• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2001년도 추계학술대회 논문집 Vol.14 No.1
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• pp.117-120
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• 2001

A new photoalignment material PFCPMI, poly[4-(fluorocinnamate)phenylmaleimide], was synthesized and the nematic liquid crystal (NLC) aligning capabilities on the photopolymer surface. The NLC pretilt angle generated by non-UV filter method on the PFCPMI surface was higher than that of the UV filter method. A good LC alignment by non-UV filter method was observed at $150^{\circ}C$ of annealing temperature. However, the alignment defect of the NLC by UV filter method was measured above $150^{\circ}C$ of annealing temperature. Consequently, the high pretilt angle and the good LC alignment in NLC using non-UV filter method can be acheived.

• 한국전기전자재료학회논문지
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• 제11권10호
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• pp.878-884
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• 1998

We have investigated that the monodomain alignment of nematic liquid crystal (NLC) is obtained with polarized ultraviolet(PUV) light irradiation on polyimide (PI) surface. The LC alignment capability increases with increasing the UV light irradiation time. The polarized UV light irradiation on oblique angle of 60。 irradiated on PI surface rotated by 90。 at 10 min. after being normally irradiated on PI surface at 30 min., the generated pretilt angle of NLC is about 2.5。. The pretilt angle of NLC is attributed to the interaction between the LC molecules and the asymmetric triangular structure of polymer surface due to photo-depolymerization of polymer with the oblique UV light on PI surface. The voltage -transmittance and response time characteristics of photo-aligned twisted nematic (TN)-LCD with UV light irradiation time 60 min. were almost same in comparison with the rubbing-treated TN-LCD.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2001년도 추계학술대회 논문집
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• pp.117-120
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• 2001

A new photoalignment material PFCPMI, poly [4-(fluorocinnamate) phenylmaleimide], was synthesized and the nematic liquid crystal (NLC) aligning capabilities on the photopolymer surface. The NLC pretilt angle generated by non-UV filter method on the PFCPMI surface was higher than that of the UV filter method. A good LC alignment by non-UV filter method was observed at 150\`c of annealing temperature. However, the alignment defect of the NLC by UV filter method was measured above 150$^{\circ}C$ of annealing temperature. Consequently, the high pretilt angle and the good LC alignment in NLC using non-UV filter method can be achieved.

• 한국전기전자재료학회논문지
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• 제15권5호
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• pp.423-428
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• 2002

The photoalignment material PFCPMI, poly[4-(fluorocinnamate)phenylmaleimide], was synthesized and the nematic liquid crystal(NLC) aligning capabilities on the photopolymer surface. The NLC pretilt angle geneated by non-UV filter method on the PFCPMI surface was higher than that of the UV filter method. A good LC alignment by non-UV filter method was observed at $150^{\circ}C$ of annealing temperature. However, the alignment defect of the NLC by UV filter method was measured above $150^{\circ}C$ of annealing temperatue. Consequently, the high pretilt angle and the good LC alignment in NLC using non-UV filter method can be acheived.

• 한국전기전자재료학회논문지
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• 제13권7호
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• pp.625-629
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• 2000

We synthesized a new copoly (PM4Ch-ChMA) copoly(poly(4-methacryloyloxy) chalcone-cholesteryl methacrylate) having chalconyl and cholesteryl moiety for homeotropic liquid crystal(LC) alignment. Pretilt angles of nematic(N) LC generated by linearly polarized UV exposure on the copolymer surfaces were investigated. Good thermal stabilities of the synthesized copolymer were obtained by TGA (Thermogravimetric Analysis) measurement. Pretilt angles of the NLC decreased with increasing UV exposure time on the copolymer surfaces. We consider that the pretilt angle of the NLC is attributed to increased chalcone by increased UV exposure time. High pretilt angle of the NLC is attributed to increased chalcone by increased UV exposure time. High pretilt angle of 81$^{\circ}$was observed after the UV exposure for 3 min.

