• 제목/요약/키워드: LAYERED STRUCTURE

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Structure and Physical Properties of $YSe_{1.83}$

  • 김성진;오훈정
    • Bulletin of the Korean Chemical Society
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    • v.16 no.6
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    • pp.515-518
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    • 1995
  • YSe1.83 was synthesized by vapor transport technique and its crystal structure was determined. The structure was isostructure of LaTe2-x, which was layered structure consisting of two-atom thick layers of YSe with distorted NaCl-type structure and one-atom thick layer of Se. The substructure of YSe1.83 was tetragonal with space group of P4/nmm and a=4.011(2) and c=8.261(3) Å with final R/Rw=6.4/6.9 %. The superstructure with asuper=2a, bsuper=6b and csuper=2c was found. The measurements of electronic and magnetic properties of this compound indicate that it is an electronic insulator and diamagnet.

Efficient Transdermal Penetration and Improved Stability of L-Ascorbic Acid Encapsulated in an Inorganic Nanocapsule

  • Yang, Jae-Hun;Lee, Sun-Young;Han, Yang-Su;Park, Kyoung-Chan;Choy, Jin-Ho
    • Bulletin of the Korean Chemical Society
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    • v.24 no.4
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    • pp.499-503
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    • 2003
  • Encapsulation of L-ascorbic acid (vitamin C) within a bio-compatible layered inorganic material was achieved by coprecipitation reaction, in which the layered inorganic lattice and its intercalate of vitamin C are simultaneously formed. The nano-meter sized powders of vitamin C intercalate thus prepared was again encapsulated with silica nano-sol to form a nanoporous shell structure. This ternary nanohybrid of vitamin Clayered inorganic core-$SiO_2$ shell exhibited an enhanced storage stability and a sustained releasing of vitamin C. Furthermore, the nano-encapsulation of vitamin C with inorganic mineral was very helpful in delivering vitamin C molecules into skin through stratum corneum, facilitating transdermal penetration of vitamin C in topical application.

The structure and synthesis of intercalation compound between a layered double hydroxide and an organic compound (유기화합물이 삽입된 층상이중수산화물의 합성과 구조)

  • 우은경;허영덕
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.8 no.1
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    • pp.36-41
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    • 1998
  • Intercalation compounds of alkyl sulfonates into layered double hydroxides (LDH) have been directly synthesized. From the X-ray diffraction data and the alkyl sulfonates size, the orientation of the intercalated alkyl sulfonate into the layered double hydroxide was determined. The intercalated alkyl sulfonate is arranged with molecular chain perpendicular to the hydroxide layer with an antiparallel pattern.

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The structure of intercalation compound between a layered double hydroxide and an ethyl orange (층상이중수산화물과 에틸오렌지의 삽입화합물의 구조)

  • Jung, Woo-Chan;Huh, Young-Duk
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.7 no.1
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    • pp.137-142
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    • 1997
  • We synthesized the intercalation compound between a layered double hydroxide and an ethyl orange. The orientation of the intercalated ethyl orange into the layered double hydroxide was investigated. The molecular plane of the ethyl orange and its N=N axis lie nearly perpendicular to the hydroxide layers with an antiparallel pattern.

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FMS process planning using a symmetric multi-layered coevolutionary algorithm (대칭형 다계층 공진화 알고리듬을 이용한 FMS 공정계획)

  • Kim Jae Yun;Kim Yeo Geun
    • Proceedings of the Korean Operations and Management Science Society Conference
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    • 2003.05a
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    • pp.1048-1055
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    • 2003
  • This paper proposes a new method of solving integrated problems that consist of several sub-problems in a symmetric multi-layered structure, and also demonstrate the applicability of the method. The proposed method is named Symmetric Multi-layered Coevolutionary Algorithm (SMCA). The SMCA imitates partly the natural process of endosymbiotic evolution, which is a special type of coevolution. The SMCA is applied to the process planning problem in flexible manufacturing system (FMS), taking account of the flexibility of machine, tool, process, and sequence. To do this, SMCA's components are studied and its strategies are developed to improve the performance. The proposed algorithm is compared with the existing ones in terms of solution quality. The experimental results confirm the effectiveness of our approach.

