• 제목/요약/키워드: LB Film

검색결과 299건 처리시간 0.02초

LB 막 제작을 위한 $\pi$-A Isotherm ($\pi$-A Isotherm for LB Film Deposition)

  • 송일석;김태완;손병청;박혁;강도열
    • 대한전기학회:학술대회논문집
    • /
    • 대한전기학회 1992년도 하계학술대회 논문집 B
    • /
    • pp.864-867
    • /
    • 1992
  • This paper describes optimum conditions for depositing Langumuir Blodgett(LB) films. $\pi$-A isotherm characteristics were studied with the following species, $C_{18}$-Quinolium(TCNQ), $C_{22}$-Quinolium(TCNQ), Azobenzene, Arachidic Acid, by varing length of alkyl chains, temperacture, pH, spreading amount, barrier moving speed and etc. We have observed the change of $\pi$-A isotherm depending on the above variations. From there we investigate the depositing conditions of LB films for each material.

  • PDF

Moving Wall형 LB법에 의해서 제작된 DLPC 지질막의 누적특성 (The Deposition Characterization of DLPC Lipid Membrane by Moving Wall Type LB Methode)

  • 정용호;이우선;김남오;이경섭
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 1997년도 춘계학술대회 논문집
    • /
    • pp.342-345
    • /
    • 1997
  • We fabricated the sample of u1tra thin lipid membrane(L-${\alpha}$-DLPC ) by LB methode. The $\pi$-A isotherm of the DLPC was measured at the air-water interface varying with the compressing speed and amounts of solutions for spreading. For good property of lipid monolayer film, it was necessary for the lower speed of compressing, and 40${\mu}\ell$ of solutions for spreading. The molecular arrangement of deposited films were evaluated by measuring the absorption, transmitance and intensity with the UV spectrophotometer. The Y-type multilayers prepared at 50mN/m showed weaker than Z-type. So we found building-up of structurally high quality LB films is essential to study properties of the films and to get reproducible data.

  • PDF

Functional Layer-by-Layer Assembled Multilayers Based on Nucleophilic Substitution reaction

  • 조진한
    • 한국재료학회:학술대회논문집
    • /
    • 한국재료학회 2011년도 춘계학술발표대회
    • /
    • pp.9.2-9.2
    • /
    • 2011
  • Ultrathin polyelectrolyte (PE) multilayer films prepared by the versatile layer-by layer (LbL) assembly method have been utilized for the preparation of light-emitting diodes, electrochromic, membrane, and drug delivery system, as well as for selective area patterning and particle surface modification because the various materials with specific properties can be inserted into the film with nano-level thickness irrespective of the size or the shape of substrate. Since the introduction of the LbL technique in 1991 by Decher and Hong, various hydrophilic materials can be inserted within LbL films through complementary interactions (i.e., electrostatic, hydrogen-bonding or covalent interaction). In this study, it is demonstrated that LbL SA multilayer films based on nucleophilic substitution reaction can allow the preparation of the highly efficient magnetic and/or optical films and nonvolatile memory devices.

  • PDF

BAM(Brewster angle microscopy)을 이용한 PAAS(Polyamic Acid Alkylamine Salts)의 Langmuir막과 Langmuir-Blodgett막의 특성 연구 (A. Study on the PAAS(Polyamic Acid Alkylamine Salts) Langmuir Films and Langmuir-Blodgett Films using BAM(Brewster angle microscopy))

  • 이승엽;강도열;김태완
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 1996년도 추계학술대회 논문집
    • /
    • pp.147-151
    • /
    • 1996
  • Brewster angle microscopy(BAM) makes it possible to observe the monolayer states on the water subphase and the phase transitions from a gaseous phase via a expanded phase to a condensed phase. Also BAM can be used to observe the films on the solid substrate such as Langmuir-Blodgett(LB) films. In this Paper Polyamic Acid Alkylamine Salts(PAAS) was used for forming L films and LB films and $\pi$-A isotherm showed pressure of each phase. We obtained BAM images as surface pressure increased. Images of LB films were compared with data from ellipsometry which was used to measure the film thickness. Images of both L films and LB films were analyzed with computer in the point of brightness.

  • PDF

MIS 구조의 DLPC LB 막의 제작과 전압-전류 특성 (Fabrication of DLPC LB films with MIS structure and I-V characteristics)

  • 이우선;정용호;정종상;손경춘;김상용;장의구;이경섭
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 1998년도 춘계학술대회 논문집
    • /
    • pp.155-158
    • /
    • 1998
  • MLS capacitor with lipid ultra thin films were deposited by Langmuir-Blodgett (LB) method on the sillicon wafer. The current versus voltage and capacitance versus voltage relationships are depend on the applied voltage, electrode area and electrode materials. LB films deposited were made of L-$\alpha$-DLPC, the 1 layer's thickness of 35$\AA$ was measured by ellipsometer. And MLS capacitor with different electrode materials, the work function of these materials was investigated to increase the leakage current. The result indicated the lower leakage current and very high saturation value of capacitance was reached within 700-800 pF when the two electrode was Ag. And $\varepsilon$$_1$, $\varepsilon$$_2$ versus photon energy showed good film formation.

