• Proceedings of the Materials Research Society of Korea Conference
• /
• 2003.11a
• /
• pp.98-98
• /
• 2003

초내열성 결정화유리는 전기전자부품, 천체만원경의 반사경, 직화용 조리기기, 군사용 부품 등에 광범위하게 이용되고 있는데 이중 LAS 계가 가장 오랫동안 알려진 조성 계이다. 이 결정화유리는 주입성형후 열처리에 의하여 결정상을 생성하여 사용되는데 표면이 매우 낮은 조도를 갖는 것으로 알려져 있으나 실제로는 제조상에 조도가 높게 나타나는 문제점이 제기되고 있다. 따라서 본 연구에서는 미세조직적인 측면에서 이러한 점을 연구하고자 Li$_2$O-AL$_2$O$_3$-SiO$_2$를 주성분으로 하고 소량의 MgO와 핵생성제로서 TiO$_2$, ZrO$_2$를 사용하여 시편을 제조하였다. 제조된 결정화유리의 결정화도의 차이에 따라 AFM, $\alpha$-STEP등으로 표면의 조도를 정량화였다. 결정상의 종류, 크기, 결정화도, 결정상간의 간격 등이 표면의 조도에 어떻게 영향을 주는가 에 대하여 연구한 결과를 제시하였다.

• Proceedings of the KIEE Conference
• /
• 2002.07c
• /
• pp.1494-1496
• /
• 2002

내열 충격성 및 적외선 투과를 갖는 LAS($Li_2O-Al_2O_3-SiO_2$)계 글라스세라믹스를 제조하였다. 본 연구에서는 LAS계에 $TiO_2$를 핵형성제로, 점도를 감소시키기 위해 $P_2O_5$를 첨가하여 유리를 제조한 후, 글라스세라믹 결정상을 석출시켰다. 석출된 주 결정상은 ${\beta}$-eucryptite(SS)이었으며, 열팽창 계수가 거의 제로에 가까운 값을 얻었다. 또한 선택적인 스펙트럼의 흡수를 위한 color dopants에 대한 기초 자료 등이 조사되었다.

• Journal of Powder Materials
• /
• v.27 no.4
• /
• pp.287-292
• /
• 2020

The subject of this study is a zeolite generated as a by-product of recycling LAS (lithium-aluminum-silicate) resources, a kind of glass and ceramic produced by induction. The zeolite by-product is modified into Mg-zeolite using Mg as a cation to absorb Pb, a heavy metal generated from water pollution caused by recent industrial wastewater. An ion-exchange method is used to carry out the modification process, from zeolite byproduct to Mg-zeolite, and simultaneously absorb the Pb in the heavy-metal solution (99.032 mg/L). It is found that the sodium zeolite in the raw material residue can be modified to magnesium zeolite by reacting it with a mixture solution at 1 M concentration for 24 h. As a result, it is found that the residual Pb (0.130 mg/L) in the heavy metal solution is shown to be absorbed by 99.86%, with successful formation of a Mg-modified zeolite.

• Proceedings of the Korean Ceranic Society Conference
• /
• 2003.10a
• /
• pp.163.1-163
• /
• 2003

• Journal of Biomedical Engineering Research
• /
• v.11 no.2
• /
• pp.295-304
• /
• 1990

In order to use for artificial dental tooth (dental crowens) , new glass-ceramics material has been studied. Its basic composition and the condition of heat treatment for crystalization, mechanical and chemical properties were investigated. Adding of the LAS system composition in the basic glass, time and temperature for crystalization were shortened. Fracture toughness (kic)of samples heat treated at 90$0^{\circ}C$ for 2 hours is 2.5-2.6MN/m3/2, the optimum condition of heat treatment for artificial tooth is A and B samples heating to 75$0^{\circ}C$ for 2 hours, raising to 90$0^{\circ}C$ and maintaining at 90$0^{\circ}C$ for 2 hours and C sample heating to 75$0^{\circ}C$ maintaining at 75$0^{\circ}C$ for 2 hours. In acid and'alkali solution, chemical durability is excellent.

• Journal of the Korean Ceramic Society
• /
• v.32 no.2
• /
• pp.171-182
• /
• 1995

Five eucryptite and ten spodumene compositional powders were syntehsized from three sillimanite group, two kaolin group, and five pyrophyllite group silicate minerals. Those powders were isotatically pressed and fired at 1200~135$0^{\circ}C$ for 2 hrs, and then the sintered bodies were characterized. Silicate minerals with molar ratio of Al2O3 to SiO2 correspond to those of eucryptite and spodumene are kaolin and pyrophyllite group silicate minerals, respectively. Sintering characteristics of eucryptite from kaolin group and spodumene from pyrophyllite group mineral were superior to those from other silicate minerals. Eucryptite sintered bodies with 95~97% relative densities and densified microstructures can be obtained using Hadong pink kaolin as starting materials by sintering over broad temperature zone(1250~135$0^{\circ}C$). The eucryptite sintered bodies which were fired at 130$0^{\circ}C$ for 2hrs, from Hadong pink kaolin had within 3.0wt% microstructural compositional variations compaired with stoichiometric compound, and had good negative thermal expansiion property with -3.55$\times$10-6/$^{\circ}C$ thermal expansion coefficient. Spodumene sintered bodies which were prepared from pyrophyllite group silicate minerals, had dense microstructures and high densities by densification through liquid phase sintering with enlarged temperature range. The specimens which were fired at 130$0^{\circ}C$ for 2 hrs from Gusipyrophillite, had dense microstructure with crystallines mainly, and low thermal expansion property with 0.62$\times$10-6/$^{\circ}C$ thermal expansion coefficient. The porous texture and residual glass phase in LAS system ceramics which were prepared from silicate minerals, tend to increase the thermal expansion properties of sintered bodies to positive direction.

