• Title/Summary/Keyword: LC (Liquid Crystal) Alignment

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Photosensitive Polymers: Effects of Photoreactive Group and UV-Exposure on Alignment of Liquid-Crystals on the Film Surface

  • Ree, Moon-Hor;Kim, Sang-Il;Lee, Seung-Woo
    • 한국정보디스플레이학회:학술대회논문집
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    • 2000.01a
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    • pp.41-42
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    • 2000
  • Photosensitive polyimides containing cinnamoyl and coumarin side groups were synthesized in a high molecular weight, giving a good quality of films. Nematic liquid-crystal (LC) molecules on the film were aligned along the direction with an angle of $97-99^{\circ}$ respect to the polarization of ultraviolet (UV) light. The LC alignment was induced mainly by the photoaligned polymer chains made by the first UV-exposure even though the film was treated by multiple exposures with changing the polarization of UV light. From these results, it is concluded that the LC alignment on the film is induced by the photodimerization rather than the trans-cis photoisomerization.

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Investigation on Liquid Crystal Alignment Effects of SiNx Thin Film Irradiated by Ion Beam (이온 빔 조사된 SiNx 박막의 액정 배향 효과에 관한 연구)

  • Lee, Sang-Keuk;Kim, Young-Hwan;Kim, Byoung-Yong;Han, Jin-Woo;Kang, Dong-Hun;Kim, Jong-Hwan;Seo, Dae-Shik
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.398-398
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    • 2007
  • Most recently, the Liquid Crystal (LC) aligning capabilities achieved by ion beam exposure on the diamond-like carbon (DLC) thin film layer have been successfully studied. The DLC thin films have a high mechanical hardness, a high electrical resistance, optical transparency and chemical inertness. Nitrogen doped Diamond Like Carbon (NDLC) thin films exhibit properties similar to those of the DLC films and better thermal stability than the DLC films because C:N bonding in the NDLC film is stronger against thermal stress than C:H bonding in the DLC thin films. Moreover, our research group has already studied ion beam alignment method using the NDLC thin films. The nematic liquid crystal (NLC) alignment effects treated on the SiNx thin film layers using ion beam irradiation for three kinds of N rations was successfully studied for the first time. The SiNx thin film was deposited by plasma-enhanced chemical vapor deposition (PECVD) and used three kinds of N rations. In order to characterize the films, the atomic force microscopy (AFM) image was observed. The good LC aligning capabilities treated on the SiNx thin film with ion beam exposure for all N rations can be achieved. The low pretilt angles for a NLC treated on the SiNx thin film with ion beam irradiation were measure.

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LC Aligning Capabilities of a Nematic Liquid Crystal on Homeotropic Polyimide Surface by New Ion-beam Irradiation

  • Ok, Chul-Ho;Kang, Dong-Hun;Lee, Kang-Min;Han, Jin-Woo;Kim, Byoung-Yong;Oh, Byeong-Yun;Kim, Young-Hwan;Hwang, Jeong-Yeon;Lee, Sang-Keuk;Han, Jeong-Min;Seo, Dae-Shik
    • Transactions on Electrical and Electronic Materials
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    • v.8 no.6
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    • pp.265-267
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    • 2007
  • The liquid crystal(LC) aligning capabilities of a nematic liquid crystal(NLC) on a homeotropic polyimide(PI) surface using a new ion-beam method were studied. Exposure ion-beam of $45^{\circ}$ incidence angle shows a good LC alignment of the NLC on the homeotropic PI surface. Also, on the homeotropic PI surface, the tilt angle of the NLC by exposure ion-beam of $45^{\circ}$ incidence angle had a tendency to decrease as increased ion-beam energy density. And, on the homeotropic PI surface, the alignment character of the NLC with respect to ion-beam energy was good at 1500 eV. And we achieved satisfactory result for EO character.

Liquid Crystal Alignment on the SiC Thin Film by the Ion Beam Exposure Method (SiC 박막에 이온빔 배향을 이용한 틸트 발생에 관한 연구)

  • Kang, Hyung-Ku;Kang, Hee-Jin;Hwang, Jeoung-Yeon;Lee, Whee-Won;Bae, Yu-Han;Moon, Hyun-Chan;Kim, Young-Hwan;Seo, Dae-Shik;Lim, Sung-Hoon;Jang, Jin
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.07a
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    • pp.489-490
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    • 2005
  • We studied the nematic liquid crystal (NLC) aligning capabilities using the new alignment material of the SiC (Silicon Carbide) thin film. The SiC thin film exhibits good chemical and thermal stability. The good thermal and chemical stability makes SiC an attractive candidate for electronic applications. A vertical alignment of nematic liquid crystal by ion beam exposure on the SiC thin film surface was achieved. The about $87^{\circ}$ of stable pretilt angle was achieved at the range from $30^{\circ}$ to $45^{\circ}$ of incident angle. The good LC alignment is main-tained by the ion beam alignment method on the SiC thin film surface at high annealing temperatures up to 300.

