• Title/Summary/Keyword: L-A-S

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Preparation and Crystal Structures of Silver(I), Mercury(II), and Lead(II) Complexes of Oxathia-Tribenzo-Macrocycles

  • Siewe, Arlette Deukam;Ju, Huiyeong;Lee, Shim Sung
    • Bulletin of the Korean Chemical Society
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    • v.34 no.3
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    • pp.725-730
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    • 2013
  • An investigation of the coordination behavior of sulfur-containing mixed-donor tribenzo-macrocycles $L^1-L^3$ ($L^1$: 20-membered $O_3S_2$, $L^2$: 20-membered $O_2S_3$, and $L^3$: 23-membered $O_4S_2$) with $d^{10}$-metal ($Ag^+$, $Hg^{2+}$, and $Pb^{2+}$) salts is reported. The X-ray structures of five complexes (1-5) with different structural types and stoichiometries, including mono- to dinuclear species have been determined. Reactions of $L^2$ and $L^3$ with the silver(I) salts ($PF_6{^-}$ and $SCN^-$) afforded two dinuclear 2:2 (metal-to-ligand) complexes with different arrangements: a sandwich-type cyclic dinuclear complex $[Ag_2(L^2)_2](PF_6)_2{\cdot}3CH_2Cl_2$ (1) and a linear dinuclear complex $[Ag_2(L^3)_2(SCN)_2]$ (2), in which two monosilver(I) complex units are linked by an Ag-Ag contact. Reactions of $L^1$ and $L^2$ with mercury(II) salts ($SCN^-$ and $Cl^-$) gave a mononuclear 1:1 complexes $[Hg(L^1)(SCN)_2]$ (3) and $[Hg(L^2)Cl_2]$ (4) with anion coordination in both cases. $L^2$ reacts with lead(II) perchlorate to yield a mononuclear sandwich-type complex $[Pb(L^2)_2(ClO_4)_2]$ (5), giving an overall metal coordination geometry of eight with a square antiprism arrangement. From these results, the effects of the donor variation and the anioncoordination ability on the resulting topologies of the soft metal complexes are discussed.

Genetic Transformation of Microtuber Disk of Potato(Solanum Tuberosum) by Agrobacterium Tumefaciens (Agrobacterium tumefaciens에 의한 Microtuber 감자 (Solanum tuberosum) 절편(切片)의 유전적(遺傳的) 형질전환(形質轉換)에 관한 연구(硏究))

  • Lee, Young Bok;Seong, Bong Jae;Lee, Eun Gyoung;Lee, Ki Won;Choi, Kwan Sam
    • Korean Journal of Agricultural Science
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    • v.20 no.2
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    • pp.133-144
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    • 1993
  • Calli were induced on microtuber disks of potato(S.tuberosum) infected with three binary vectors transconjugated with C58, A281 and LBA 4404 of Agrobacterium tumefaciens and pBI121. The frequency inducing callus was the highest by infection of C121 carrying pC58 and pBI121, and shoots were differentiated on the calli without any hormonal application. Transformed calli were selected by their resistance to kanamycin and identified by GUS activity. The frequency of callus formation by infection of binary vector strain was affected according to the hormonal application.

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A reducible case of double hypergeometric series involving the riemann $zeta$-function

  • Park, Junesang;H. M. Srivastava
    • Bulletin of the Korean Mathematical Society
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    • v.33 no.1
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    • pp.107-110
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    • 1996
  • Usng the Pochhammer symbol $(\lambda)_n$ given by $$ (1.1) (\lambda)_n = {1, if n = 0 {\lambda(\lambda + 1) \cdots (\lambda + n - 1), if n \in N = {1, 2, 3, \ldots}, $$ we define a general double hypergeometric series by [3, pp.27] $$ (1.2) F_{q:s;\upsilon}^{p:r;u} [\alpha_1, \ldots, \alpha_p : \gamma_1, \ldots, \gamma_r; \lambda_1, \ldots, \lambda_u;_{x,y}][\beta_1, \ldots, \beta_q : \delta_1, \ldots, \delta_s; \mu_1, \ldots, \mu_v; ] = \sum_{l,m = 0}^{\infty} \frac {\prod_{j=1}^{q} (\beta_j)_{l+m} \prod_{j=1}^{s} (\delta_j)_l \prod_{j=1}^{v} (\mu_j)_m)}{\prod_{j=1}^{p} (\alpha_j)_{l+m} \prod_{j=1}^{r} (\gamma_j)_l \prod_{j=1}^{u} (\lambda_j)_m} \frac{l!}{x^l} \frac{m!}{y^m} $$ provided that the double series converges.

