• Title/Summary/Keyword: L-curve

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Comparison of linear and non-linear equation for the calibration of roxithromycin analysis using liquid chromatography/mass spectrometry

  • Lim, Jong-Hwan;Yun, Hyo-In
    • Korean Journal of Veterinary Research
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    • v.50 no.1
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    • pp.11-17
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    • 2010
  • Linear and non-linear regressions were used to derive the calibration function for the measurement of roxithromycin plasma concentration. Their results were compared with weighted least squares regression by usual weight factors. In this paper the performance of a non-linear calibration equation with the capacity to account empirically for the curvature, y = ax$^{b}$ + c (b $\neq$ 1) is compared with the commonly used linear equation, y = ax + b, as well as the quadratic equation, y = ax$^{2}$+ bx + c. In the calibration curve (range of 0.01 to 10 ${\mu}g/mL$) of roxithromycin, both heteroscedasticity and nonlinearity were present therefore linear least squares regression methods could result in large errors in the determination of roxithromycin concentration. By the non-linear and weighted least squares regression, the accuracy of the analytical method was improved at the lower end of the calibration curve. This study suggests that the non-linear calibration equation should be considered when a curve is required to be fitted to low dose calibration data which exhibit slight curvature.

Effects of the Low Temperature Vacuum Drying Process on Drying Curve and Physico-Chemical Properties of Astringent Persimmons (저온진공건조 공정에 의한 떫은 감의 건조 및 품질 특성)

  • Hur, Sang-Sun
    • Journal of the Korean Applied Science and Technology
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    • v.33 no.1
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    • pp.58-66
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    • 2016
  • This study was performed to investigate drying characteristics and quality properties of dried persimmon with vacuum drying process. Drying characteristic curve of the dried persimmon showed that the constant rate drying period and falling rate drying period exist definitely. $_{\circ}Brix$, sugar content and hardness value of the dried persimmon increased as the vacuum pressure and heating temperature increased, but L value of the dried persimmon lower. The results indicated that the optimal conditions were at vacuum pressure of 40~50kPa abs., heating temperature of $30^{\circ}C$ and drying time of 3~4days.

Effects of Nutritional Sources on Degradation of Polychlorinated Biphenyls (PCBs) by Pseudomonas sp. P2 (Pseudomonas sp. P2에 의한 Polychlorinated Biphenyls(PCBs) 분해에 대한 영양원의 영향)

  • 최상기;금정호
    • Journal of Environmental Science International
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    • v.5 no.5
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    • pp.611-617
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    • 1996
  • The effects of nutritional sources on growth of Pseudomonas sp. P2 were investigated in medium containing biphentyl as a carbon source. To determine characterization of Pseudomonas sp. P2, the incubation time was determined to 100 h of the log phase in the growth curve. The optimal compositions for the growth of Pseudomonas sp. P2 degrading polychlorinated biphenyls (PCBs) were 1000 mg/L $NH_4NO_3$, 1000mg/L KH_2PO_4$, 100mg/L MgSO_4$.$7H_2O$, 30mg/L $CaCl_2$.$2H_2O$, 200mg/L NaCl, and 10mg/L $FeSO_4$.$7H_2O$. Pseudomonas sp. P2 showed the degradability of 59.3%, 57.6%, 51.4%, and 48.7% at 500mg/L, 1000mg/L, 1500mg/L, and 2000mg/L of the PCBs within insulating oil after 100 h incubation under the optimum conditions, respectively.

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Studies on Efficient Plowing Methods and the Shapes of Field for 4 Wheel Tractor (사수트렉터를 위한 효율적인 정기방법과 포장형상에 관한 연구)

  • 원장우
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.12 no.3
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    • pp.2019-2028
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    • 1970
  • 1. Experiments were made for the efficient plowing method by the 4 wheel tractor, the results are as follow; 1) In case of plowing of inner side of the field, the efficient turning method to be the smallest turning time is the $\Omega$-shaped turning method in the turning distance less than 2r (r is the minimum turning radius of the tractor), and also, it is the U-shaped turning method in the turning distance larger than 2r. 2) 2.5r is most efficient in the unit turning section 'w' on plowing of the inner side of the field. 3) In case of plowing of outer side of the field, intermitted plowing method is efficient in case of W>-0.0345 L + 35.84, and also, semi-followed plowing method is efficient in case of W<-0.0345 L + 35.84. 4) The smaller the width of outer side of outer side of the field 'I' is, the higher is the plowing efficiency, and it is estimated that the minimum value 2r is suitable to 'I' in plowing of inner side and outer side of the field. 2. Study on the correlation between the unit field and plowing efficiencies obtained the following results; 1) plowing efficienies increase generally according as length-width ratio L/W and area A increase. 2) Percent of increase of plowing efficiencies decreases generally according as length-width ratio and area enlarge. 3) The limit that change of T is large owing to L/W is 6 for 20 a, 5 for 30 a, 4 for 50 a, 3 for 80 a, less than 2.5 for 100 a, generally, in L/W-T curve. 4) Rate of change of T-A curve is similar to rate of change of $T=A-\frac{2}{3}$ curve in spite of influence of L/W. 5) In case that length-width ratio is more than 3, effects of increase of 10 a area influenced upon plowing efficiencies are as much as effects of about 5 increase of length width ratio without correlation of size of the field. 6) In case that length-width ratio is 2 to 3, effects of increase of 10 a area influenced upon plowing efficiencies are as much as effects of about 4 to 2 increase of length-width ratio without correlation of size of the field, and the effects decrease according as not only length-width ratio decreases but also area increases, generally.