  • PDF

N-docosyl pyridinium(TCNQ) LB막의 NO$_2$가스탐지 특성에 관한 연구 (A Study of The NO$_2$Gas Detect Properties of N-docosyl pyridinium(TCNQ) LB Film)

  • 유병호;조형근;김형석;이창희;김정수
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 1994년도 춘계학술대회 논문집
    • /
    • pp.75-78
    • /
    • 1994
  • Organic ultra thin films about 500${\AA}$ in thickness are fabricated by LB(Langmuir-Blodgett) technique and their gas detect properties are investigated. The LB films deposited are made of the specimen named as N-docosyl pyridinium(TCNQ) and the deposition is verified by capacitance conductivity measurement. From the study of gas detect properties with I-V characteristics and UV spectrum we have found that their conductivities were increased about 3 times of magnitude and peaks of UV spectrum were decreased.

  • PDF

Octa-dodecyloxy Copper-Phthalocyanine LB 막의 NO$_2$ 가스 탐지 특성에 관한 연구 (A Study on the NO$_2$ Gas Detection Characteristics of Octa-dodecy1oxy Copper-Phthalocyanine LB Films)

  • 구자룡;이한성;하윤경;김영관;김정수
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 1997년도 추계학술대회 논문집
    • /
    • pp.1-4
    • /
    • 1997
  • In this study, ruin films of Octla-dodecyloxy copper-phthalocyanine were prepared by Langmuir-Blodgett (LB) method and characterirzed by using UV-Vis absorption spectroscopy and ellipsometry. [1],r[2] Optimal transfer condition of LB films was investigated and preliminary results of current-voltage(1-V) characteristics of these films exposed to NO$_2$ gas as were discussed functions of film thickness, temperature and NO$_2$ gas concentration.

  • PDF

말레에이트계.이타코네이트계 공중합체 LB막의 가스 반응 특성 비교 (Comparison to Gases Response Characteristics of Maleate and Itaconate Copolymer LB Films)

  • 이을식;김도균;최용성;장정수;권영수
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 1997년도 추계학술대회 논문집
    • /
    • pp.461-464
    • /
    • 1997
  • In this paper, the response characteristics for organic vapors has been studied using both itaconate copolymer and maleate copolymer, which have different hydrophilic group and same hydrophilic group. The conductivity of sensitive LB films was decreased in the range of 18 layers and maintained over 30 layers, which can describe the behaviors of urganic vapors such as penetration and surface absorption. It was thought that the organic vapors was penetrated into sensitive 13 films below 18 layer and the electrode was covered with sensitive LB film over 30 layers.

  • PDF

고분자 감웅성 LB막을 이용한 One-channel 가스센서의 개발연구 (A Study on Development of One-channel Gas Sensor Using Polymeric Sensitive LB Films)

  • 강현욱;김정명;권영수
    • 대한전기학회:학술대회논문집
    • /
    • 대한전기학회 1996년도 추계학술대회 논문집 학회본부
    • /
    • pp.261-263
    • /
    • 1996
  • The study on the development of one-channel gas sensor using the quartz crystal analyzer were attempted. The adsorption and desorption behavior of organic gases were investigated using the resonant frequency and resistance method of quartz crystal. The sensitive materials were deposited on the quartz crystal analyzer(QCA) by using Langmuir-Blodgett method. To investigate the response characteristics of organic vapours and response mechanism, resonant frequency-resonant resistance (F-R) diagram was used. In our experimental results, the response mechanism between sensitive LB film and organic vapours was obtained using F-R diagram. And the position of each organic vapour were different as to the kind and injection amount. Thus F-R diagram can be applied to one-channel gas sensor using the QCA and useful to analyze the response mechanism between organic vspours and sensitive LB films.

  • PDF

랭뮤어-블로젯법에 의한 양친매성 스쿠아릴리움 색소의 초박막 제작 (Fabrication as Ultra-thin films of Amphiphilic Squarylium dye by the Langmuir-Blodgett Technique)

  • 정순욱
    • 한국재료학회지
    • /
    • 제9권6호
    • /
    • pp.595-598
    • /
    • 1999
  • Ultra-thin films of amphiphilic Squarylium dye were prepared on the hydrophilic glass substrate by Langumuir-Blodgett(LB) technique. From the measurement of the surface pressure-area($\pi$-A) isotherm at air-water interface, it was found that amphiphilic Squarylium dye can form the stable monolayers. Using the LB technique, the Z-type monolayer assembly can be obtained. The amphiphilic Squarylium dye LB films exhibit λ\ulcorner at 684nm. The absorption is significantly red-shifted from solution of amphiphilic Squarylium dye(637nm in chloroform), suggesting that the Squarylim chromophores form J-aggregate in the LB film.

  • PDF