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KINEMATICS AND CHEMISTRY OF THE S140/L1204 MOLECULAR COMPLEX

  • Park, Yong-Sun;Minh, Young-Chul
    • Journal of The Korean Astronomical Society
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    • v.28 no.2
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    • pp.255-264
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    • 1995
  • The HII region S140 and the associated molecular cloud L1204 have been observed with 10 molecular transitions, CO (1-0), $^{13}CO$ (1-0), $C^{18}O$ (1-0), CS (2-1), $HCO^+$ (1-0), HCN (1-0), SO (${2_2}-{1_1}$), $SO_2(2_{20}-3_{13})$, OCS (8-7), and $HNCO\;(4_{04}-3_{03})$ with ${\sim}50"$ angular resolutions. More than 7,000 spectra were obtained in total. The morphology of this region shows a massive fragment (the S140 core) and the extended envelope to the northeast. Several gas condensations have been identified in the envelope, having masses of ${\sim}10^{3}M_{\odot}$ and gas number densities of ${\lesssim}10^{4}cm^{-3}$ to $3{\times}10^{5}cm^{-3}$ in their cores. The column densities of the observed molecular species toward the S140 core appear to be the typical warm clouds' abundances. It seems to be that the S140 core and L1204 have been swept up by an expanding shell called the Cepheus bubble. The large value of $L_{IR}$(embedded\;stars)/$M_{cloud}\;{\sim}\;5\;L_{\odot}$/$M_{\odot}$ of the S140 core may suggest that the star formation has been stimulated by the HII region, but the shock velocity and the pressure of the region seem to give a hint of the spontaneous star formation by the self gravity.

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Study of Gungguitakli-San on the Anti-Cancer in L1210 and S-180 cells Transplanted Mice (궁귀탁리산(芎歸托裏散)의 L1210과 S-180이 이식된 마우스에 대한 항암(抗癌) 작용(作用) 연구(硏究))

  • Park, Su-Yeon;Kim, Jong-Han;Choi, Jung-Hwa;Park, Yong-Ho
    • The Journal of Korean Medicine Ophthalmology and Otolaryngology and Dermatology
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    • v.19 no.1
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    • pp.55-64
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    • 2006
  • Objective : The purpose of this study was to investigate effect of Gungguitakli-San(GTS) on the anti-tumor, immunocytes. Methods : This study estimated the proliferation of L1210 and S-180 cell lines, mouse splenocytes and thymocytes in vitro, and estimated the proliferation of L1210 cell, S-180 cell, thymocytes and splenocytes and body weight in S-180 cells-transplanted mice. The cytotoxicity and proliferation of cells were tested using a colorimetric tetrazoliun assay(M1T assay). Results : The results of this study were obtained as follow ; 1. GTS was significantly increased in the proliferation of thymocytes and splenocytes In vitro. 2. GTS was significantly showed cytotoxicity on the L1210 cell lines and 8-180 cell lines in vitro. 3. GTS was significantly showed cytotoxicity on the L1210 cell lines in vivo. 4. GTS was significantly increased in the weight of mice and decreased weight of sarcoma, in S-180 cells transplanted mice. 5. GTS was significantly increased in the period of survive, in S-180 cells transplanted mice. Conclusions : The author thought that GTS had action of anti-cancer by becoming immunocytes activity and by cytotoxicity of cancer cells.

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Quality Characteristics and Antioxidant Activities of Noodles added with Spergularia marina L. Griseb Powder (세발나물 분말 첨가 국수의 품질 특성 및 항산화 활성)

  • Chang, Hyesun;Kim, Minseon;Kim, Minzy;Lee, Jisuk;Kim, Yaeboon;Sim, Ki Hyeon
    • Journal of the East Asian Society of Dietary Life
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    • v.27 no.1
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    • pp.50-60
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    • 2017
  • This study evaluated the quality characteristics and antioxidant activities of Spergularia marina L. Griseb powder from halophyte plants added to noodles at ratios of 0%, 0.5%, 1.0%, 1.5%, and 2.0% in order to examine its applicability as a substitute for salt. For quality characteristics of noodles with Spergularia marina L. Griseb powder, pH increased (p<0.05) and salinity decreased (p<0.01) with higher added Spergularia marina L. Griseb powder content. Water absorption ratio decreased (p<0.01) while turbidity decreased (p<0.001) with greater addition of Spergularia marina L. Griseb powder. However, volume expansion ratio increased with greater addition of Spergularia marina L. Griseb powder, but there was no significant difference. For chromaticity, L value and a value decreased (p<0.001) while b value increased (p<0.001) with greater addition of Spergularia marina L. Griseb powder. For texture, hardness (p<0.001), gumminess (p<0.001), and cohesiveness (p<0.01) increased with greater amount of added Spergularia marina L. Griseb powder; however, there were no significant differences in adhesiveness, springiness, and chewiness according to the amount of added Spergularia marina L. Griseb powder. In the sensory evaluation, for color, the score was 5.55 points when 1.5% Spergularia marina L. Griseb powder was added, which was the best preference (p<0.001); for flavor, preference was best (5.64 points) when 2.0% Spergularia marina L. Griseb powder was added; for taste, preference was best (5.36 points) (p<0.001) when 2.0% Spergularia marina L. Griseb powder was added; for overall preference (overall quality) the score was 5.55 points when 1.0% Spergularia marina L. Griseb powder was added, which was the best preference (p<0.001). For antioxidant activities, antioxidant activities including total phenol content, total flavonoid content, and DPPH free radical scavenging activity increased (p<0.001) with the amount of added Spergularia marina L. Griseb powder. As a result of the above research, preference was the highest and quality was excellent overall when 1.0% Spergularia marina L. Griseb powder was added. Thus, addition of 1.0% Spergularia marina L. Griseb instead of salt would be desirable.

