• Bulletin of the Korean Chemical Society
• /
• v.33 no.12
• /
• pp.4117-4121
• /
• 2012

The solvolysis rate constants of allyl chloroformate ($CH_2=CHCH_2OCOCl$, 3) in 30 different solvents are well correlated with the extended Grunwald-Winstein equation, using the $N_T$ solvent nucleophilicity scale and $Y_{Cl}$ solvent ionizing scale, with the sensitivity values of $0.93{\pm}0.05$ and $0.41{\pm}0.02$ for l and m, respectively. These l and m values can be considered to support a $S_N2$ reaction pathway. The activation enthalpies (${\Delta}H^{\neq}$) were 12.5 to 13.4 $kcal{\cdot}mol^{-1}$ and the activation entropies (${\Delta}S^{\neq}$) were -34.4 to -37.3 $cal{\cdot}mol^{-1}{\cdot}K^{-1}$, which is also consistent with the proposed bimolecular reaction mechanism. The solvent kinetic isotope effect (SKIE, $k_{MeOH}/k_{MeOD}$) of 2.16 was also in accord with the $S_N2$ mechanism. The values of product selectivity (S) for the solvolyses of 3 in alcohol/water mixtures was 1.3 to 3.9, which is also consistent with the proposed bimolecular reaction mechanism.

• Bulletin of the Korean Chemical Society
• /
• v.13 no.4
• /
• pp.395-398
• /
• 1992

Rate of solvolysis of dansyl chloride in aqueous binary mixtures of acetone, methanol and ethanol are reported. Kinetic solvent isotope effects in methanol and product selectivities in alcohol-water mixtures are also reported. Kinetic data are interpreted with the Grunwald-Winstein and Kivinen equations. The value of $k_{CH3OH}/k_{CH3OD}=1.76$ suggests that a general have catalyzed and/or an $S_AN$ pathway is operative in methanol, a less polar solvent. Rate-rate profiles for solvolysis of dansyl chloride in the aqueous binary media indicate a change in reaction channel from $S_AN$ (in less polar media) to $S_N2$ (in more polar media) mechanism.

• The Journal of Korean Institute for Practical Engineering Education
• /
• v.2 no.1
• /
• pp.154-163
• /
• 2010

The object of this study is to investigate the penetration characteristics according to the change of stacking sequences and curvature radius in the composite laminated shell. They are staked to [02/902]S and [0/902/0]s, their interlaminar number are two and four. We are manufactured to composite laminated shells with various curvature radius. Curvature radius of composite shell is 100, 150, 200mm and ${\infty}$(it's meaning flat-plate). In general, kinetic energy after impact-kinetic energy before impact increased linearly in all specimens. Absorbed energy increased linearly as the curvature increased, and absorbed energy of [02/902]S specimen, which is small interlaminar number, was higher than [0/902/0]s specimen.

• Bulletin of the Korean Chemical Society
• /
• v.35 no.1
• /
• pp.51-56
• /
• 2014

The solvolysis rate constants of 2,4-dimethoxybenzenesulfonyl chloride (1) in 30 different solvents are well correlated with the extended Grunwald-Winstein equation, using the $N_T$ solvent nucleophilicity scale and $Y_{Cl}$ solvent ionizing scale, with sensitivity values of $0.93{\pm}0.14$ and $0.65{\pm}0.06$ for l and m, respectively. These l and m values can be considered to support a $S_N2$ reaction pathway. The activation enthalpies (${\Delta}H^{\neq}$) were 12.4 to $14.6kcal{\cdot}mol^{-1}$ and the activation entropies (${\Delta}S^{\neq}$) were -15.5 to -$32.3kcal{\cdot}mol^{-1}{\cdot}K^{-1}$, which is consistent with the proposed bimolecular reaction mechanism. The solvent kinetic isotope effects (SKIE) were 1.74 to 1.86, which is also in accord with the $S_N2$ mechanism and was possibly assisted using a general-base catalysis. The values of product selectivity (S) for solvolyses of 1 in alcohol/water mixtures was 0.57 to 6.5, which is also consistent with the proposed bimolecular reaction mechanism. Third-order rate constants, $k_{ww}$ and $k_{aa}$, were calculated from the rate constants ($k_{obs}$), together with $k_{aw}$ and $k_{wa}$ calculated from the intercept and slope of the plot of 1/S vs. [water]/[alcohol]. The calculated rate constants, $k_{calc}$ ($k_{ww}$, $k_{aw}$, $k_{wa}$ and $k_{aa}$), are in satisfactory agreement with the experimental values, supporting the stoichiometric solvation effect analysis.