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Step-wise Anion-Exchange in Layered Double Hydroxide Using Solvothermal Treatment

  • Lee, Jong-Hyeon;Rhee, Seog-Woo;Jung, Duk-Young
    • Bulletin of the Korean Chemical Society
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    • v.26 no.2
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    • pp.248-252
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    • 2005
  • Synthetic layered double hydroxides (LDHs), [$Mg_4Al_2(OH)_{12}]CO_3{\cdot}nH_2O$, were prepared in the submicron size of plate-like polycrystals. Anion-exchange reactions with various linear dicarboxylic acids were performed to produce LDH/organic hybrid materials by solvothermal treatment in toluene. X-ray powder diffraction spectra for the products indicated that the interlayer spacings of LDHs remarkably changed, up to 20 $\AA$ when 1,10-decanedicarboxylic acid anions were intercalated as an organic guest. Dicarboxylates-LDHs samples could be also re-exchanged consecutively with other dicarboxylic acids or carbonate without serious destruction of layer structure under the scanning electron microscopic observation.

Dynamic Behavior of Rigid Circular Foundation in Water-Saturated Transversely Isotropic Layered Stratum (지하수로 포화된 가로등방성 층상지반에 설치된 강체 원형 기초의 동적 거동)

  • Lee, Jin-Ho;Park, Jung-Jun;Kim, Jae-Kwan;Jin, Byeong-Moo
    • Proceedings of the Earthquake Engineering Society of Korea Conference
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    • 2005.03a
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    • pp.47-51
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    • 2005
  • If a structure is founded on the ground saturated with pore water, then the ground should be modeled as a saturated two-phase porous medium for accurate earthquake response analysis. In this study, an axisymmetric transmitting boundary hyperelement is developed for modeling of far field of the ground using u-U formulation for water-saturated transversely isotropic layered stratum. The developed hyperelement is verified by comparing the dynamic stiffness of rigid circular foundation on water-saturated isotropic layered stratum with the case of using equivalent single-phase medium model.

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Numerical Analysis of UV Laser Patterning of Polymeric Thin-Film (자외선 레이저를 이용한 폴리머 박막 가공의 수치해석)

  • Oh, B.K.;Lee, S.K.;Song, M.K.;Kim, J.W.;Hong, S.K.
    • Laser Solutions
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    • v.12 no.4
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    • pp.1-5
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    • 2009
  • Conventional patterning based on wet-process for multi-layered film is a relatively complex and costly process though it is a necessary step for fabrication of TFT-LCD module. Recently, a direct pattering by laser has been studied because it is low cost and simple process compared to the wet process. In this work, the selective removal process of multi-layered film (polyimide/indium tin oxide/glass) is studied by modeling the thermal and mechanical behavior for multi-layered structure. Especially, the effects of thickness of polyimide layer are examined.

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Time-dependent analysis of reinforced concrete structures using the layered finite element method

  • Bradford, M.A.;Gilbert, R.I.;Sun, S.C.H.
    • Structural Engineering and Mechanics
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    • v.8 no.6
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    • pp.561-578
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    • 1999
  • The response of a reinforced concrete structure to loading is both immediate and time-dependent. Under a sustained load, the deflections caused by creep and shrinkage may be several times their instantaneous values. The paper describes a general finite element procedure, based on the so-called layered model, to analyse reinforced concrete members, and shows in particular how the simple Step by Step Method may be incorporated into this procedure. By invoking the Modified Newton Raphson Method as a solution procedure, the accuracy of the finite element method is verified against independent test results, and then applied to a variety of problems in order to demonstrate its efficacy. The method forms a general method for analysing highly indeterminate concrete structures in the time domain.

A Two-Layered Fuzzy Logic Controller for Systems with Deadzones

  • Kim, Jong-Hwan;Park, Jong-Hwan;Lee, Seon-Woo
    • Proceedings of the Korean Institute of Intelligent Systems Conference
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    • 1993.06a
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    • pp.826-829
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    • 1993
  • Existing fuzzy control methods do not perform well when applied to systems containing nonlinearities arising from unknown deadzones. We propose a novel two-layered fuzzy logic controller for controlling systems with deadzones. The two-layered control structure consists of a fuzzy logic-based pre-compensator followed by a conventional fuzzy logic controller. Our proposed controller exhibits superior transient and steady-state performance compared to conventional fuzzy controllers. We illustrate the effectiveness of our scheme using computer simulation examples.

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