Production of Rosmarinic Acid, Lithospermic Acid B, and Tanshinones by Suspension Cultures of Ti-Transformed Salvia miltiorrhiza Cells in Bioreactors

  • Zhong, Jian-Jiang;Hui Chen;Feng Chen
    • Journal of Plant Biotechnology
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    • v.3 no.2
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    • pp.107-112
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    • 2001
  • The kinetics of Ti-transformed Salvia miltiorrhiza cell cultures was studied in 250-$m\ell$ shake flasks by using B5 medium with addition of 30 gfL of sucrose. In the cell cultures, the maximum cell mass obtained was 11.5 g DW/L on day 15. The highest amount of phenolic compounds - rosmarinic acid (RA) and lithospermic acid B (LAB) reached 871.3 mg/L (day 15) and 121.3 mg/L (day 13), respectively. The total tanshinone production, i.e., intracellular plus extracellular cryptotanshinone, tanshinone 1, and tanshinone IIA, was 5.3 mg/L on day 13. For the cultivations in 2.4-L stirred bioreactors, the residual sugar level and medium conductivity were a little higher in a small turbine impeller reactor ($T_s$) than those in a large turbine impeller reactor ($T_L$), while a higher cell density was obtained in the $T_L$. For the production of tanshinones and phenolics, better results were obtained in the $T_L$ than in the $T_s$. In the $T_L$, similar or even a little higher production titers of tanshinones and phenolic compounds were achieved compared to those in the flasks. The results suggest that the shake flask results could be successfully scaled up to the $T_L$ reactor. Such a large impeller reactor like $T_L$ may be better than a small impeller one for the large-scale production of the valuable metabolites by the suspension cultures of Ti transformed S.miltiorrhiza cells. This is considered due to the beneficial culture environment in the $T_L$, such as low shear rates as estimated theoretically.

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Isolation and Identification of Antioxidant from Oriental Therapeutic Drug for Hepatitis B (간염 치료제인 민간제제에서 항산화 물질의 분리 및 확인)

  • 김승호;이종우;함경수
    • Microbiology and Biotechnology Letters
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    • v.21 no.2
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    • pp.171-175
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    • 1993
  • The antioxidant in the oriental drug, NP-S, traditionally used as a therapeutic agent for Hepatitis B was identified. The NP-S was divided into two fractions at molecular weight cut-off of 1000 by ultrafiltration and the fraction having molecular weight less than 1000 was named as NP-S(l)10. Both NP-S and NP-S(l)10 had antioxidant activity. An antioxidant that was extracted by chloroform from water-insoluble fraction in lyophilized NP-S(l)10 had a little smaller activity than NP-S(l)10 and identified as cyclooctasulfur(S8) by mass spectrum.

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Extreme Points, Exposed Points and Smooth Points of the Space 𝓛s(2𝑙3)

  • Kim, Sung Guen
    • Kyungpook Mathematical Journal
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    • v.60 no.3
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    • pp.485-505
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    • 2020
  • We present a complete description of all the extreme points of the unit ball of 𝓛s(2𝑙3) which leads to a complete formula for ║f║ for every f ∈ 𝓛s(2𝑙3). We also show that $extB_{{\mathcal{L}}_s(^2l^3_{\infty})}{\subset}extB_{{\mathcal{L}}_s(^2l^n_{\infty})}$ for every n ≥ 4. Using the formula for ║f║ for every f ∈ 𝓛s(2𝑙3), we show that every extreme point of the unit ball of 𝓛s(2𝑙3) is exposed. We also characterize all the smooth points of the unit ball of 𝓛s(2𝑙3).

A Method of Interoperating Heterogeneous Simulation Middleware for L-V-C Combined Environment (L-V-C 통합 환경 실현을 위한 이기종 시뮬레이션 미들웨어 연동 방안)

  • Cho, Kunryun;No, Giseop;Jung, Sihyun;Keerativoranan, Nopphon;Kim, Chongkwon
    • Journal of KIISE
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    • v.42 no.2
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    • pp.213-219
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    • 2015
  • Simulation is used these days to verify the hypothesis or the new technology. In particular, National Defense Modeling & Simulation (M&S) is used to predict wartime situation and conduct the military training. National Defense M&S can be divided into three parts, live simulation, virtual simulation, and constructive simulation. Live simulation is based on the real environment, which allows more realistic sumulation; however, it has decreased budget efficiency, but reduced depictions of reality. In contrast, virtual and constructive simulations which are based on the virtual environment, have increased budget efficiency, but reduced depictions of reality. Thus, if the three parts of the M&S are combined to make the L-V-C combined environment, the disadvantages of each simulation can be complemented to increases the quality of the simulation. In this paper, a method of interworking heterogeneous simulation middeware for L-V-C combined environment is proposed, and the test results of interworking between Data Distribution Service (DDS) and High Level Architecture (HLA) are shown.