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Effects of UV Irradiation and Thermal Treatment of Photo-Degradable Polyimide Layer on LC Alignment (광분해성 고분자를 이용한 액정배향에서의 광조사 및 열처리 효과)

  • Lee, Jang-Ju;Lee, Won-Ho;Shin, Yong-Il;Paek, Sang-Hyon
    • Polymer(Korea)
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    • v.36 no.2
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    • pp.145-148
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    • 2012
  • The effects of the linearly polarized UV (LPUV) irradiation and thermal treatment of a photo-degradable polyimide (CBDA-ODA) alignment layer (AL) on its AL properties, liquid crystal (LC) alignment, and LCD characteristics have been investigated. The best quality of LC photo-alignment have been induced by the LPUV-irradiation with much (about 5~10 times) less dosage than that generating the maximum anisotropy of the AL. A thermal treatment of the LPUV-irradiated AL has effectively removed the undesirable, low-M.W. fragments of the AL generated during the photo-decomposition and increased the stability of the AL, which has resulted in improvement of the LC alignment and the LCD property.

FTIR study of E7 liquid crystals confined to perfluorinated carboxylic acid treated cylindrical cavities of Anodisc membranes

  • Ha, Ki-Ryong;Ahn, Hee-Jun;Yoon, Sung-Kyoun;Lee, Dong-Ho;West, John L.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2004.08a
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    • pp.369-372
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    • 2004
  • Orientation of E7 liquid crystals(LCs) confined to 200 nm-diameter cylindrical cavities of Anodisc membranes are investigated by FTIR dichroism techniques. The cavity walls of the confining pores are chemically modified with different perfluorinated carboxylic acids (PCA, $C_nF_{2n+1}$COOH, n=3, 4, 5, 6). From the FTIR spectra of PCA treated alumina Anodsic membranes, we found the salt formation between -COOH group of PCA and Anodisc membrane. From the FTIR spectra of LC filled Anodisc membranes, we found abrupt alignment direction change of LC molecules between n=4 and 5 for 1 mM PCA treated Anodisc membranes, from parallel to perpendicular direction to the cavity walls. But 5mM PCA treated Anodisc membranes, alignment direction of LC molecules changed between n=3 and n=4, from parallel to perpendicular direction.

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FTIR study of E7 liquid crystals confined to cylindrical cavities of Anodisc membranes

  • Ha, Ki-Ryong;Ahn, Hee-Jun;Jung, Kwang-Wook;Ahn, Won-Sool;West, John L.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2003.07a
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    • pp.475-477
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    • 2003
  • Orientation of E7 liquid crystals (LCs) confined to 200 nm-diameter cylindrical cavities of Anodisc membranes are investigated by FTIR dichroism techniques. The cavity walls of the confining pores are chemically modified with different aliphatic acids ($C_nH_{2n+1}COOH$, n=5, 6, 7, 9). From the FTIR spectra of aliphatic acid treated alumina Anodsic membranes, we found the salt formation between -COOH group of aliphatic acid and Anodisc membrane. From the FTIR spectra of LC filled Anodisc membranes, we found abrupt alignment direction change of LC molecules between n=6 and 7 for 2% aliphatic acid treated Anodisc membranes, from parallel to perpendicular direction to the cavity walls. But 4% aliphatic acid treated Anodisc membranes, alignment direction of LC molecules changed between n=5 and n=6, from parallel to perpendicular direction. The same trend was observed for $^2H-NMR$ measurements.

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Phase-Separated Pixel Isolation Method for Roll-to-Roll Processing in Flexible Liquid Crystal Displays

  • Kim, Hak-Rin;Jang, Se-Jin;Jung, Jong-Wook;Jin, Min-Young;Kim, Jae-Hoon
    • Journal of Information Display
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    • v.6 no.1
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    • pp.1-7
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    • 2005
  • We propose new fabrication methods of a pixel-isolated liquid crystal (LC) structure for flexible display applications. In the LC structure fabricated through the proposed method, the patterned interpixel walls for sustaining the cell thickness are supported by the solidified polymer layer through anisotropic phase separation of LC/polymer composite, causing the alignment of the LC molecules to have very good mechanical stability against external pressure. In addition, we show that such pixel-isolating walls can be made by the stamping method which can be applied to fabricate large size plastic LCDs by roll-to-roll processing.

High Speed Displays Based on a Nonchiral Smectic C Liquid Crystal in an Antiparallel Planar Geometry

  • Jeong, Cherl-Hyun;Na, Jun-Hee;Yoon, Tae-Young;Yu, Chang-Jae;Lee, Sin-Doo
    • 한국정보디스플레이학회:학술대회논문집
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    • 2005.07a
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    • pp.571-574
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    • 2005
  • We demonstrated a high speed liquid crystal (LC) display mode based on a nonchiral smectic C LC in an antiparallel planar geometry. In this antiparallel planar nonchiral smectic C (APNSC) LC mode, analog gray scales and wide viewing properties are achieved using a stepwise thermal annealing process (STAP). Because of an initially stable LC alignment in large area through the STAP, the APNSC LC mode exhibits the characteristics of fast response and high contrast ratio. This new APNSC mode is suitable for processing the dynamic image at a video rate in the next-generation LCDs.

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Soft-lithography for preparing patterned liquid crystal orientations

  • Kim, Hak-Rin;Jung, Jong-Wook;Shin, Min-Soo;Kim, Myung-Eun;Lee, You-Jin;Kim, Jae-Hoon
    • 한국정보디스플레이학회:학술대회논문집
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    • 2006.08a
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    • pp.615-620
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    • 2006
  • We demonstrate novel soft-lithographic techniques for preparing patterned liquid crystal (LC) orientations at an alignment layer. By controlling patterning conditions such as wetting property and operating temperature depending on polymeric materials, multi-directional or modified LC alignment conditions can be simply achieved.

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