• KSBB Journal
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• 제5권2호
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• pp.133-139
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• 1990

1회의 회분실험 데이터로부터 효소반응 속도식의 매개 변수를 쉽게 추정할 수 있는 방법을 제시하였다. 여러 가지 반응패턴을 갖는 모델식에 있어서 효소반응 데이터를 적용시킨 결과 정확하고 간편하게 매개변수값을 추정할 수 있었다. 가역반응의 경우에는 3개의 매개변수를 갖는 모델식의 형태로 평형 기질농도 및 매개변수를 추정할 수 있었다. 또한 반응특성이 잘 알려져 있지 않은 효소 반응 시스템에 있어서는 효소반응이 기질이나 생산물의 저해작용을 받는지 여부와 그 저해패턴을 확인할 수 있었다.

• 대한화학회지
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• 제12권2호
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• pp.61-64
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• 1968

Compressibility and expansibility of activation, ${\Delta}K^{\neq}\;and\;{\Delta}E^{\neq},$ are defined with the use of general principles that an activation parameter is the difference in partial molar quantities of the parameter for the transition and initial state. Two related parameters, (${\partial}{\Delta}H^{\neq}/{\partial}P)_{\gamma}\;and\;{\Delta}W^{\neq}(=P{\Delta}V^{\neq}),$ are also derived. Simpler interpretation of the existing kinetic data are possible with these activation parameters, while other derivations lead to complicated expressions of no practical significance.

• 상하수도학회지
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• 제20권3호
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• pp.329-338
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• 2006

The research aims to provide the basic data for practical applications by correlating the bio-kinetic coefficients with the load of recalcitrant organic matter in box-mill wastewater. The activated sludge process was employed to a Wastewater disposal plant in an industrial setting, increase of consequently leading to the organic load. The parameter values derived by Monod-kinetic analysis were as follows:specific substrate removal rate $K_{max}=0.17day^{-1}$, half saturation constants $K_s=60.37mg/l$, decay coefficient $K_d=0.142day^{-1}$, microbial yield coefficient y = 0.388mg/mg, and max specific growth rate ${\mu}_{max}=0.006day^{-1}$. In view of biodegradability, the $TCOD_{Mn}/TBOD_5$ ratios of inflow and outflow were 1.07 and 1.41, and the $SCOD_{Mn}/SBOD_5$ ratios of inflow and outflow were 1.10 and 1.50, respectively. The higher $TCOD_{Mn}/TBOD_5$ ratio of outflow indicated that metabolites of a microorganism have accumulated in the cells.

• 한국환경과학회지
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• 제7권6호
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• pp.773-782
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• 1998

The adsorption experiment of phenol(Ph) from aqueous solution on granular activated carbon was studied in order to design the fixed-bed adsorption column. The experimental data were analyzed by unsteady-state, one-dimensional heterogeneous model. Finite element method(FEM) was applied to analyze the sensitivity of parameter and to predict the fixed-bed adsorption column performance on operation variable changes. The prediction model showed similar effect to mass transfer and intraparticle diffusion coefficient changes suggesting that both parameter present mass transfer rate limits for GAC-phenol system. The Freundlich constants had a greater effect than kinetic parameters for the performance of fixed-bed adsorption column. FEM solution facilitated prediction of concentration history in solution and within adsorbent particle.

• Bulletin of the Korean Chemical Society
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• 제29권11호
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• pp.2145-2151
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• 2008

• 공업화학
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• 제23권2호
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• pp.204-209
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• 2012

상업용 루테늄 촉매 상에서 에탄의 수증기 개질 반응에 대한 kinetics 데이터를 얻기 위하여 반응온도, 에탄의 분압, 수증기/에탄의 비 등을 변화시키면서 반응 실험을 수행하였다. Kinetics 데이터를 사용하여 Power rate law kinetic model 과 Langmuir-Hinshelwood model의 parameter를 구하였다. 또한 kinetic model식을 적용하여 PRO/II를 이용한 공정 모사를 통해서 에탄의 수증기 개질 반응기 sizing을 수행하였다. 동일한 전환율을 얻기 위해서는 Power rate law model을 적용하였을 경우가 Langmuir-Hinshelwood model을 적용하였을 경우보다 개질 반응기의 부피가 더 큼을 알 수 있었다. Langmuir-Hinshelwood model에 의해 계산된 반응 속도가 반응 실험 결과에 의해 구해진 반응 속도와 더 잘 일치했기 때문에 Langmuir-Hinshelwood model을 적용하여 계산된 반응기의 크기가 실제 반응기 설계에 더 적절하다고 판단된다.

