• Applied Chemistry for Engineering
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• v.30 no.2
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• pp.205-211
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• 2019

Over the past several decades, the polymer dispersed liquid crystal (PDLC) has received particular attention as a material for developing smart window due to their electro-optical switchable properties. In this study, PDLC cells were fabricated using acrylate monomers, namely 2-hydroxyethyl acrylate (2-HEA) and ethylene glycol phenyl ether acrylate (EGPA), and the effect of the monomer composition on their electro-optical properties was investigated. The monomer mixture with a low viscosity (~10 cps) was easily filled between indium tin oxide (ITO) glasses by capillary action at room temperature. PDLC cells prepared using the mixture ratio of 1 : 9 (2-HEA : EGPA) did not show a complete opaque state at a 0 V condition but exhibited unstable electro-optical properties under an electric field. As the LC composition increased in the reaction mixture for PDLC cell preparation, the $V_{th}$ (threshold voltage) and $V_{sat}$ (saturation voltage) values as well as contrast ratio (CR) increased. $V_{th}$ and $V_{sat}$ values also increased with the cell gap thickness. PDLC cells with a $20{\mu}m$ cell gap thickness exhibited higher CR than those with 10 and $40{\mu}m$ cell gap thicknesses. Particularly, PDLC cells prepared using the mixture ratio of 7 : 3 (2-HEA : EGPA) showed excellent electro-optical properties such as a low driving voltage and high contrast ratio.

• Journal of Technologic Dentistry
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• v.45 no.2
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• pp.31-38
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• 2023

Purpose: This in vitro study aimed to compare the trueness of 3-unit fixed dental provisional prostheses (FDPs) fabricated by three different additive manufacturing and subtractive manufacturing procedures. Methods: A reference model with a maxillary left second premolar and the second molar prepped and the first molar missing was scanned for the fabrication of 3-unit FDPs. An anatomically shaped 3-unit FDP was designed on computer-aided design software. 10 FDPs were fabricated by subtractive (MI group) and additive manufacturing (stereolithography: SL group, digital light processing: DL group, liquid crystal displays: LC group) methods, respectively (N=40). All FDPs were scanned and exported to the standard triangulated language file. A three-dimensional analysis program measured the discrepancy of the internal, margin, and pontic base area. As for the comparison among manufacturing procedures, the Kruskal-Wallis test and the Mann-Whitney test with Bonferroni correction were evaluated statistically. Results: Regarding the internal area, the root mean square (RMS) value of the 3-unit FDPs was the lowest in the MI group (31.79±6.39 ㎛) and the highest in the SL group (69.34±29.88 ㎛; p=0.001). In the marginal area, those of the 3-unit FDPs were the lowest in the LC group (25.39±4.36 ㎛) and the highest in the SL group (48.94±18.98 ㎛; p=0.001). In the pontic base area, those of the 3-unit FDPs were the lowest in the LC group (8.72±2.74 ㎛) and the highest in the DL group (20.75±2.03 ㎛; p=0.001). Conclusion: A statistically significant difference was observed in the RMS mean values of all the groups. However, in comparison to the subtractive manufacturing method, all measurement areas of 3-unit FDPs fabricated by three different additive manufacturing methods are within a clinically acceptable range.

• 한국정보디스플레이학회:학술대회논문집
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• 2004.08a
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• pp.831-833
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• 2004

A novel transflective-type LC mode with good display performance has been developed In order to drive both transmissive and reflective modes simultaneously without any modulation of gamma in a single-gap structure, we have introduced a new design concept in the reflective region, where the capacitance is separated into liquid crystal($C_{LC}$} and organic layer($C_{OL}$), playing a key role as a voltage divider in our cap-divided VA-mode. With this cap-divided method having both merits of simplifying process and good legibility, we have achieved good optical characteristics such as high contrast ratio and wide viewing angle in a single-gap homeotropic panel design.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.19 no.2
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• pp.185-188
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• 2006

We studied on the reverse twist near the pixel edge depending on the rubbing direction for the fringe field switching (FFS) mode. Liquid crystal (LC) dynamic and the transmittance near the pixel edge, where the various field directions are generated, depend on the initial rubbing direction because the position of reverse twist is decided by the angle between the electric direction and the LC director at a bias voltage. For example, when the rubbing angle is $7^{\circ}$, the reverse twist appears on the bottom position of the right sharp comer of the pixel edge so that the reverse region exists far away from main active region. But, when the rubbing angle is $-7^{\circ}$, the reverse twist appears on the top position of the right sharp comer of the pixel edge, resulting that the region becomes more close to the main active area and the unstable disclination lines (DLs) easily intrude into the active region. Therefore, it is necessary to keep the reverse twist region far from the active region and it is possible by controlling the rubbing direction in the design of a pixel electrode.

