• 제목/요약/키워드: Korean Anthracite

검색결과 195건 처리시간 0.03초

전기로 슬래그 포밍에 미치는 가탄재 종류의 영향 (Effect of Carbon Materials on the Slag Foaming in EAF Process)

  • 김영환;유정민;엄형식
    • 자원리싸이클링
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    • 제28권2호
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    • pp.40-45
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    • 2019
  • 전기로 공정은 스크랩을 재활용하여 주원료로 사용하고 아크에 의해 용해하며, 전력을 주 에너지로 사용한다. 슬래그 포밍은 전력에너지 저감에 중요한 요소 기술이다. 투입되는 가탄재(분탄)와 슬래그 중 FeO와의 반응과 용강 중의 카본과 투입되는 산소와의 반응에 의해 CO가스가 발생된다. 이러한 반응에 의해 발생된 CO가스는 슬래그에 포집되어 슬래그 포밍 현상이 일어난다. 전기로 제강 공정에서 일반적으로 가탄재는 가공분탄(무연탄)과 cokes를 사용하고 있다. 본 연구는 전기로 제강 공정에 사용되는 가탄재에 따른 슬래그 포밍의 영향을 조사하였다. 연구 결과 가공분탄 보다는 cokes에 의해 슬래그 포밍 높이가 증가 되었으며, 입도 $500{\mu}m$ 이하의 입자 함량이 증가할수록 포밍높이가 증가하는 결과를 나타내었다. 이러한 결과를 바탕으로 조업에 적용한 결과, 슬래그 포밍높이 증가와 가탄재 원단위 저감, 전력에너지 저감의 효과를 얻었다.

지속가능 에너지 패러다임 변화속에서 석탄의 활용 (Usage of Coal in the Paradigm Shift toward Sustainable Energy)

  • 박제현;양인재;이진수;이청룡
    • 자원환경지질
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    • 제53권6호
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    • pp.793-807
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    • 2020
  • 그린뉴딜정책의 실현은 석탄을 연료에서 원료로 활용분야로의 전환을 촉진시킬 것이다. 석탄은 수소의 생산, 인조 흑연 및 활성탄의 제조 원료로 활용될 수 있다. 석탄은 Steam carbon(SC) 반응과 Water-Gas Shift(WGS) 반응 및 탄산화 반응을 통하여 수소를 생산할 수 있으며, CO2격리기술과 연동되어 사용되어야 한다. 인조흑연은 실리콘이나 철 등의 무기촉매의 존재하에서 탄화도가 높은 무연탄 등을 2400~2800℃의 흑연화 온도까지 열처리함으로서 제조될 수 있기 때문에 무연탄은 석유계 피치에 비해 원료 가격경쟁력 측면에서 잠재성이 있다. 한편, 최근 목질기원의 활성탄에 필적하는 넓은 비표면적 혹은 많은 양의 미세기공을 가진 석탄기원의 활성탄이 제조될 수 있음을 여러 연구를 통해 확인되었다. 따라서 석탄기원의 활성탄은 목질기원의 활성탄을 대체할 수 있을 것으로 기대된다.

Fly ash 시용(施用)이 수도(水稻)의 수량(收量)과 논 토양(土壤)의 유효규산(有效珪酸) 함량(含量)에 미치는 영향(影響) (Effect of Fly ash Application on the Yield of Rice and Silicate Availability in Paddy Soil)