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Effect of Soil Water Content on Growth, Photosynthetic Rate, and Stomatal Conductance of Kimchi Cabbage at the Early Growth Stage after Transplanting (정식 후 초기 생장기 배추의 생장, 광합성 속도 및 기공전도도에 미치는 토양수분의 영향)

  • Kim, Sung Kyeom;Lee, Hee Ju;Lee, Hee Su;Mun, Boheum;Lee, Sang Gyu
    • Journal of Bio-Environment Control
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    • v.26 no.3
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    • pp.151-157
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    • 2017
  • The objectives of this study were to determine the impact of soil water content on the growth, stomatal conductance, and photosynthesis of Kimchi cabbage and to evaluate proper parameters for development of growth models. There were five levels of irrigation amount treatments (0, 200, 300, 400, and 500 mL/d/plant) and those were commenced at one day after transplanting (DAT). We measured soil water content, stomatal conductance, photosynthesis characteristics, and the A-Ci curve. The growth of Kimchi cabbage as affected by irrigation amount was evaluated at 38 days after transplanting, however, the growth with 0 and 200 mL/d/plant irrigation amount treatments measured at 29 DAT. The relationship between soil water content and stomatal conductance was highly correlated ($r^2=0.999$) and the function represented by y = 6097.4x - 4.2984. The stomatal conductance of Kimchi cabbage leaves showed $300mmol{\cdot}m^{-2}{\cdot}s^{-1}$ when the soil water content was below $0.05m^3/m^3$. The stomatal conductance was rapidly decreased by scarcity of soil moisture. A-Ci curve indicated normal curve in fully irrigation treatment (500 mL/d/plant), however, $CO_2$ couldn't diffuse through the intercellular Kimchi cabbage leaves treated with 0 mL/d/plant. The dry weight of full irrigation treatment was greater approximately 6.8 times than that of deficit irrigation (0 mL/d/plant). In addition, leaf area index showed a logarithmic function (y = 16.573 + 3.398 ln x) with soil water content and that of R-squared represents 0.913. Results indicated that the soil water content was highly correlated with stomatal conductance and leaf area index. Indeed, the scarcity soil moisture reduced photosynthesis and retarded growth.

Study on Behavior Characteristics of L-Type Flange Bolt Connection for Supporting Structures of Wind Turbines (풍력터빈 지지구조물 L형 플랜지 볼트 접합부의 거동 특성에 관한 연구)

  • Jung, Dae-Jin;Hong, Kwan-Young;Choi, Ik-Chang
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.34 no.5
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    • pp.279-286
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    • 2021
  • In this study, we investigated the behavior characteristics of the L-type flange bolt connection, which is used to connect upper and lower flanges having L-type ring sections, by bolts. This connection is mainly used in domestic wind turbine structures, wherein it is a vital component as any imperfection could cause the collapse of the entire structural system. Therefore, understanding the behavior characteristics of the L-type flange bolt connection is imperative. In this study, the connection's response to external force was simulated using finite element (FE) analysis and the FE model was idealized to behave as a single L-type bolt flange. The variation in the bolt tension and the L-type flange stress were analyzed to understand the behavior characteristics of the connection. Moreover, the bolt-load function models proposed by Petersen, Schmidt/Neuper and VDI 2230, theoretically expressing a relation between bolt tension and external force, were compared to evaluate the suitability of the FE analysis and analyze the significant behavior characteristics of the connection. Furthermore, the changes in the bolt-load curve due to the variations in the partial dimensions of the L-type flange bolt connection were analyzed.

