• Journal of Korean Society of Rural Planning
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• v.8 no.2 s.16
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• pp.3-16
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• 2002

의사결장지원시스템은 다양한 분야에 적용되어 왔으며, 그 중 수자원 및 수질 관련 분야에도 다각적으로 적용되어 왔다. 본 연구에서는 미 농무성의 자연자원보전국(NRCS, Natural Resources Conservation Service)에서 개발한 유출곡선법(Curve Number Method)과 EMC(Event Mean Concentration)을 사용한 L-THIA(Long-Term Hydrologic Impact Assessment) 수문/수질 모형을 강우자료 데이터베이스, 웹기반 지리정보시스템, 웹 사용자 편의 시스템과 통합한 수문/수질 L-THIA web 의사결정지원시스템을 개발하였다. L-THIA web은 도시계획가나 지방자치단체, 또는 지방의 공동체가 사용할 수 있도록 쉽고 단순한 사용자 편의 시스템을 제공하고 있으며, 미국의 50개 본토의 주와 카운티(County) 이름으로 기상자료와 수문토양분류(Hydrologic Soil Group)을 인터넷 지리정보시스템을 이용하여 제공하고 있다. 본 연구는 지방자치단체 및 지역공동체의 실무자를 사용자로 수문/수질 평가 및 관리를 위한 시스템으로 유용하게 활용될 수 있을 것으로 사료된다.

• Proceedings of the Korea Water Resources Association Conference
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• 2010.05a
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• pp.1134-1138
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• 2010

호소의 수질오염 문제를 해결하기 위해선 우선 소하천에서 강우유출에 의한 비점오염물질이 어디서 얼마나 발생하는지에 대한 정량적인 조사가 필요하다. 그러나 유역의 오염원에 대한 정량적인 조사가 이루어지려면 많은 비용과 시간 그리고 노력이 필요하다. 따라서 본 연구에서는 대청호 상류유역의 소하천인 안내천을 대상으로 강우유출수 조사를 실시하고, 높은 예측 정확성 때문에 세계적으로 널리 쓰이고 있는 Long-Term Hydrologic Impact Assessment(L-THIA)을 이용하여 실측데이터와 L-THIA 모델의 결과를 비교하였다. 안내천의 유역면적은 16.5 $km^2$로 유역의 약 69.5%가 산림, 농업 및 초지지역이 25.3% 그리고 주거지역이 2.6%로 조사되었다. 수질분석을 위하여 자동수질시료채취기(ISCO sampler 6712)를 설치하여 시간단위의 시료를 채취한 뒤 수질농도를 측정하였다. 수질항목은 유기물질인 $BOD_5$, TOC, T-N, T-P 항목에 대하여 수질오염 공정시험법으로 분석하였다. WHAT 시스템을 이용하여 분리된 직접유출량은 315.5~161,835.1 $m^3$의 범위로 나타났다. 직접유출량을 이용하여 산정한 유역의 EMC 농도는 안내천 유역의 $EMC_{BOD}$는 1.0~2.4 mg/L, $EMC_{TOC}$는 1.429~5.491 mg/L, $EMC_{COD}$는 2.2~10.2 mg/L, $EMC_{TN}$은 2.906~10.864 mg/L, $EMC_{TP}$는 0.029~0.285 mg/L의 범위를 보였다. 또한 실측된 유량과 농도를 이용하여 산정한 오염부하는 안내천 유역이 $BOD_5$ 37.9~390.9 g, $COD_{Mn}$ 0.8~1,657.5 g, TOC 0.54~791.83 g, T-N 0.968~1,758.174 g, T-P 0.011~42.139 g의 범위로 나타났다. L-THIA 모델을 이용하여 직접유출량의 산정된 결과와 실측 결과를 비교 분석한 결과 결정계수와 유효지수가 0.95와 0.93으로 높게 나타나 대청호 상류유역에서 발생하는 유출량을 모의하는데 적절할 것으로 판단된다. 토지이용도와 토양도 그리고 일 강우자료만으로 구축되는 L-THIA 모델을 이용하여 대청호 상류의 소하천 유역에 대하여 비점오염원 유출특성을 해석하는 것이 가능 할 것으로 판단된다.

