• Title/Summary/Keyword: Krypton

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Importance of convection during physical vapor transport of Hg2Cl2 in the presence of Kr under environments of high gravitational accelerations

  • Kim, Geug-Tae
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.22 no.1
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    • pp.29-35
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    • 2012
  • Special attention in the role of convection in vapor crystal growth has been paid since some single crystals under high gravity acceleration of $10g_0$ appear considerably larger than those under normal gravity acceleration ($1g_0$). With increasing the gravity acceleration from $1g_0$ up to $10g_0$, the total molar flux for ${\Delta}T$ = 30 K increases by a factor of 4, while for ${\Delta}T$ = 90, by a factor of 3. The maximum molar fluxes for three different gravity levels of $1g_0$, $4g_0$ and $10g_0$, appear approximately in the neighborhood of y = 0.5 cm, and the molar fluxes show asymmetrical patterns, which indicate the occurrence of either one single or more than one convective cell. As the gravitational level is enhanced form $1g_0$ up to $10g_0$, the intensity of convection is increased significantly through the maximum molar fluxes for ${\Delta}T$ = 30 K and 90 K. At $10g_0$, the maximum total molar flux is nearly invariant for for ${\Delta}T$ = 30 K and 90 K. The total molar flux increases with increasing the gravity acceleration, for $1g_0{\leq}g_y{\leq}10g_0$, and decreases with increasing the partial pressure of component B, a noble gas called as Kr (Krypton), $P_B$. The ${{\mid}U{\mid}}_{max}$ is directly proportional to the gravity acceleration for 20 Torr $P_B{\leq}300$ Torr. As the partial pressure of $P_B$ (Torr) decreases from 300 Torr to 20 Torr, the slopes of the ${{\mid}U{\mid}}_{max}s$ versus the gravity accelerations increase from 0.29 sec to 0.54 sec, i.e. by a factor of 2. The total molar flux of $Hg_2Cl_2$ is first order exponentially decayed with increasing the partial pressure of component B, $P_B$ (Torr) from 20 Torr up to 300 Torr.

Spectra of Optical-field Ionized Gases by a Femtosecond Ti:Sapphire Laser

  • Mock, Tomas;Shin, Hyun-Joon;Cha, Yong-Ho;Lee, Dong-Gun;Hong, Kyung-Han;Nam, Chang-Hee
    • Journal of the Optical Society of Korea
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    • v.2 no.2
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    • pp.50-53
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    • 1998
  • We report on the spectroscopic investigation of optical-field ionized plasmas in the soft X-ray spectral region. The experiment was carried out by focusing pulses of the high-power Ti:Sapphire laser with an energy of ~ 40 mJ and time duration of ~30 fs into a gas jet of krypton, xenon, and argon from a pulsed nozzle. Strong soft X-ray emission on lines from ionic stages of $Kr^{7+} , Kr^{8+} , Xe^{7+} , Ar^{7+} , and Ar^{8+}$ is reported. The experimental result was found to be in good agreement with theoretical prediction.

Factors Affecting the Minimum Detectable Activity of Radioactive Noble Gases (방사성 노블가스 측정을 위한 최소검출방사능 산출의 조절인자)

  • Park, Ji-young;Ko, Young Gun;Kim, Hyuncheol;Lim, Jong-Myoung;Lee, Wanno
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.16 no.3
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    • pp.301-308
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    • 2018
  • Anthropogenic radioactive noble gases formed by nuclear fission are significant indicators used to monitor the nuclear activity of neighboring countries. In particular, radioactive xenon, owing to its abundant generation and short half-life, can be used to detect nuclear testing, and radioactive krypton has been used as a tracer to monitor the reprocessing of nuclear fuels. Released radioactive noble gases are in the atmosphere at infinitesimal amounts due to their dilution in the air and their short half-life decay. Therefore, to obtain reliable and significant data when performing measurement of noble gases in the atmosphere, the minimum detectable activity (MDA) for noble gases should be defined as low as possible. In this study, the MDA values for radioactive xenon and krypton were theoretically obtained based on the BfS-IAR system by collecting both noble gases simultaneously. In addition, various MDA methods, confidence level and analysis conditions were suggested to reduce and optimize MDA with an assessment of the factors affecting MDA. The current investigation indicated that maximizing the pretreatment efficiency and performance maintenance of the counter were the most important aspects for Xe. In the case of Kr, since sample activities are much higher than those of Xe, it is possible to change the target MDA or to simplification of the analysis system.