  • 김용웅;윤종희;김광식
    • 한국토양비료학회지
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    • 제27권4호
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    • pp.275-283
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    • 1994
  • 논 토양(土壤)에 무연탄(無煙炭)과 유연탄(有煙炭)의 fly ash를 시용(施用)하여 fly ash가 수도(水滔)의 생장(生長)과 양분흡수(養分吸收) 및 토양중(土壤中)의 유효규산(有效珪酸) 함량(含量)에 미치는 영향(影響)을 조사(調査) 분석(分析)한 결과(結果)를 요약(要約)하면 다음과 같았다. 1. 벼의 수량(收量)은 무연탄회(無煙炭灰) 처리구(處理區)에서는 처리량(處理量)이 증가(增加)될수록 감소(減少)되었으나 유연탄회(有煙炭灰) 처리구(處理區)에서는 처리량(處理量)이 증가(增加)될수록 벼의 수량(收量)도 증가(增加)하였다. 2. 생육시기별(生育時期別) 수도(水稻)의 무기성분(無機成分) 함량(含量)은 전질소(全窒素), $P_2O_5$, $K_2O$, CaO, MgO는 생육(生育)이 진전(進展)됨에 따라 함량(含量)이 감소(減少)되고, $SiO_2$ 함량(含量)은 생육(生育)과 비례하여 수확기(收穫期)로 갈수록 증가(增加)되는 경향(傾向)을 보였다. 3. 수도(水稻) 생육기간중(生育期間中)의 토양(土壤) 화학성(化學性)을 보면 pH와 유기물(有機物) 함량(含量) 및 무기성부(無機成分) $P_2O_5$, $K_2O$, CaO, MgO, 유효규산 함량은 무연탄회(無煙炭灰) 처리구(處理區)보다 유연탄회(有煙炭灰) 처리구(處理區)가 더욱 높았으며, 석탄회 처리량이 증가 함에따라 무기(無機) 성분(成分)의 함량(含量)도 증가(增加)하는 경향(傾向)이었다. 4. 1N-NaOAc 침출법(浸出法)과 담수보온(湛水保溫) 정치법(靜置法)으로 생육(生育) 시기별(時期別)로 분석(分析)한 논 토양(土壤)의 $SiO_2$ 함량(含量)과 수도(水稻)의 $SiO_2$ 함량(含量)의 상관관계(相關關係)를 살펴보면 무연탄(無煙炭) 처리구(處理區)에서는 두 분석법(分析法) 모두 유의성(有意性)이 없었으나, 유연탄회(有煙炭灰) 처리구(處理區)에서는 담수보온(湛水保溫) 정치법(靜置法)에서 고도(高度)의 유의상관(有意相關)을 나타냈다.

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한국공업화과정(韓國工業化過程)에서의 광물자원(鑛物資源)의 수급구조변화(需給構造變化)와 경제성장(經濟成長)에 있어서의 역할(役割) (The Changing Patterns of Demand-Supply and Role of Mineral Resources in Economic Growth during Industrialization of the Republic of Korea)

