• Title/Summary/Keyword: L-particles

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Photolytic Characteristics of Ni-TiO2 Composite Coating from Electroless Plating (무전해 Ni-TiO2 복합도금을 이용한 광분해 특성 연구)

  • Choi, Chul-Young;Han, Gil-Soo;Jo, Il-Guk;Kim, Young-Seok;Kim, Yang-Do
    • Journal of the Korean institute of surface engineering
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    • v.42 no.4
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    • pp.157-160
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    • 2009
  • Many fundamental studies have been carried out regarding waste water and hazardous gas treatments technologies using the photolysis effect of $TiO_2$. However, a permanent use of $TiO_2$ particles immobilized using organic or organic-inorganic binders is impossible. In this study, Ni-$TiO_2$ composite coating was produced by electroless plating to trap $TiO_2$ particles in the Ni coating layer. The electroless plating was performed in the bath solutions with three different concentrations of $TiO_2$ particles : 10 g/l, 20 g/l, and 40 g/l. The surface and photolytic characteristics of the coating layer was investigated by the use of SEM, a scratch tester, and an UV-Visible spectrophotometer. The results showed that the amounts of immobilized $TiO_2$ particles and the photolytic rate of the coating increased with the initial content of $TiO_2$ particles in the electroless bath. In addition, the photolytic rate of the Ni-$TiO_2$ composite coating was remarkably promoted by etching process in 10% HCl solution.

Study on Effect of Particle Size of Ferrous Iron and Polishing Abrasive on Surface Quality Improvement (자기연마가공에서 자성입자와 연마재의 크기에 따른 표면개선 효과)

  • Lee, Sung-Ho;Son, Byung-Hun;Kwak, Jae-Seob
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.38 no.9
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    • pp.1013-1018
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    • 2014
  • Magnetic Abrasive Polishing (MAP) process is a nontraditional method for polishing the surface of workpiece by using the flexibility of tool. At present, a mixture of polishing abrasives and ferrous particles is used as the tool in the MAP process. Previously, an experiment was conducted with different sizes of polishing abrasives with an aim to improve the polishing accuracy. However, the sizes of ferrous particles are also expected to have a dominant effect on the process, warranting a study on the effect of the size of ferrous iron particles. In this study, an experiment was conducted using three different sizes of ferrous particles. Iron powder of average diameters 8, 78 and $250{\mu}m$ was used as ferrous particles. The effect of each ferrous particle size was evaluated by comparing the improvements in surface roughness. The particle size of a ferrous iron was found to play a significant role in MAP and particles of $78{\mu}m$ facilitated the best improvement in surface roughness.

Formation of 3-Dimensional Networks of Colloidal Particles in a Nematic Host

  • West, John L.;Glushchenko, Anatoliy;Zhang, Ke;Reznikov, Yuri
    • 한국정보디스플레이학회:학술대회논문집
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    • 2002.08a
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    • pp.191-192
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    • 2002
  • We reported pushing of colloidal particles by a moving isotropic-nematic phase boundary. Here, we report tailoring the structure of 3-dimensional networks formed by these particles by adjusting the rate of phase transition and by application of an electric field. The resulting networks affect the electro-optic performance of liquid crystal devices.

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Preparation and Antitumor Activities of Poly(polyethylene glycol methacrylate-co-methacryloyloxymethyl-5-fluorouracil) Prodrug

  • Cho, Suk-Hyung;Kim, Kong-Soo
    • Macromolecular Research
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    • v.11 no.5
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    • pp.317-321
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    • 2003
  • In order to prepare a prodrug, poly(polyethylene glycol methacrylate-co-methacryloyloxymethyl-5-fluorouracil) (poly(PEGM-co-MAOFU)) prodrug particles were prepared by precipitation polymerization of MAOFU and PEGM in polyacrylic acid solution. The size of prodrug particles were 0.2-0.35 ${\mu}{\textrm}{m}$. The antitumor activity of prodrugs against sarcoma-l80 tumor cell in mice was demonstrated and the polymer particles themselves showed low toxicity and good biocompatibility when they were administrated into mice.

