• Title/Summary/Keyword: Kondo

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Switching and sensing molecular spins by chemical reactions on metal surfaces

  • Kahng, Se-Jong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2015.08a
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    • pp.63.2-63.2
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    • 2015
  • Controlling and sensing spin states of magnetic molecules such as metallo-porphyrins at the single molecule level is essential for spintronic molecular device applications. Axial coordinations of diatomic molecules to metallo-porphyrins also play key roles in dynamic processes of biological functions such as blood pressure control and immune response. However, probing such reactions at the single molecule level to understand their physical mechanisms has been rarely performed. Here we present on our single molecule association and dissociation experiments between diatomic and metallo-porphyrin molecules on Au(111) describing its adsorption structures, spin states, and dissociation mechanisms. We observed bright ring shapes in NO adsorbed metallo-porphyrin compelxes and explained them by considering tilted binding and precession motion of NO. Before NO exposure, Co-porphryin showed a clear zero-bias peak in scanning tunneling spectroscopy, a signature of Kondo effect in STS, whereas after NO exposures it formed a molecular complex, NO-Co-porphyrin, that did not show any zero-bias feature implying that the Kondo effect was switched off by binding of NO. Under tunneling junctions of scanning tunneling microscope, both positive and negative energy pulses. From the observed power law relations between dissociation rate and tunneling current, we argue that the dissociations were inelastically induced with molecular orbital resonances. Our study shows that single molecule association and dissociation can be used to probe spin states and reaction mechanisms in a variety of axial coordination between small molecules and metallo-porphyrins.

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Correlation-Based Watermarking Scheme Using Wavelet Transform and Extended Sequences

  • Kanai, Ryota;Kondo, Shozo;Atsuta, Kiyoaki
    • 제어로봇시스템학회:학술대회논문집
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    • 2004.08a
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    • pp.1717-1720
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    • 2004
  • In this paper we propose a new scheme of watermarking using the discrete wavelet transform, the discrete cosine transform, and the performance evaluation function, which does not deteriorate image quality and have robustness to attacks such as compression and scaling. moreover even if a detected watermark, which is a bit sequence in this paper, has some error bits, it can be correctly recovered using correlation-based determination scheme.

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Automatic Detection of Interstitial Lung Disease using Neural Network

  • Kouda, Takaharu;Kondo, Hiroshi
    • International Journal of Fuzzy Logic and Intelligent Systems
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    • v.2 no.1
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    • pp.15-19
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    • 2002
  • Automatic detection of interstitial lung disease using Neural Network is presented. The rounded opacities in the pneumoconiosis X-ray photo are picked up quickly by a back propagation (BP) neural network with several typical training patterns. The training patterns from 0.6 mm ${\O}$ to 4.0 mm ${\O}$ are made by simple circles. The total evaluation is done from the size and figure categorization. Mary simulation examples show that the proposed method gives much reliable result than traditional ones.

Design of the multi-input deadbeat state regulator with the minimal input energy

  • Kiyota, Takanori;Kondo, Eiji;Sunaga, Teruo
    • 제어로봇시스템학회:학술대회논문집
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    • 1989.10a
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    • pp.890-895
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    • 1989
  • This paper discusses the regulator problem of minimizing the input energy for the multi-input linear time-invariant discrete-time system with the zero terminal state. The optimal inputs are expressed by the state feedback form and they are made up of three phases. The optimal feedback gains are independent of the initial state.

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High performance torque control of induction motor by speed sensorless vector control

  • Harashima, Fumio;Kondo, Seiji;Inoue, Shuji
    • 제어로봇시스템학회:학술대회논문집
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    • 1990.10b
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    • pp.1410-1414
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    • 1990
  • A method of speed sensorless vector control of induction motor is proposed in this paper. This method uses the slip frequency estimated by only the primary voltage and current. As this slip frequency accords with the command value of it, the commanded primary frequency is controlled. The validity of the method is confirmed by the simulation and experimental results.

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Alexander Polynomials of Knots Which Are Transformed into the Trefoil Knot by a Single Crossing Change

  • Nakanishi, Yasutaka
    • Kyungpook Mathematical Journal
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    • v.52 no.2
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    • pp.201-208
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    • 2012
  • By the works of Kondo and Sakai, it is known that Alexander polynomials of knots which are transformed into the trivial knot by a single crossing change are characterized. In this note, we will characterize Alexander polynomials of knots which are transformed into the trefoil knot (and into the figure-eight knot) by a single crossing change.