  • 윤석규
    • 자원환경지질
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    • 제18권1호
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    • pp.65-92
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    • 1985
  • A total of 12 mineral commodities significant in domestic output, economy and/or strategy of the Republic of Korea are chosen to examine the structural changes in production and demand-supply of these minerals during the last two decades of her industrialization. These include iron and manganese ores as the raw materials for iron and steel making, copper, zinc and tungsten ores among other non-ferrous metallic minerals, limestone (cement), kaolin, talc, pyrophyllite and graphite among other non-metallic minerals, and anthracite coal as the only domestic source of fossil energy. These are reviewed historically in time-series based on the statistical data which are tabulated and graphed in terms of domestic output, export, import, apparent demand-supply, its increasing rate, and self-sufficiency rate of each commodity. The increasing rates of demand-supply (IRDS) of some more important commodities are compared with those of Gross Domestic Production (GDP) and Economic Growth Rate (EGR) to evaluate how the IRDS contributed to the GDP and EGR. The major results revealed are as follows: Among the 12 commodities, the domestic output of 8 commodities appeared to have grown with steady upward trends: they are ores of lead, zinc and tungsten, limestone (cement), kaolin, talc, pyrophyllite and anthracite coal. Two commodities, ores of iron and copper, continued with unchanging or slightly declining trends and varied fluctuations, in spite of their cardinal importance to the heavy industry and strategy of Korea. The remaining two, graphite and manganese ore, have gradualy declined in domestic output in which the former has still enough resource potential but the latter has not and virtually ceased its domestic output. Trade patterns for mineral commodities in the Republic of Korea during the last two decades have changed greatly, being marked by a shift from mineral-exporting to mineral importing, mainly because of increasing consumption of mineral raw materials for industrialization rather than beceuse of decreasing output of domestic mineral commodities in quantity. In terms of trade patterns, the 12 commodities concerned in this study can be classified into the following four groups. The 1st group - ores of lead and tungsten have only been exported without imports. The 2nd group - amorphous graphite, and pyrophyllite have mainly been exported but partly been imported. The 3rd group - kaolin, talc and crystalline graphite have equally been exported and imported, but quantity of imports have rapidly been increased with time. The 4th group - ores of iron, manganese and zinc have shifted from exports to imports during the industrialization, particularly owing to the initiation of iron and steel making by the Pohang Iron and Steel Company in the middle 1970' s and the new establishment of the Onsan Zinc Refinery in the late 1970' s. All of the 12 commodities under considerations were far above 100% in self-sufficiency rate before or in the early 1960' s. Recently, however, most of them have been declined to below 100% except for those of limestone (cement) and pyrophyllite. It is particularly serious to identify that the self-sufficiency rates of the three important metallic minerals, iron, copper and manganese ores in 1982 appeared to be 5.1%, 0.5%, and 0.01%, respectively. The average self-sufficiency rate of the total domestic minerals produced in 1982 was 14.4% (in value) for that year. Mining industry appeared to be extremely high in its intermediate demand rate whereas its intermediate input rate to be quite low indicating that mineral raw materials have been exerted strong forward linkage effects upon the other industries rather than backward linkage effects. In comparing the curves of increasing rates of demand-supply of several major minerals - iron ore, manganese ore, copper ore, limestone (cement), kaolin, and anthracite coal - with those of Gross Domestic Production and Economic Growth Rate drawn on every graph, it is clearly shown that the curves of increasing rates of demand-supply comprise around 6 to 7 periods of cycles which roughly harmonious with those of the curves of GDP and EGR, except for the curve of anthracite coal of which the configuration seems to have resulted from the (artificial) government's mineral policy rather than from economic free market mechanism. The harmonic feature of these curves well suggests that the increasing rates of demand-supply of major minerals have been significantly contributed to the GDP and EGR. In addition, the wider amplitudes of the iron, manganese and copper curves than those of the limestone (cement) and kaolin curves indicate that the contribution of the former, metallic commodities, has been greater than that of the latter, non-metallic commodities.

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한국산 저질무연탄 연소용 순환식유동층 연소로 개발(간막이벽과 내부노즐을 설치한 순환유동층내에서의 유체거동) (Technical Development for the Circulating Fluidized Bed Combustor of firing Korean Low Grade Anthracite Coals (Particle Flow Patterns in a Circulating Fluidized-Bed with an internal Nozzle and a Partition Wall))

  • 이관석
    • 열처리공학회지
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    • 제6권4호
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    • pp.243-248
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    • 1993
  • A Circulating Fluidized-Bed (CFB) with an internal nozzle and a partition wall was proposed. The technique of fluidization is related to operations first used commercially in the fields of metallurgical and mechanical engineering such as the heat treatment of metals and power station combustors. In the modified CFB, an internal nozzle and a partition wall were additionally set in the main bed. This cold mode CFB apparatus made of acrylic resin; the main bed is 1,500mm high and 100mm in the inner diameter, the internal nozzle is 130mm high and 10mm in the inner diameter, and the partition wall is 7mm thick and 100mm in the diameter. Glass beads of $89{\mu}m$ in the mean diameter were employed as bed materials.

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수증기 활성화법으로 제조된 활성탄의 탄화온도에 따른 세공구조 고찰 (Characteristics of pore structure of steam activated carbon with carbonization temperature)

  • 이송우;나영수;김도한;최동훈;류동춘;송승구
    • 한국환경과학회지
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    • 제9권4호
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    • pp.345-349
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    • 2000
  • Activated carbons were prepared from Korean coal by steam activation in this study. The variation of pore structure of the activated carbons were investigated according to different carbonization temperatures. Yield, surface area, pore volume and pore structure of this activated carbon were compared with those of activated carbon prepared without carbonization. The investigated carbonization temperature ranged from 700${\circ}C$ to 1,000${\circ}C$. Carbonization was carried out in nitrogen atmosphere for 70 minutes and activation was performed by steam at 950${\circ}C$ for 210 minutes. Surface area and pore volume of the resulting activated carbons increased with carbonization temperature. Also pore volume increased by 20% compared to the activated carbon without carbonization. Especially, in mesopore region, the activated carbon carbonized at 900${\circ}C$ had more pores by 60% than that of activated carbon carbonized at other temperature.

