• Title/Summary/Keyword: Korean bentonite

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Influence of Ca-Na-Cl physicochemical solution properties on the adsorption of Se(-II) onto granite and MX-80 bentonite

  • Joshua Racette ;Andrew Walker ;Shinya Nagasaki ;Tianxiao Tammy Yang ;Takumi Saito ;Peter Vilks
    • Nuclear Engineering and Technology
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    • v.55 no.10
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    • pp.3831-3843
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    • 2023
  • The adsorption behaviour of Se(-II) onto granite and MX-80 bentonite in Ca-Na-Cl solutions has been studied utilizing adsorption experiments and surface complexation modelling. Adsorption kinetic experiments allude to steady-state adsorption periods after 7 days for granite and 14 days for MX-80 bentonite. Batch adsorption experiments were carried out to determine the influence that the physicochemical solution properties would have on Se(-II) adsorption behaviour. Adsorption of Se(-II) onto granite and MX-80 bentonite follows the trend of anionic adsorption, with a decrease in Rd values as the solution pH increased. There is also an ionic strength influence on the adsorption of Se(-II) onto granite with a decrease in the Rd value as the ionic strength increased. This effect is not found when observing Se(-II) adsorption onto MX-80 bentonite. Final experiments with a representative groundwater, determined that the adsorption of Se(-II) onto granite and MX-80 bentonite returned Rd values of (1.80 ± 0.10) m3·kg-1 and (0.47 ± 0.38) m3·kg-1, respectively. In support of the experiments, a surface complexation modelling approach has been employed to simulate the adsorption of Se(-II) onto granite and MX-80 bentonite, where it was determined that two different surface complexes, ≡S_Se- and ≡SOH2+_H2 were capable of simulating Se(-II) adsorption behaviour.

An Experimental Study on the Sorption Properties of Uranium(VI) onto Bentonite Colloids (벤토나이트 콜로이드에 대한 우라늄(VI) 수착특성에 대한 실험적 연구)

  • Baik Min-Hoon;Cho Won-Jin;Hahn Pil-Soo
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2005.06a
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    • pp.239-247
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    • 2005
  • In this study, an experimental study on the sorption properties of uranium(VI) onto bentonite colloids generated from a domestic calcium bentonite (called as Gyeongju bentonite). Gyeongju bentonite has been considered as a potential candidate buffer material in the Korean disposal concept for high-level radioactive wastes. The size and concentration of the bentonite colloids used in the sorption experiment were measured by a filtration method. The result showed that the concentration of the synthesized bentonite colloid suspension was 5100ppm and the size of the most of bentonite colloids(over $98\%$) was in the range of 200-450nm in diameter. The amount of uranium lost by the sorption onto bottle walls, by precipitation, and by ultrafiltration or colloid formation was analyzed by carrying out some blank tests. The loss of uranium by the ultrafiltration was significant in the lower ionic strength(i.e., in the case of 0.001M $NaClO_4$) due to the cationic sorption effect onto the ultrafilter by a surface charge reversion. The distribution coefficient (or pseudo-colloid formation constant) for the sorption of uranium(VI) onto bentonite colloids was $10^4^{\sim}10^6$ mL/g depending upon pH and the distribution coefficient was highest in the neutral pH around 6.5.

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Viability test hydrocarbon-degrading bacterium by carriers according to temperature conditions

  • 박진희;김영식;여인봉;박기영
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2002.04a
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    • pp.203-208
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    • 2002
  • 미생물 생산은 다양한 산업에 이용되는 핵심산업이다. 그러나 미생물을 장기간 보존하거나 생산 후 현장처리에 상황에 있어 미생물의 활성이 환경 및 각종조건에 따라 장기간 유지되지 못하는 경향이 있다. 따라서, 본 실험에서는 Pseudomonas putida SSEoX의 생산 후 시중에서 판매되는 perlite, diatomite, bentonite, zeolite, dolomite, vermicullite 등의 담체를 이용하여 미생물의 생리활성유지를 위한 실험을 자연현상에서 나타날 수 있는 다양한 온도에서 담체의 종류별로 수행하였다. 그 결과 bentonite를 이용한 담체의 경우 5, 20, 3$0^{\circ}C$에서 40일간 미생물의 밀도가 거의 감소하지 않은 결과로 나타났고 zeolite의 경우 20일 이내의 저온에서 생존율이 높은 것으로 나타났으나 온도의 상승으로 생존율이 현저히 떨어졌다. 또한 Dololite의 경우 초기 20일 내에서는 20t에서 생존율이 매우 높았으나 40일 후 생존율이 현저히 감소하였다. 또한 bentonite의 경우 전체적으로 생존율이 거의 감소되지 않았으며 그중 5$^{\circ}C$와 2$0^{\circ}C$에서 생존율이 가장 높았고 3$0^{\circ}C$에서 30일 후까지는 비교적 적은 감소를 보였으며 40일 이후 비교적 큰 감소율이 있었다. 따라서, 본 실험결과 비교적 낮은 온도에서 bentonite와 vermiculite를 혼합한 담체를 이용한 미생물보존이 가장 우수만 생존유지법이었다.