• Journal of Korean Society on Water Environment
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• v.23 no.6
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• pp.897-905
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• 2007

Approximately 70% of Korea is composed of forest areas. Especially 48% of agricultural field is practiced at highland areas over 400 m in elevation in Kangwon province. Over 90% of highland agricultural farming is located at Kangwon province. Runoff characteristics at the mountainous area such as Kangwon province are largely affected by steep slopes, thus runoff estimation considering field slopes needs to be utilized for accurate estimation of direct runoff. Although many methods for runoff estimation are available, the Soil Conservation Service (SCS), now Natural Resource Conservation Service (NRCS), Curve Number (CN)-based method is used in this study. The CN values were obtained from many plot-years dataset obtained from mid-west areas of the United States, where most of the areas have less than 5% in slopes. Thus, the CN method is not suitable for accurate runoff estimation where significant areas are over 5% in slopes. Therefore, the CN values were adjusted based on the average slopes (25.8% at Doam-dam watershed) depending on the 5-day Antecedent Moisture Condition (AMC). In this study, the CN-based Long-Term Hydrologic Impact Assessment (L-THIA) direct runoff estimation model used and the Web-based Hydrograph Analysis Tool (WHAT) was used for direct runoff separation from the stream flow data. The $R^2$ value was 0.65 and the Nash-Sutcliffe coefficient value was 0.60 when no slope adjustment was made in CN method. However, the $R^2$ value was 0.69 and the Nash-Sutcliffe value was 0.69 with slope adjustment. As shown in this study, it is strongly recommended the slope adjustment in the CN direct runoff estimation should be made for accurate direct runoff prediction using the CN-based L-THIA model when applied to steep mountainous areas.

• Bulletin of the Korean Chemical Society
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• v.20 no.3
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• pp.276-280
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• 1999

The different core-modified porphyrins 21-thia-23-carba-12-aza-5,10-dimesityl-15,20-diphenylporphyrin (6), and their N(12)-methyl derivatives (8) were synthesized by acid-catalyzed [3+1] condensation of the corresponding 16-thia-5,10-dimesityltripyrromethanes and 2,4-bis[(α-hydroxy-α-phenyl)methyl]pyrrole. Spectroscopic evidence indicates the existence of two different tautomeric forms at room temperature in porphyrin (6). A third form of tautomer was observed when the temperature was lowered to 223 K. The most stable tautomer is one in which the nitrogenic proton resides outside the core of the macrocycle. The ratio of the three different tautomers (outer N-H/ two inner N-H, i.e. 6/12/13) was 1/l/0.5 in the case of (6) while the ratio of 1/l/0.3 was observed in the case of (10). In the case of 21-oxa-23-carba-12-aza-5,10,15,20-tetraphenylporphyrin (7), the only stable tautomeric form observed by 1H NMR was the one that nitrogenic proton resides inside the core on

• The Korean Journal of Pesticide Science
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• v.7 no.4
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• pp.310-313
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• 2003

New series of 9-(5-Isoxazolemethoxyphenyl)imino-8-thia-l,6-diazabicyclo[4.3.0]nonan-7-one which are the cyclic imide type compounds were designed and synthesized. The herbicidal activities of main dominant weeds to these compounds were evaluated under rice field condition. There is the possibility for a new herbicide since the most of compounds were excellent to main dominant weeds occurring in rice field without the serious rice injury.

• Bulletin of the Korean Chemical Society
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• v.19 no.9
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• pp.897-906
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• 1998

A new synthesis has been developed for 1-thia-4,7-diazacyclononane and the complexation behavior of a particular derivative has been explored. The pentadentate ligand 4,7-bis(2-pyridylmethyl)-l-thia-4,7-diazacyclononane ([9]$N_2SPY_2$) and its iron(Ⅱ) and manganese(Ⅱ) complexes were prepared and characterized. Magnetic moments of 5.17 and 5.90 μB respectively, indicate that the iron(Ⅱ) and manganese(Ⅱ) complexes are high spin. Charge transfer transitions (d-π*) occur for [Fe(Ⅱ)([9]$N_2SPY_2)(X)]^{n+}$at 27027, 25000, and 24390 cm-1 for X=$H_2O$, Cl-, and OH-, respectively. In acetonitrile solution, the cyclic voltammogram of the manganese(Ⅱ) complex exhibits a redox couple at 0.92 V vs. NHE while the redox potentials for [Fe(Il)([9]$N_2SPY_2)(X)]^{n+}$ are 0.70, 0.66, and 0.37 V vs. NHE for X=$H_2O$, Cl-, and OH-, respectively. The d-π* charge transfer energy and Fe(Ⅱ)/Fe(Ⅲ) redox potential for [Fe(Ⅱ)([9]$N_2SPY_2)(X)]^{n+}$ increase in the same order: $H_2O>Cl^- >OH^-$. The crystal structures of the iron(Ⅱ) and manganese(Ⅱ) complexes reveal that the metal ions are sixcoordinate, binding to four nitrogen atoms and a sulfur atom from the pentadentate ligand, as well as a chloride anion, with the chloride and sulfur atoms in cis positions. The two metals have similar coordination geometries, which are closer to trigonal prismatic than octahedral. In both iron and manganese complexes, the M-N($sp_3$) trans to Cl- is 0.07 Å longer than the one cis to Cl- , and M-N($sp^2$) trans to S is 0.05 longer than the one cis to S atom.