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低質炭의 利用硏究 (第一報) 無燃固體燃料의 燃燒速度의 測定) (Studies on the Utilization of Low Quality Coals (1) Determination of combustion velocity of smokeless solid fuels)

  • 오신섭;김정혁
    • 대한화학회지
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    • 제4권1호
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    • pp.78-80
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    • 1957
  • Up to now, only superficial studies on the combustion velocity of smokeless fuels have been reported, while it should be a basical factor on the utilization of low quality coals and some other smokeless solid fuels. It was, therefore, difficult to choose raw material coals in manufacturing gaseous fuels. With the intent to solve above problem, we have determined combustion velocity of domestic anthracites, graphites, coalites of lignite and cokes from Japanese bituminous coal. The results show that the cokes from Japanese bituminous coal which has been used as raw material in the manufacturing gaseous fuels such as water gas, or producer gas in Korea can be replaced by some sources of domestic anthracite or coalite of lignite.

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A Case Study of Desulphurization by Limestone Adsorbent in an Industrial CFBC Boiler

  • Park, Young-Goo;Kim, Seung-Ho;Jo, Young-Min
    • Journal of Korean Society for Atmospheric Environment
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    • 제21권E2호
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    • pp.67-74
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    • 2005
  • Domestic anthracite contains a large amount of fine particles, which causes to fire the back side of the boiler and to form the clinker deteriorating the combustion efficiency. At this time, the fine limestone adsorbents for a desulphurization agent may be used to facilitate an aggravation of the boiler, so that fine mode of limestone (<0.1mm) has been used no more than $25\%$ in local power stations of Korea. The present test carried out with an in-situ boiler, however, showed that higher content $(up\;to\;50\%)$ of fine limestone particles did not entail any mal-function. In addition, the desulphurization was found to be as good as the old mode of limestone adsorbents.

해수-석탄회 상호작용에 의한 원소 용출특성: 실험연구

  • 박성민;김강주;장수범;황갑수
    • 한국지하수토양환경학회:학술대회논문집
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    • 한국지하수토양환경학회 2003년도 총회 및 춘계학술발표회
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    • pp.455-458
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    • 2003
  • We investigated the leaching of elements from anthracite ashes by interactions with seawater. The results show that consumption rates of dissolved oxygen are 7.5 times greater in the seawater system than in the fresh water system and indicate that the differences in DO consumption rate may plat a role in regulating the element leaching from the coal ashes. It is revealed that seawater's pH buffering capacity is the most important factor that makes the leaching of elements and their chemical behaviors in the seawater system different from those in the fresh water environments. In overall, element leaching from the weathered ash is smaller than that from the fresh ash. However, the leaching of Si, Fe, Al, Mn, phosphate, and some other elements were independent of weathering. They were dependant only on the pH of the solutions.

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정수처리과정(淨水處理過程)에서의 잔류불소(殘留弗素)이온 거동(擧動)에 관한 연구(硏究) (A Study on the Behavior of Residual Fluoride in Water Treatment Process)

  • 이택순;문병현;서규태;진홍식
    • 상하수도학회지
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    • 제14권2호
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    • pp.164-173
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    • 2000
  • Fluoridation of drinking water to a level of about 0.8mg/l (below 1.5mg/l) for reducing the incidence of tooth decay is recommended. However, concerns about potential problems of unknown effects and overdosing hinders the fluoridation. This study describes the work performed to obtain information on the behavior of fluoride under various conditions in the process of water fluoridation. Effects of water treatment chemicals, water treatment unit, and water distribution on water fluoridation were investigated at both lab and an actual water treatment plant. Residual fluoride concentration was not affected by lime and chlorine dosage up to 20mg/l. Flocculation with PAC slightly decreased the residual fluoride concentration as PAC dosage increased. Average fluoride concentration of 0.87mg/l at an intake basin was decreased to 0.83mg/l by sedimentation, 0.81mg/l by dual media(sand+anthracite) filtration, and 0.79mg/l by granular activated carbon filtration in the water treatment plant.

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