Investigation of Water Safety in Non-treated Drinking Water with Trace Toxic Metals

  • Ly, Suw Young;Kim, Dae Hong;Lee, Ga Eun
    • Toxicological Research
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    • v.29 no.3
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    • pp.211-215
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    • 2013
  • The trace toxic metal copper was assayed using mercury immobilized on a carbon nanotube electrode (MCW), with a graphite counter and a reference electrode. In this study, a macro-scale convection motor was interfaced with a MCW three-electrode system, in which a handmade MCW was optimized using cyclic- and square-wave stripping voltammetry. An analytical electrolyte for tap water was used instead of an expensive acid or base ionic solution. Under these conditions, optimum parameters were 0.09 V amplitude, 40 Hz frequency, 0.01 V incremental potential, and a 60-s accumulation time. A diagnostic working curve was obtained from 50.0 to 350 ${\mu}g/L$. At a constant Cu(II) concentration of 10.0 ${\mu}g/L$, the statistical relative standard deviation was 1.78% (RSD, n = 15), the analytical accumulation time was only 60 s, and the analytical detection limit approached 4.6 ${\mu}g/L$ (signal/noise = 3). The results were applied to non-treated drinking water. The content of the analyzed copper using 9.0 and 4.0 ${\mu}g/L$ standards were 8.68 ${\mu}g/L$ and 3.96 ${\mu}g/L$; statistical values $R^2$ = 0.9987 and $R^2$ = 0.9534, respectively. This method is applicable to biological diagnostics or food surveys.

Quantitative analysis of Spirulina platensis growth with CO2 mixed aeration

  • Kim, Yong Sang;Lee, Sang-Hun
    • Environmental Engineering Research
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    • v.23 no.2
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    • pp.216-222
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    • 2018
  • The growth characteristics of Spirulina platensis were investigated using four photo-bioreactors with $CO_2$-mixed air flows. Each reactor was operated under a specific condition: 3% $CO_2$ at 50 mL/min, 3% $CO_2$ at 150 mL/min, 6% $CO_2$ at 50 mL/min, and 6% CO2 at 150 mL/min. The 3% $CO_2$ at 150 mL/min condition produced the highest algal growth rate, while the 6% $CO_2$ at 150 mL/min conditioned produced the lowest. The algal growth performance was suitably assessed by the linear growth curve rather than the exponential growth. The medium pH decreased from 9.5 to 8.7-8.8 (3% $CO_2$) and 8.4-8.5 (6% $CO_2$), of which trends were predicted only by the pH-carbonate equilibrium and the reaction kinetics between dissolved $CO_2$ and $HCO_3{^-}$. Based on the stoichiometry between the nutrient amounts and cell elements, it was predicted that depleted nitrogen (N) at the early stage of the cultivation would reduce the algal growth rates due to nutrient starvation. In this study, use of the photobioreactors capable of good light energy distribution, proper ranges of $CO_2$ in bubbles and medium pH facilitated production of high amounts of algal biomass despite N limitation.

Breakthrough modeling of furfural sorption behavior in a bagasse fly ash packed bed

  • Singh, Saurabh;Srivastava, Vimal Chandra;Goyal, Akash;Mall, Indra Deo
    • Environmental Engineering Research
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    • v.25 no.1
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    • pp.104-113
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    • 2020
  • Adsorptive breakthrough modelling is essential for design of a sorption packed bed. In this work, breakthrough modelling of the furfural uptake in bagasse fly ash (BFA) packed bed has been performed. Effect of various parameters like bed height (Z = 15-60 cm), flow rate (Q = 0.02-0.04 L/min) and initial furfural concentration (Co = 50-200 mg/L) on the breakthrough curve of furfural sorption in a BFA packed bed have been studied. Enhanced breakthrough performance was observed for the higher value of Z, and lower values of Co and Q. For Co = 100 mg/L, packed bed operated at Q = 0.03 L/min and Z = 60 cm was found to have lowest adsorbent utilization rate of 5.61 g/L with highest breakthrough volume of 14.67 L. Bed depth service time and Thomas models well represented the experimental data points under all experimental conditions. It can be concluded that BFA can be utilized efficiently in continuous system for the removal of furfural. Overall, more than 99% of furfural was adsorbed in BFA packed bed at experimental conditions.

Evaluation of Mechanical Properties and Microstructure of Thermally Aged 308 and 316L Stainless Steel Welds (가속 열시효에 따른 308 및 316L 스테인리스강 용접부의 기계적 물성 및 미세구조 평가)

  • Kong, Byeong Seo;Hong, Sunghoon;Jang, Changheui;Kim, Maan-Won
    • Transactions of the Korean Society of Pressure Vessels and Piping
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    • v.13 no.1
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    • pp.92-100
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    • 2017
  • Due to the presence of ferrite phase in the finished welds, austenitic stainless steel welds (ASSWs) are considered susceptible to the thermal aging embrittlement during long-term service in light water reactor environment. In this study, the thermal aging embrittlement of typical ASSWs, E308 and ER316L welds, were evaluated after the long-term exposure up to 20,000 h at $400^{\circ}C$, which is considered as an accelerated thermal aging condition. After thermal aging, the decrease of tensile ductility and fracture toughness was observed. The microstructure observation with high resolution transmission electron microscopy revealed that spinodal decomposition in ferrite phase of both E308 and ER316L welds would be the main cause of the degradation of mechanical properties. Also, it was shown that the difference of thermal ageing embrittlement between ER316L and E308 welds was significant, such that the reduction of fracture resistance for ER316L weld was much larger than that of E308 weld.