• 한국정보디스플레이학회:학술대회논문집
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• 2002.08a
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• pp.560-562
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• 2002

The liquid crystal(LC) pixel capacitance Clc, which varies as a function of applied pixel voltage, is a main factor of pixel voltage errors on input gamma voltage, and therefore of the electro-optics(E-O) characteristics of LC pixel for a-Si TFT LCDs. The pixel voltage error(${\Delta}$Vp) for input gamma voltage was simulated for 14.1 inch diagonal XGA panel. An agreement between the experimental results and simulation was satisfactory for the gamma voltage compensation, ${\Delta}$Vp of the input gamma voltage. The proposed compensation method was successfully introduced to a 14.1 inch diagonal XGA panel, and a remarkable improvement of image sticking was achived.

• Macromolecular Research
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• v.14 no.1
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• pp.1-33
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• 2006

Polyimides (PIs) exhibit excellent thermal stability, mechanical, dielectric, and chemical resistance properties due to their heterocyclic imide rings and aromatic rings on the backbone. Due to these advantageous properties, PIs have found diverse applications in industry. Most PIs are insoluble because of the nature of the high chemical resistance. Thus, they are generally used as a soluble precursor polymer, which forms complexes with solvent molecules, and then finally converts to the corresponding polyimides via imidization reaction. This complexation with solvent has caused severe difficulty in the characterization of the precursor polymers. However, significant progress has recently been made on the detailed characterization of PI precursors and their imidization reaction. On the other hand, much research effort has been exerted to reduce the dielectric constant of PIs, as demanded in the microelectronics industry, through chemical modifications, as well as to develop high performance, light-emitting PIs and liquid crystal (LC) alignment layer PIs with both rubbing and rubbing-free processibility, which are desired in the flat-panel display industry. This article reviews this recent research progresses in characterizing PIs and their precursors and in developing low dielectric constant, light-emitting, and LC alignment layer PIs.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.17 no.2
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• pp.201-206
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• 2004

We have performed computer simulation and experiment to obtain electro-optic characteristics of reflective hybrid aligned nematic (R-HAN) cell driven by fringe field, in which the cell consists of polarizer, optical compensation film, LC layer and reflector. Conventional R-HAN cell driven by fringe field using only the LC layer shows high wavelength dispersion at dark-state and thus viewing angle characteristic is strongly wavelength-dependent. In order to improve this demerit, we added one optical compensation film to conventional R-HAN cell. The display with optimized cell parameters shows low wavelength dispersion at dark-state and exhibits a wide viewing angle without the occurrence of grey scale inversion over a wide range of viewing angles and the contrast ratio greater than 5 over exists about 120$^{\circ}$ in vortical direction and 160$^{\circ}$in horizontal direction. Experimental results show good agreements with theoretical results and fast response time.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2006.04a
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• pp.64-65
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• 2006

We studied the nematic liquid crystal (NLC) alignment capability by the IB(on bean) alignment method on a NDLC(Nitrogen Diamond Like Carbon) as a-C:H thin film, and investigated electro-optical performances of the IB aligned IPS(In plane switching}cell with NDLC surface. A good LC alignment by IB exposure on a NDLC surface was achieved. Monodomain alignment of the IB aligned IPS cell can be observed. The goodelectro-optical (EO) characteristics of the IB aligned IPS cell was observed with oblique IB exposure on the NDLC as a-C:H thin film for 1 min.

• Journal of the Korea Institute of Information and Communication Engineering
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• v.11 no.9
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• pp.1724-1728
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• 2007

In this paper we propose a novel electrode structure for high transmittance in the Patterned Vertical Alignment (PVA) LC cell. We use the 'TechWiz LCD' for calculation of the director configuration and optical characteristics. We studied the area decreasing the transmittance through the electrode structure for wide viewing angle and proposed new electrode design to change LC director configuration in the area. We show the comparison of the calculated optical transmittance between the conventional PVA mode and the proposed PVA mode. From the results, we confirm that the optical transmittance of the proposed structure of the PVA cell becomes higher.

• Applied Chemistry for Engineering
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• v.33 no.1
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• pp.50-57
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• 2022

Ti-In-Zn-O (TIZO)/Ag/TIZO multilayer transparent electrodes were prepared on glass substrates at room temperature using RF/DC magnetron sputtering. Obtained multilayer structure comprising TIZO/Ag/TIZO (10 nm/10 nm/40 nm) with the total thickness of 60 nm showed a transmittance of 86.5% at 650 nm and a sheet resistance of 8.1 Ω/□. The multilayer films were expected to be applicable for use in energy-saving smart window based on polymer-dispersed liquid crystal (PDLC) because of their transmittance properties to effectively block infrared rays (heat rays). We investigated the effects of the content ratio of prepolymer, the thickness of the PDLC coating layer, and the ultraviolet (UV) light intensity on electro-optical properties, and the surface morphology of polyester acrylate-based PDLC systems using new TIZO/Ag/TIZO transparent conducting electrodes. A PDLC cell with a thickness of 15 ㎛ PDLC layer photocured at an UV intensity of 1.5 mW/cm² exhibited good driving voltage, favorable on-state transmittance, and excellent off-haze. The LC droplets formed on the surface of the polymer matrix of the PDLC composite had a size range of 1 to 3 ㎛ capable of efficiently scattering incident light. Also, the PDLC-based smart window manufactured using TIZO/Ag/TIZO multi-layered transparent electrodes in this study exhibited a light brown, which will have an advantage in terms of aesthetics.