The Application of Aluminum Coagulant for the Improvement of Water Quality in Three Recreational Ponds (알루미늄 응집제를 사용한 호수수질 개선 사례 연구)

  • Kang, Phil-Goo;Kim, Bom-Chul
    • Korean Journal of Ecology and Environment
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    • v.36 no.4 s.105
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    • pp.447-454
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    • 2003
  • Aluminum coagulant was applied to two eutrophic lakes (Lake Sukchon, in Seoul, and a pond on the campus of Kangwon National University), to precipitate suspended particles and phosphate from the water column. Aluminum sulfate (alum) was used for seven treatments and polyaluminum chloride (PAC) was used for one treatment. The effect of treatment varied depending on the dose of alumium coagulant. Particles and phosphate were completely precipitated from the water column with a dose of 10.0 mgAl/l. Partial removal was observed at doses of 3.3 and 1.8 mgAl/l, but not at 0.45 mgAl/l. Therefore, coagulant should be applied at a dose over the threshold in order to remove particles effectively, which seems to be between 1.8 and 10.0 mgAl/l. The length of treatment effect was determined by new inputs of nutrients and particles from external sources. Renewal of pond water by stream water caused recovery of algal growth in Lake Sukchon, and rainfall runoff and ground water pumping caused a return of turbid water in the campus pond. During treatment there was no sign of decreasing pH, or harmful effects on fish or mussels. Aluminum coagulant may be an economically feasible alternative for water quality improvement when the external control of pollutant sources is difficult. However, repeated application is required when there is a renewal of lake water or new input of nutrients.

A Study on the Zeta Potential Measurement and the Stability Analysis of Nano Fluids using a Particle Image Processing System (입자 영상 처리 시스템을 이용한 콜로이드 입자의 제타포텐셜 측정 및 나노유체 분산 특성 연구)

  • Lee, J.K.;Kim, S.C.;Kim, H.J.;Lee, C.G.;Ju, C.H.;Lee, L.C.
    • Journal of ILASS-Korea
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    • v.8 no.1
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    • pp.16-22
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    • 2003
  • Zeta potential measurements of colloid particles suspended in a liquid are performed by a Zeta Meter developed. There are many applications of colloid stability in spray technology, paints, wastewater treatment, and pharmaceuticalse. Zeta potentials of charged particles are obtained by measuring the electrophoretic velocities of the particles using video enhanced microscopy and image analysis program. The values of zeta potential of polystyrene latex(PSL), $silica(SiO_2)$M, polyvinylidence difluoride(PVDF), silicon nitride, and alumina particles in deionized (DI) water were measured to be -40.5, -31.9, -25.2, -15.1 and -10.1mV, respectively. The particles having high zeta potential less than -20 mV are stable in DI water, because the double layers of them have strong repulsive forces mutually, and the particles having low zeta potential over -20mV are unstable due to Van Der Waals forces. Silica(>20nm), PSL, aluminum and PVDF particles were found to be stable that would remain separate and well disperse, while silicon nitride and alumina particles were found to be unstable that would gradually agglomerate in DI water.

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Stability of W/O and O/W Type Emulsions by Various Solid Particles (다양한 분체를 이용한 W/O와 O/W 형 에멀젼의 안정화)

  • Lee, Sang-Gil;Kim, Young-Ho;Pyo, Hyeong-Bae;Lee, Dong-Kyu
    • Journal of the Korean Applied Science and Technology
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    • v.27 no.3
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    • pp.353-360
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    • 2010
  • This study was carried out to investigate the possibility of solid particles as a stabilizing agent instead of surfactant for preparing emulsions in the cosmetics. The type of emulsions stabilized by solid particles was dependent on wettability of the particles for water and oil. The optimal conditions of emulsions stabilized by solid particles were determined with ratio of water and oil phase, polarity of oils and amount of stabilizers. In the foundation appling the optimal condition of emulsions stabilized by solid particles without surfactant, the stable emulsion type foundation was successfully prepared. As a result, this work indicates that emulsions stabilized by solid particles can be applied to make-up cosmetics.