Comparison of Lung Ventilation Scan Using Technegas and $^{99m}Tc-DTPA$ Aerosol (Technegas 환기스캔과 $^{99m}Tc-DTPA$ Aerosol 스캔의 비교)

  • Choi, Yoon-Ho;Kim, Sang-Eun;Lee, Dong-Soo;Chung, June-Key;Lee, Myung-Chul;Kim, Keun-Youl;Koh, Chang-Soon;Koong, Sung-Soo
    • The Korean Journal of Nuclear Medicine
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    • v.24 no.2
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    • pp.237-243
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    • 1990
  • Pulmonary embolism demands rapid and accurate diagnosis. And ventilation imaging has greatly improved the diagnostic accuracy of pulmonary embolism in addition to perfusion imaging. Agents currently used include xenon-133, krypton-81m and technetium-99m radioaerosols. However radioactive gases are compromised by availability and cost for krypton-81m, radiation dose, gamma energy and non?physiologic behaviour for xenon-133. Radioaerosols of technetium-99m componds are rapidly cleared from the lung after inhalation, and their relative low effeciency (specific radioactivity) and wide distribution of particle sizes make them also suboptimum. A new ventilation agent, Technegas is a suspension of structured graphite ellipsoids with diameter below 20nm, labelled with $^{99m}Tc$ in a carrier gas of Argon. This report describes the authors' clinical experience with Technegas. This is the first reported clinical study of this agent in Korea. A comparison of Technegas and $^{99m}Tc-DTPA$ aerosol was performed in 12 patients with various pulmonary diseases such as COPD, pulmonary tuberculosis and pleural effusion. All patients were studied with $^{99m}Tc-DTPA$ aerosol inhalation and Technegas ventilation. In both studies image quality was assessed (1) semiquantitatively by scoring bronchial and gastric activity, (2) subjectively by direct visual comparison of peripheral lung images and (3) quantitatively by computing the peripheral penetration index(PI) for each lungs. The bronchial activites were seen in 7 out of 12 cases with $^{99m}Tc-DTPA$ aerosol and in 5/12 with Technegas. The gastric activities were seen in 5/12 and 1/12 cases respectively. The average values of PI were 61.26% with $^{99m}Tc-DTPA$ aerosol and 69.20% with Technegas (p>0.05). Using $^{99m}Tc-DTPA$ aerosol, COPD patients showed deposition in the central airways with poor visualization of the peripheral areas of the lungs. In Technegas studies these phenomena were less prominent, and the examination is well tolerated by pateients and requires only a minimum of patient cooperation. With superiority of easy availability and handling, better physical characteristics and favorable Image quality, Technegas is a Promising agent for lung ventilation scanning.

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Physicochemical Characteristics of Zeolite Mineral by Alkali Solution Treatment (알칼리 처리에 의한 Zeolite 광물의 물리화학적 특성)

  • Yim, Going
    • The Journal of Natural Sciences
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    • v.8 no.2
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    • pp.119-127
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    • 1996
  • The effect of sodium hydroxide treatment on some physicochemical properties of zeolite mordenite mineral was studied with chemical analyses, powder X-ray diffraction, thermal analyses, infrared analysis, measurement of carbon dioxide adsorption and gas chromatography. Mordenite mineral from tuffaceous rocks in Yeongil and Wolsung area was used as a starting material and treated with 0.1-5N NaOH aqueous solution at about $95^{\circ}C$ in the water bath for three hours.At the concentration of sodium hydroxide below 0.5N, all chemical compositions in the tuff were virtually insoluble and the mordenite structure did not change. At the concentration above 1N, the chemical compositions such as silica, alumina, etc., were dissolved. The dissolution ratio of silica was lager than that of alumina, and the ratio of silica to alumina in the tuff decreased sharply in the concentration range of 2 to 3N. Intensity of X-ray diffraction peak of mordenite (202) plane and the adsorbed amount of carbon dioxide also decreased with the increasing concentration of sodium hydroxide above 1N. These decreases corresponded to the degree of mordenite structure collapsed.The separation of gas chromatography of nitrogen, oxygen and carbon monoxide was not affected by the sodium hydroxide treatment, but elution peaks of methane and krypton tended to be broadened and their retention time was shortened. The elution peaks of both methane and krypton tended to be overlapped with those of nitrogen and oxygen.

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A Study on the Condensation Performance of Curtain-wall Window in High-Rise Residential Building (초고층 주거건물 커튼월의 창호부 결로 성능평가에 관한 연구)

  • Seok Ho-Tae;Chung Man-Seok;Kwak Hyun-Chul;Kwon Jong-Wook
    • Journal of the Korean housing association
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    • v.16 no.4
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    • pp.81-89
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    • 2005
  • The purpose of this thesis is thermal performance simulation about various type that can apply in the high-rise residential building to estimate condensation performance of window that is consisted of frame and glazing in curtain wall. The result of this thesis are summarized as follows. First, condensation occurrence point when relative humidity is $30{\cdot}40{\cdot}50\%$ is shortest Low-e double glass. Difference by type of gas and spacer was a little by $2{\~}6$ cm, among it, the case that apply krypton in gas and the case that apply double seal in spacer were less condensation occurrence distribution. Second, when analyzed improved proposal of window and existing plan through simulation, improved proposal is superior from general side of the interior and exterior temperature, thermal break surrounding temperature and temperature of frame end, condensation occurrence point etc. Therefore, if it was used improved proposal with effect that improve in curtain wall of high-rise residential building, it may improve window condensation performance of curtain wall.