• Journal of Microbiology and Biotechnology
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• v.6 no.2
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• pp.92-97
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• 1996

Portage kinetic constants of peptide transport can be measured by competitive spectrophotometry. The kinetic constants of L-Glu-L-Glu transport in Escherichia coli were ascertained using L-Phe-L-3-thia-Phe (PSP) as a detector. Since the production of thiophenol upon intracellular hydrolysis of PSP was competitively inhibited by L-Glu-L-Glu, it was able to compute the kinetic constants of L-Glu-L-Glu using this method. The resulted data were in agreement with the values obtained by the method of Michaelis-Menten kinetics. The potential of this method was examined against dipeptide transport systems in various microorganisms. These results strongly suggest that the overall properties of individual systems for dipeptide transports can be easily characterized by competitive spectrophotometry.

• Journal of Microbiology and Biotechnology
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• v.15 no.4
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• pp.899-902
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• 2005

Peptide assimilation by Helicobacter pylori was investigated using L-phenylalanyl-3-thia-phenylalanine (PSP) as a detector peptide; the release of thiophenol upon enzymatic hydrolysis of PSP was spectrophotometrically detected with the aid of 5,5'-dithiobis[2-nitrobenzoic acid] (DTNB). By adding PSP to whole-cell suspension, thiophenol was produced progressively, resembling that found in Esherichia coli or Staphylococcus aureus. Interestingly, the rate of thiophenol production by H pylori in particular was markedly reduced when cells were pretreated with trypsin, indicating surface exhibition of peptidase. According to the competitive spectrophotometry using alanyl-peptides, H pylori did not appear to assimilate PSP through the peptide transport system. No discernible PSP assimilation could be ascertained in H pylori cells, unless provided with some additives necessary for peptidase activity, such as $Ni^{2+}\;or\;Mg^{2+}$ and an appropriate concentration of potassium or ammonium salts. These observations strongly suggest that, regardless of a presumptive peptide transport system, peptide assimilation of H. plori appears to be highly dependent upon milieu conditions, due to unique peptidase exhibition on the cell surface.

• Applied Chemistry for Engineering
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• v.19 no.1
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• pp.51-58
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• 2008

A series of oleic acid esters containing mercaptobenzothiazole and dialkylenedithiocarbamate, which are potential environmentally friendly lubricating grease additives, were synthesized as 90% yield through several method such as nucleophilic substitution of dialkyl amine and carbon disulfide, reduction reaction, and condensation reaction. The structures of the additives were confirmed by $^1H$-NMR, FT-IR and EA analysis. The additives (1 wt%) were soluble in 100 N BO except C4-DTC-OE and soluble in soybean oil. The tribological properties as lubricating additives in 100 N BO were evaluated using 4-ball tester and the results showed as follows: Bz-thia-OE < C4-DTC-OE < Pyrro-DTC-OE < C8-DTC-OE. Whereas, the 4-ball anti-wear properties were not shown in soybean oil.

• Journal of Korean Society on Water Environment
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• v.25 no.2
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• pp.245-255
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• 2009

CN values are changed by various surface condition, which is cover type or treatment, hydrologic condition, or percent impervious area, even the same combination of land use and hydrologic soil group. In this study, CN parameters were regionalized for Nakdong River Basin by Long-Term Hydrologic Impact Assessment (L-THIA) coupled with SCE-UA, which is one of the global optimization technique. Six watersheds were selected for calibration (optimization) and periodic validation and two watersheds for spatical validation as ungauged watershed within Nakdong River Basin. Nash-Sutcliffe (NS) values were 0.66~0.86 for calibration, 0.68~0.91 for validation, and 0.60 and 0.85 for ungauged watersheds, respectively. Urban area for the selected watersheds covered high impervious area with 85% for residential area and 92% for commercial/industrial/transportation area. Hydrologic characteristics for crop area was similar to row crop with contoured treatment and poor hydrologic condition. For the forested area, hydrologic characteristics could be clearly distinguished from the leaf types of plant. Deciduous, coniferous, and mixed forest showed low, moderate, and high runoff rates by representing wood with fair and poor hydrologic condition, and wood-grass combination with fair hydrologic condition, respectively. CN parameters from this study could be strongly recommended to be used to simulate runoff for ungauged watershed.