-Seok
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.11 no.3
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    • pp.160-163
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    • 2008
  • $CO_2$ ocean sequestration is being considered as a way to earn a frame of time to change other industrial life pattern to overcome the global warming crisis. The method is to dilute the captured $CO_2$ into ocean by ejecting the liquefied $CO_2$ through nozzles. The main issue of such method is the effectiveness and safety, and in both problems the rising speed of those LCO2 droplet is the key parameter. In this paper, the rising speed of LCO2 droplets is numerically studied including the effect of the surfactant which can be residing along the density interface of the droplets. A front tracking method with a simple surface tension model is developed and the rising speed of the droplets is carefully investigated with varying the various parameters. It is demonstrated that the variable surface tension can change the deformation of the droplet, the flow near the interface, and the rising speed.

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Separation and Purification of 2,6-Dimethylnaphthalene Present in the Fraction of Light Cycle Oil by Crystallization Operation (결정화조작에 의한 접촉분해경유 유분에 함유된 2,6-디메틸나프탈렌의 분리·정제)

  • Kim, Su Jin
    • Applied Chemistry for Engineering
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    • v.29 no.6
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    • pp.799-804
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    • 2018
  • The separation and purification of 2,6-dimethylnaphthalene (2,6-DMN) present in the light cycle oil (LCO) fraction was investigated by a crystallization operation. Solute crystallization (SC) was performed using LCO fraction and iso-propyl alcohol as a raw material and a SC solvent, respectively. Increasing the operation temperature and volume ratio of the solvent to the raw material (S/F) resulted in improving the purity of 2,6-DMN, whereas the yield decreased. As a result of the crystallization operation in three steps containing the SC using LCO fraction (13.9% 2,6-DMN) and isopropyl alcohol, the re-crystallization 1 (RC 1) using the crystals recovered by SC and methyl acetate, and RC 2 using the crystals recovered by RC 1 and methyl acetate, the crystal with 99.9% 2,6-DMN was recovered with 19.5% yield. Furthermore, the separation and purification process of 2,6-DMN present in the LCO fraction was reevaluated by using the experimental results obtained through each operations of SC, RC 1, and RC 2.

Analysis of a Passivation Layer for Full Switching of LCOS Panel (LCOS의 Full On을 위한 Passivation Layer 영향분석)

  • 강기형;이유진;송남철;김민석;황현하;조철식
    • Proceedings of the Optical Society of Korea Conference
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    • 2000.08a
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    • pp.230-231
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    • 2000
  • 동전만한 작은 크기의 화면을 원하는 크기로 확대해서 보여주는 micro-display는 부피가 작고 가벼운 장점으로 인해 HMD(Head Mount Display)에 적용되었으나, 최근들어 TV나 monitor등에 확대 적용되고 있다. 이러한 micro-display중 LCOS는 최근 가장 활발히 연구되고 있는 micro-display이다$^{(1).(4)}$ . LCOS는 Liquid Crystal On Silicon의 약어로 반도체 제조에 사용되는 silicon wafer위에 액정소자를 얹어 제작하는 것이다. LCOS는 액정화면을 구동하기 위한 silicon back-plate의 반도체 기술, 화상을 표시하는 액정소자 기술, 표시된 화면을 사용자가 볼 수 있도록 투사하는 조명/투사광학 기술등이 집적화된 display이다. LCOS의 최적 특성을 위해서는 각 부분의 성능 최적화뿐만 아니라 각 기술들의 상호 연결 및 접목이 중요하다. (중략)

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Spray Characteristics of a Coal Slurry with Liquid Carbon Dioxide (고압 저등급탄-이산화탄소 슬러리 분무특성에 관한 연구)

  • KIM, CHANGYEON;KIM, HAKDUCK;SONG, JUHUN
    • Transactions of the Korean hydrogen and new energy society
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    • v.26 no.4
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    • pp.357-362
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    • 2015
  • There is potential method to utilize the liquid carbon dioxide ($LCO_2$) in coal gasification plants. The $LCO_2$ could be used to effectively transport coal particles instead of conventional carrier such as liquid water ($H_2O$) particularly in wet-fed gasifier. However, there is a lack of fundamental study on the atomization behavior of $LCO_2$ coal slurry under high pressure condition. In this study, the flashing spray characteristics of a coal mixture with $LCO_2$ was examined during a throttling process by using a flow visualization system. The spray of coal water slurry which is in the Rayleigh-type break up mode was significantly different. This difference indicates that the coal water slurry did not effectively transport the coal, as compared to $LCO_2$ coal slurry.

Lithium Lanthanum Titanate Solid Electrolyte for All-Solid-State Lithium Microbattery (전고상박막전지를 위한 (Li,La)TiO3 고체전해질의 제조와 특성)

  • 안준구;윤순길
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.17 no.9
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    • pp.930-935
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    • 2004
  • $({Li}_{0.5}0{La}_{0.5}){TiO}_3$ (LLTO) solid electrolyte was grown on LiCo{O}_2 (LCO) cathode films deposited on $Pt/Ti{O}-2/Si{O}_2/Si$ substrate using pulsed laser deposition for all-solid-state lithium microbattery. LLTO solid electrolyte exhibits an amorphous phase at various deposition temperatures. LLTO films deposited at 10$0^{\circ}C$ showed a clear interrace without any chemical reaction with LCO, and showed an initial discharge capacity of 50 $\mu$Ah/cm$^2$-$\mu$m and capacity retention of 90 % after 100 cycles with Li anode in 1mol$ LiCl{O}_4$ in propylene carbonate (PC). The increase of capacity retention in LLTO/LCO structure than LCO itself was attributed to the structural stability of LCO cathode films by the stacked LLTO. The cells of LLTO/LCO with LLTO grown at $100^{\circ}C$ showed a good cyclic property of 63.6 % after 300 cycles. An amorphous LLTO solid electrolyte is possible for application to solid electrolyte for all-solid-state lithium microbattery.