Laser scribing for buried contact solar cell processing (전극함몰형 태양전지의 제조를 위한 레이저 scribing)

  • 조은철;조영현;이수홍
    • Electrical & Electronic Materials
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    • v.9 no.6
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    • pp.593-599
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    • 1996
  • Laser scribing of silicon plays an important role in metallization including the grid pattern and the front surface geometry which means aspect ratio of metal contacts. To make a front metal electrode of buried contact solar cell, we used ND:YAG lasers that deliver average 3-4W at TEM$\_$00/ mode power to sample stage. The Q-switched Nd:YAG laser of 1.064 gm wavelength was used for silicon scribing with 20-40.mu.m width and 20-200.mu.m depth capabilities. After silicon slag etching, the groove width and depth for buried contact solar cell are -20.mu.m and 30-50.mu.m respectively. Using MEL 40 Nd:YAG laser system, we can scribe the silicon surface with 18-23.mu.m width and 20-200.mu.m depth controlled by krypton arc lamp power, scan speed, pulse frequency and beam focusing. We fabricated a buried contact Silicon Solar Cell which had an energy conversion efficiency of 18.8 %. In this case, the groove width and depth are 20.mu.m and 50.mu.m respectively.

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Thermodynamic Properties of Kr Gas Adsorbed on Graphite Surface (흑연 표면에 흡착된 Kr 기체의 열역학적 성질)

  • Woon-Sun Ahn;Kyung Hee Ham;Eun Ah Yoo;Kwang Soon Lee
    • Journal of the Korean Chemical Society
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    • v.26 no.4
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    • pp.211-217
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    • 1982
  • Assuming krypton molecules adsorbed on the graphite surface as a two-dimensional (2D) gas, 4th virial coefficient of the virial equation is calculated by the use of cluster integrals. The Henry's law constant, and 2nd and 3rd virial coefficients are also calculated. Adsorption isotherms calculated from this virial equation agree very satisfactorily with experimental results. The interaction energy of Kr-graphite surface is calculated assuming the pairwise additivity of Lennard-Jones(12,6) potential, and parametars therein are taken as; ${\varepsilon}_{gs}$/k = 71.1 K, ${\varepsilon}_{gg}$/k = 170 K, ${\sigma}_{gs}$ = 354 pm, and ${\sigma}_{gg}$ = 368 pm.

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The Analysis of Electron Transport Coefficients in Kr and Xe Atom Gas (Kr과 Xe 원자기체의 전자수송계수의 해석)

  • Jeon, Byung-Hoon
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.22 no.8
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    • pp.104-108
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    • 2008
  • Accurate sets of electron collision cross sections and the electron transport coefficients for atoms and molecules are necessary for quantitative understanding of plasma phenomena Kr and Xe atom are used in many industrial applications, such as in PDP and fluorescent induction lamps(FILs). Therefore, we analysed and calculated the electron transport coefficients, the electron drift velocity W, the longitudinal and transverse diffusion coefficient $ND_L$ and $ND_T$, and the ionization coefficient $\alpha$/N in pure Kr and Xe gases over the wide E/N range from 0.001 to 500[Td] at 1[Torr] by two-tenn approximation of the Boltzmann equation.

Vacuum Ultraviolet Photolysis of Ethyl Bromide at 123.6 nm

  • Hee-Soo Yoo;K. H. Jung
    • Bulletin of the Korean Chemical Society
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    • v.1 no.1
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    • pp.35-39
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    • 1980
  • A vacuum ultraviolet photolysis of ethyl bromide was studied in the pressure range of 0.5-19.9 torr and at 123.6 nm krypton resonance line. The pressure effect on the reaction was studied by increasing the reactant pressure and by adding an inert gas, e.g., He. In the observation the monatomic gas is found to be no effect in the reaction. A scavenger effect of the reaction was also performed by adding NO gas as a radical scavenger and was found to be quite efficient to scavenge a radical product $C_2H_6$. The observation of the major reaction product $C_2H_6$ was interpreted in terms of a molecular elimination. Nontheless the decreasing phenomenon of ${\phi}_{C_2H_4}/{\phi}_{C_2H_6}$ with pressure rise was attributed to the existence of the two electronically excited states. One state proceeds to the molecular elimination and the other to carbon-bromine bond fission. The excitation and the decomposition mechanisms between two excited states and the reaction products were interpreted in terms of the first excitation which proceeds the molecular elimination, and the second excitation which resulted from the first excited state by collisional cross over decomposes by carbon-bromine bond fission.