• 상하수도학회지
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• 제27권4호
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• pp.457-468
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• 2013

Based on the activated sludge model(ASM), a mathematical model which represents the aerobic sludge digestion by sequencing batch reactor(SBR) combined with ultrasonic treatment was composed and performed in this study. Aerobic digestion using sequencing batch reactor(SBR) equipped with ultrasound treatment was also experimented for the purpose of parameter calibration. Most of the presented kinetic parameters in ASM or ASM2 could be used for the aerobic digestion of sludge but the parameters related in hydrolysis and decay rate needed modification. Hydrolysis rate constant of organic matter in aerobic condition was estimated at $0.3day^{-1}$ and the maximum growth rate for autotrophs in aerobic condition was $0.618day^{-1}$. Solubilization reactions of particulate organics and nitrogen by ultrasonication was added in this kinetic model. The solubilization rate is considered to be proportional to the specific energy which is defined by specific ultrasound power and sonication time. The solubilization rate constant by ultrasonication was estimated at $0.202(W/L)^{-1}day^{-1}$ in this study. Autotrophs as well as heterotrophs also decomposed by ultrasonic treatment and the nitrification reaction was limited by the lack of autotrophs accumulation in the digester.

• KSBB Journal
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• 제13권1호
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• pp.52-57
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• 1998

The present work proposes a simple electrochemical method applicable to any immobilization processes of oxidase using a Clark type oxygen electrode as a base transducer. The present work suggests an optimal immobilization technique among three different methods of glucose oxidase(GOD) onto one side of $37[\mu}$mthick blend membranes, composed o 80% of cellulose triacetate and 20% of polycaprolactone, on the basis of the maximum Michaelis-Menten parameter(Vm) determined by either steady state or transient analyses. The electrode system was made of disk type gold cathode(4mm diameter) and Ag/AgCl anode. One side of the blend membrane was in contact with the cathode surface while the other side was immobilized with GOD either in covalent-bond or cross-linked forms, the latter being covered by $25{\mu}$m thick dialysis membrane of cellulose acetate. The resultant current density was on-line monitored by a potentiostat while glucose level was varied from 1 to 20 mM. The present study shows that direct cross-linking of GOD with glutaraldehyde was mostly preferred for fabrication of glucose sensor, on the basis of resultant kinetic parameters from either steady state or transient analyses.

• 감성과학
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• 제6권4호
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• pp.25-32
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• 2003

본 논문은 "풋 스캐너"와 "족압분석 시스템"을 이용하여 획득한 측정 데이터에서 새로운 보행분석 평가 방법을 제안하였다. 기존의 많은 연구자들에 의해서 보행시 발바닥의 육안적 검사와 압력분포의 분석 방법이 많이 논의되었다. 또한 연구자들은 압력곡선, 압력중심 궤적과 압력중심에서의 속도에 관해서 관심을 가져왔다. 그러나 이런 실험결과들은 실험환경과 피험자의 조건에 의해 의존된다. 결론적으로 우리는 이런 문제를 해결하기 위해 특별한 에너지 변수 등을 고려해야만 한다. 운동 에너지와 충격량 변수는 보행 분석에 활용될 수 있으며, 본 논문의 결과는 8명의 피험자들의 실험을 통하여 새로운 변수의 유용성을 확인하였다. 새로운 변수의 유용성을 확인하였다.

• Nuclear Engineering and Technology
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• 제50권7호
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• pp.1017-1023
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• 2018

The measurement and calculation of neutronic parameters in nuclear research reactors has an important influence on control and safety of the nuclear reactor. The power peaking factors, reactivity coefficients and kinetic parameters are the most important neutronic parameter for determining the state of the reactor. The position of the control shim safety rods in the core configuration affects these parameters. The main purpose of this work is to use the MTR_PC package to evaluate the effect of the partially insertion of the control rod on the neutronic parameters at the operating core of the Tehran Research Reactor. The simulation results show that by increasing the insertion of control rods (bank) in the core, the absolute values of power peaking factor, reactivity coefficients and effective delayed neutron fraction increased and only prompt neutron life time decreased. In addition, the results show that the changes of moderator temperature coefficients value versus the control rods positions are very significant. The average value of moderator temperature coefficients increase about 98% in the range of 0-70% insertion of control rods.