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The Strength Properties of Cement-Bentonite Soil Mixtures with Geosynthetics and Metakaolin (토목섬유 및 메타카올린 첨가 시멘트-벤토나이트 혼합토의 강도 특성)

  • Lee, Jae-Deuk;Yeon, Kyu-Seok;Kim, Kwang-Woo;Kim, Yong Seong
    • Journal of The Korean Society of Agricultural Engineers
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    • v.54 no.6
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    • pp.159-167
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    • 2012
  • In the present study, an investigation has been made on the application of cement-bentonite soil mixtures as the countermeasure against leachate produced by buried animal carcasses. For this purpose, the strength characteristics of the cement-bentonite soil mixtures mixed with geotextile and metakaolin. After the mixtures with different contents of the cement (0 %, 10 %), bentonite (0 %, 5 %, 10 %, 15 %, 20 %), and weathered soil (100 %, 95 %, 90 %, 85 %, 80 %) were prepared, metakaolin and geotextile were added with different contents (metakaolin : 0 %, 5 %, 10 %, 15 %, 20 % of the cement weight; geotextile : 0 %, 0.5 %, 1 %, 1.5 %, 2 %). Experimental results suggested that the early strength of the mixture increases due to the pore filling, the hydration acceleration, and the pozzolan reaction when metakaolin of 5~10 % of the cement weight was added. In addition, the compressive strength increase when 0.5~1 % geotextile contents were added, and the above these contents, the rate of strength increase was gradually decreased because of the fibrous tangles.

A Study on Development Type Bentonite Mate Waterproofing Materials under the Influence of Salt Water (개량형 벤토나이트 매트 방수재의 염수 영향에 관한 연구)

  • Kim Yung-Buok;Kim Su-Ryon;Kwak Kyu-Sung;Oh Sang-Keun
    • Proceedings of the Korean Institute of Building Construction Conference
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    • v.y2004m10
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    • pp.45-49
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    • 2004
  • A general bentonite mate waterproofing material applied salt pollution without particular way(it is a land reclaimed from a sea(or near by sea). Analysis showed that it(general bentonite mate) has a little resistant salt pollution and a little watertightness. There are a lot of problem before completed structure because of salt pollution. So that, they have to a sum of money to repair works. Also, to repaired a part leak water again and again. because it doesn't match for salt pollution. So, I am going to study about a bentonite mate waterproofing material in salt pollution and it will be within the range of possibility to underground structure under the salt pollution. Also, I suggest waterproofing method in salt pollution about workability, stability, economy and etc.

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A Study on Engineering Characteristics of the Drilling Fluid Dependingon the Mix Water (배합수에 따른 안정액의 공학적 특성 분석)

  • Choi, Jung-Hyuk;Yoo, Chung-Sik;Han, Yun-Su
    • Journal of the Korean Geosynthetics Society
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    • v.15 no.4
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    • pp.43-52
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    • 2016
  • This paper presents the results of a engineering characteristic to the effect of drilling fluid with different mix designs for use in bore hole collapse prevention. The bore hole collapse prevention mechanism for the bentonite based drilling fluid was first discussed together with the effect of conditioning with different additives on engineering characteristics of bentonite based drilling fluid. As result, bentonite with polymer have a outstanding characteristics as compared to CMC Properties thickening effect In the case of sea water with attatulgite be superior to bentonite. Therefore, in this paper presented qualitative result on the performance of the drilling fluid depending on the water.

Thinning Effect Due to Bentonite Migration on Performance of GCL (벤토나이트 유실로 인한 협착이 GCL 거동에 미치는 영향)

  • Choi, Hangseok;Lee, Chulho;Stark, Timothy D.
    • Journal of the Korean Geosynthetics Society
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    • v.5 no.4
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    • pp.49-58
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    • 2006
  • Recently, geosynthetic clay liners (GCLs) have increasingly been used to replace compacted clay liners (CCLs) in composite liner systems. Since the introduction of GCLs to waste containment facilities, one of the major concerns about their use has been the hydraulic equivalency to CCLs as required by regulations. Laboratory test results and more recently field observations show that the thickness, or mass per unit area, of hydrated bentonite in a GCL can decrease under normal stress, especially around zones of stress concentration or nonuniform stresses, such as a rock or roughness in the subgrade, a leachate sump, or wrinkles in an overlying geomembrane. This paper presents field case histories that confirm the laboratory observations of bentonite migration and the effect of bentonite migration on hydraulic equivalency and contaminant transport through a GCL.

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A Study of the Bottom Ash as Environmentally Grouting Materials (Bottom Ash를 이용한 그라우팅재의 환경적 연구)

  • Doh, Young-Gon;Kwon, Hyuk-Doo;Lee, Song
    • Journal of the Korean Geotechnical Society
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    • v.22 no.11
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    • pp.5-11
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    • 2006
  • The purpose of this study was to examine the proper mixing ratio of ordinary portland cement and Bottom Ash to recycle the Bottom Ash, which is an industrial waste. After the evaluation, the compressive strength and durability were assessed using the mixture of completely weathered soil (Hwangto), weathered granite soil, and Bentonite. Then environmental friendliness of this mixed material was examined through heavy metal leaching method. It was found out that proper mixing ratio is 6:4, and that the 6% mixture quantity of completely weathered soil (Hwangto), weathered granite soil, and Bentonite is the most effective for compressive strength and durability It was also found out through heavy metal leaching method that the Bottom Ash could be below the standard of the Clean Water Law.