Cetyl Trimethyl Ammonium Bromide-coated Nickel Ferrite Nanoparticles for Magnetic Hyperthermia and T2 Contrast Agents in Magnetic Resonance Imaging

  • Lee, Da-Aemm;Bae, Hongsubm;Rhee, Ilsum
    • Journal of the Korean Physical Society
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    • v.73 no.9
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    • pp.1334-1339
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    • 2018
  • Spherical nickel ferrite nanoparticles were synthesized using the thermal decomposition method and coated with cetyl trimethyl ammonium bromide (CTAB) after the synthesis. Transmission electron microscopy images showed that the average diameter of the particles was 9.40 nm. The status of the CTAB-coating on the surface of the particles was checked using Fourier-transform infrared spectroscopy. Their hysteresis curve showed that the particles exhibited a superparamagnetic behavior. The $T_1$ and the $T_2$ relaxations of the nuclear spins were observed in aqueous solutions of the particles with different particles concentrations by using a magnetic resonance imaging (MRI) scanner, which showed that the $T_1$ and the $T_2$ relaxivities of the particles in water were $0.57mM^{-1}{\cdot}s^{-1}$ and $10.42mM^{-1}{\cdot}s^{-1}$, respectively. In addition, using an induction heating system, we evaluated their potentials for magnetic hyperthermia applications. The aqueous solution of the particles with a moderate concentration (smaller than 6.5 mg/mL) showed a saturation temperature larger than the hyperthermia target temperature of $42^{\circ}C$. These findings show that the CTAB-coated nickel ferrite particles are suitable for applications as $T_2$ contrast agents in MRI and heat generators in magnetic hyperthermia.

Effect of Si/α-Si3N4 Ratio on the Shape of Silicon Nitride Particles Produced by SHS Method

  • Kim, Min-Sung;Park, Dong-Soo;Han, Byung-Dong;Kim, Hai-Doo;Park, Chan
    • Journal of the Korean Ceramic Society
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    • v.39 no.3
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    • pp.217-221
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    • 2002
  • Si and ${\alpha}-Si_3N_4$ powder mixtures added with 3 wt% $Y_2O_3$ were reacted under 5 MPa nitrogen pressure. The reaction products contained ${\alpha}-Si_3N_4$ particles with elongated shapes. Length and width of the elongated grains were the maximum when the starting powder mixture of 50 wt% Si - 47 wt% ${\alpha}-Si_3N_4$ and 3 wt% $Y_2O_3$ was used. Aspect ratio of the elongated grains were between 4.4 and 5. When the starting powder mixture contained 70 wt% Si, large particles with irregular shapes appeared. Meanwhile, the reaction did not proceed when the starting powder mixture contained 30 wt% Si and less. The SHS product was easy to crush and the elongated particles obtained from the starting powder mixtures of 40 wt% Si - 57 wt% ${\alpha}-Si_3N_4$ - 3 wt% $Y_2O_3$ and 50 wt% Si - 47 wt% ${\alpha}-Si_3N_4$ - 3 wt% $Y_2O_3$ were good candidates for the seeds.

Flow Characteristics of Neutrally Buoyant Particles in 2-Dimensional Poiseuille Flow through Circular Capillaries

  • Kim, Young-Won;Jin, Song-Wan;Yoo, Jung-Yul
    • 한국가시화정보학회:학술대회논문집
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    • 2006.12a
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    • pp.7-10
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    • 2006
  • An experimental study has been conducted to quantitatively characterize the motion of neutrally buoyant particles in 2-dimensional Poiseuille flow through the micron-sized circular capillaries in the range of Re (Reynolds number) $\approx0.1\sim100$. $A{\mu}-PTV$ (Particle Tracking Velocimetry) system is adopted, which consists of a double-headed Nd:YAG laser, an epi-fluorescence microscope and a cooled CCD camera. Since high shear rate can be induced due to the scale effect even at low Re, it is shown that in micro scale neutrally buoyant particles in Poiseuille flow drift away from the wall and away from the center of the capillary. Consequently, particles accumulate at the equilibrium position of $0.52\sim0.64R$ with R being the radius of the capillary, which is analogous to that of tube flow in macro scale. There is a plateau in equilibrium position at small Re, while equilibrium position starts increasing at $Re\approx30$. The outermost edge of particle cluster is closer to the center of the capillary than that in previous studies due to low Re effect. The present study quantitatively presents characteristics of particle motion in circular capillaries. Furthermore, it is expected to give optimum factors for designing microfluidic systems that are to be used fur plasma separation from the blood.

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