• Resources Recycling
• /
• v.31 no.4
• /
• pp.49-55
• /
• 2022

In this study, the heavy metal ions (of Pb, Cd, Cr, and Hg) in wastewater were removed using a spent Li₂O-Al₂O₃-SiO₂-based crystallized glass previously used as an induction top plate material. Changes in the removal efficiency of heavy metals according to different reaction parameters, such as the amount of zeolite used as a heavy-metal adsorbent, adsorption time, initial concentration of the heavy metals, and pH of the initial solution, were investigated. As the amount of zeolite added increased, the heavy-metal removal efficiency also increased. Adsorption time had a considerable influence on adsorption characteristics, and the removal efficiency of all heavy metals increased with increasing adsorption time. In the case of Cd, the removal efficiency was greatly improved depending on the adsorption time. The initial concentration of the heavy-metal solution did not affect the removal efficiency; however, the initial pH of the heavy-metal solution affected the removal efficiency. More specifically, the removal efficiency of Cd increased while that of Pb and Cr decreased with increasing pH. The adsorption characteristics of Hg were not significantly affected by pH.

• Journal of the Korean institute of surface engineering
• /
• v.27 no.2
• /
• pp.99-108
• /
• 1994

Films of glass-ceramics $Li_2O-Al_2O_3-SiO_2$(LAS)system were prepared on substrate of an iron plate(SCP) by sol-gel technique using metal alkoxide such as Si$(OC_2H_5)_4$,Al$(OC_2H_9)_3$) and Ti$(OC_2H_6)_4$). Sol which was made by means of simple spray coating, on the substrate was hydrolyzed at 75~$80^{\circ}C$ in moisture cabinet (80~90 % humidity) to form the multicomponent gel. The films up to about 0.8~1.0$mu extrm{m}$ in thickness can be obtained by repeating operation, spraylongrightarrowhydrolysis and condensationlongrightarrowdryinglongrightarrowheating and crystallization at $700^{\circ}C$ for 3~5min. The far-infrared radiation spectra of the coated films on substrate were examined by FT-IR and of films was also observed by scanning electron micrograph technique. The thermal evaluation of the gel-film is followed by TG/DTA measurements. The structure evaluation is followedd X-ray diffraction. These results suggest that this process is applicable to far-infrared radiat at thin film technique.

• Journal of Powder Materials
• /
• v.18 no.1
• /
• pp.35-40
• /
• 2011

LAS-system ceramic powder, spodumene ($Li_2O{\cdot}Al_2O_3{\cdot}4SiO_2$), was successfully synthesized by a chemical solution technique employing PVA(polyvinyl alcohol) as an organic carrier. The PVA content affected the microstructure of porous precursor gels and the crystalline development. The optimum PVA content contributed to homogeneous distribution of metal ions in the precursor gel and it resulted in the synthesis of glass free $\beta$-spodumene powder having a specific surface area of $7.57\;m^2/g$. The agglomerated $\beta$-spodumene powders were also enough soft to grind to fine powders by a simple ball milling process. The microstructures of the densified powder compacts were strongly dependant on the minor phases of spodumene solid solution and amount of liquid phase, which were formed from the inhomogeneous precursors.

• Environmental Analysis Health and Toxicology
• /
• v.7 no.1_2
• /
• pp.67-87
• /
• 1992

Each detergent-solution in the concentration of 0.4% was prepared with four kinds of raw materials of detergents and two kinds of commercial surfactants for kitchen. LAS (Linear Alkyl Benzene Sulfonate), AOS ($\alpha$-O1effine Sulfonate), SLS (Sodium Lauryl Sulfonate) and SLE (Sodium Lauryl Ester Sulfonate) were used as the raw materials. Vegetables and fruits such as cucumber, crown daisy, lettuce, strawberry and tomatos were diped in each solution and washed 5 times in static or flow state. For the other experiments, tablewares such as porcelain, stainless bowls, glass and plastic cups were diped in each solution and washed also 5 times with cold and hot water in static or flow state. The residues of the detergents on the every steps of wash-conditions were measured. The results of this study were summarized as followings: 1. The residures of the detergents on the tested vegetables and fruits after 5 times washing were detected with the range from 0.450 to 7.120 ppm in static state and from 0.343 to 6.375 ppm in flow state. 2. The residures of the detergents on the tested tablewares after 5 times washing with cold water were observed with the range from 0.057 to 0.815 ppm in static state and from 0.066 to 0.905 ppm in flow state. 4. The residures of the detergents on the tested tablewares after 5 times washing with hot water were determined with the range from 0.061 to 0.424 ppm in static state and from 0.066 to 0.368 ppm in flow state. 4. Independent on detergent types, water temperatures and washing methods, the detergents were remained stablely on the porcelain; 0.057~0.815 ppm, on the stainless bowl; 0.061~0.905 ppm, on the glass cup; 0.0l4~0.592 ppm and on the plastic cup; 0.201~0.592 ppm.