• 환경위생공학
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• 제22권3호
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• pp.89-96
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• 2007

To determine 8 anti-impotence drug/drug-like compounds such as sildenafil, vardenafil, tadalafil, homosildenafil, hydroxyhomosildenafil, aminotadalafil, pseudovardenafil and hongdenafil in foods, simultaneously, high performance liquid chromatography(HPLC) and liquid chromatography-mass spectrometry (LC/MS) were used. The HPLC/UV analysis was performed on a column of capcellpak $C_{18}$ with 0.1% sodium-1-hexansulfonate in 0.2M ammonium formate/acetonitrile as a mobile phase. Mass spectra of the compounds by LC/MS were investigated with SCAN mode(Mass range and Fragment voltage) and SIM(Selected Ion Monitoring) mode (Ion target and Fragment voltage). The results follow as; 1. The HPLC/UV analysis was detected from 5 out of 63 samples. The content of sildenafil was in the range of 32.80 ppm ${\sim}$ 60.13 ppm from 4 out of 5 samples. The contents of sildenafil, vardenafil, homosildenafil were in the range 47.14 ppm from 1 out of 5 samples. 2. The conformed result of LC/MS was equal of detected from 5 out of 63 samples in HPLC/UV analysis. An easily available, simultaneous determination of 8 standards in adulterated health related foods was established by using a combination of LC/MS methods.

• 폴리머
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• 제28권4호
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• pp.298-304
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• 2004

유전율 이방성이 음인 액정과 UV 경화용 단량체를 사용해 초기에 투명한 상태인 고분자 분산형 액정 (PDLC)셀을 제작하였고 그 셀의 전기 광학 특성을 연구하였다. 액정과 단량체의 비율이 70/30 wt%, 2$0^{\circ}C$의 노광 온도, 198㎽/$\textrm{cm}^2$ 의 노광 세기에서 만들어진 셀이 명암 대비율이 가장 우수하였다. 이 조건에서 만들어진 초기에 투명한 상태를 나타내는 고분자 분산형 액정 셀은 종래 PDLC 셀과 달리 액정들이 초기에 수직 배향막에 의해 기판에 수직으로 서게 되고 노광에 의해 중합된 고분자는 액정의 배열에 영향을 크게 미치지 않아 전압 인가 전에는 입사 된 빛이 통과하게 된다. 전압인가 시에는 전기장에 액정들이 기판에 수직 방향으로 누우면서 고분자와 액정의 굴절을 차이를 만들어내고 이는 입사된 빛을 산란시킨다. 또한 이러한 초기에 투명한 상태를 나타내는 PDLC 셀은 기존의 초기에 산란을 일으키는 PDLC 셀보다 우수한 시야각 특성을 보여주었다.

• 한국인쇄학회지
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• 제14권1호
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• pp.89-114
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• 1996

Liquid crystal-polymer composite(LCPC) films consisting of a continuous LC phase embedded in a three-dimensional network of polymer matrix are formed by photopolymerization-induced phase separ on. The LCPC films are switched from a light-scattering stats to a highly transparent stats on the application of electric fields. Since the alignment of LC molecular determines the electro-optical properties of films, the requirement for good contrast is to generate the nematic phase at high concentration. On the other hand, the concentration of UV-curable monomer must be increased above some critical value to from the flexible matrix of unbounded polymer. The mixing ratio of LC and UV-curable monomer affects the electro-optical and viscoelastic properties of LCPD films in two opposing ways. By controlling the phase separation process, at an LC fraction of 0.7, the maximum performance of LCPC films has been achieved, the response time of which is 2ms on the application of electric fields.

• Journal of Information Display
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• 제12권2호
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• pp.101-107
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• 2011

To come up with a bistable liquid crystal (LC) device using unpolarized UV light, single-step laser patterning on a photoalignment layer using a photomask was proposed to achieve an equilibrium configuration of LC molecules in contact with a periodically patterned substrate. The patterns were formed by stripes of alternating random planar and homeotropic anchoring on a submicrometer scale in the order of $0.5{\mu}m$. Two possible configurations of bistable LC cells that can be obtained by combining a micropatterned surface formed with alternating random-planar- and homeotropic-alignment with planar- or homeotropic-alignment surfaces were proposed. The alignment properties of the two proposed models were investigated, along with the microscopic switching behavior of micropatterned nematic LC cells.

• Bulletin of the Korean Chemical Society
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• 제29권9호
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• pp.1847-1849
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• 2008