• Proceedings of the Korean Vacuum Society Conference
• /
• 1999.02a
• /
• pp.135-135
• /
• 1999

• Journal of The Geomorphological Association of Korea
• /
• v.19 no.2
• /
• pp.133-143
• /
• 2012

To evaluate the kinetic energy of the raindrops, the drop size distribution and the terminal velocity of the raindrops had been measured from January to September 2010 using the laser-optical disdrometer in KIGAM, Daejeon, Korea. The relationship between kinetic energy (KE) and rainfall intensity (I) was computed as logarithmic and exponential model, respectively, under the rainfall intensity of about 142mm/h. The exponential model is more suitable for the relationship of KE-I than the logarithmic model, because the exponential model presented better fit for KE over 50mm/h of rainfall intensity. Meanwhile, the differences of the total kinetic energy existed in rainfall events with almost same total rainfall depth, and KE values of Daejeon at high rainfall intensity underestimated rather than the others under temperate climate. Therefore, these differences of KE in rainfall events and geographical regions imply the result from the variations of rainfall intensity within a rainfall event.

• Korean Journal of Applied Biomechanics
• /
• v.20 no.1
• /
• pp.67-73
• /
• 2010

The purpose of this study was to compare the differences in kinematic and kinetic parameters of the ankle and knee joint according to three landing direction(central, left, right). Fifteen collegiate male athletes(age: $22.7{\pm}3.5$ years, height: $174.9{\pm}7.1\;cm$, weight: $69.4{\pm}6.7\;kg$) with the right leg as dominant were chosen. The subjects performed series of drop landings in three directions. In terms of the three different landing directions, plantar flexion was the greatest during the central drop landings. For each initial contact of the landing direction, plantar flexion of the ankle was greatest at the central drop landing, inversion of the ankle was greatest at the right landing and valgus of the knee was greatest at the left drop landing. Regarding the peak force, the greatest was at the 1st peak force during the central drop landing. For the time-span of the 2nd peak force and the 2-1 peak force, both right sides resulted as the greatest. Therefore, with the appropriate training in landing techniques and developing neuromuscular training for proprioception by taking the injury mechanisms on ankle and knee during drop landings into account, it will assist in preventing such injuries.

• Korean Journal of Applied Biomechanics
• /
• v.24 no.3
• /
• pp.239-248
• /
• 2014

The purpose of this study was to quantify kinematic and kinetic characteristics of Yin-yang Bo gait according to their motor expertise, one of the Seokmun Ilwol martial art gait patterns. Yin-yang Bo gait pattern shows initial forefoot contact instead of heel contact, and increased time of stance phase time, internal-external rotation of ankle-knee-hip joints and pelvic. It aims to produce and store the more energy through continuous homeostasis of center of gravity (COG) and performance of stretch-shortening cycle. Some of these characteristics also were similar to the gait modification strategies for reducing knee adduction moment such as toe-out progression, medial thrust, internal rotation of hip joint. To identify the characteristics, four factors of expert Yin-yang Bo gait performance group were compared to that of none expert group; 1) angles of COG displacement and rotation 2) distal joint pre-rotation in internal-external rotation of ankle-knee-hip joints and pelvic, 3) invariability pelvic potential and pelvic segment total energy 4) knee abduction moment. Six healthy(three male) subjects participated in the experiment to perform Yin-yang gait pattern. Three-dimensional and force plate data were collected. Kinematic and kinetic data were compared between two groups using t-tests. Results showed that 1) the peak point of COG internal rotation angle was reduced in expert group, 2) kneeexternal and hip joint -internal and pelvic rotation angle peak frames were more near points in expert group.

• Bulletin of the Korean Chemical Society
• /
• v.30 no.11
• /
• pp.2779-2781
• /
• 2009

• Korean Journal of Applied Biomechanics
• /
• v.22 no.2
• /
• pp.253-259
• /
• 2012

The purpose of this study was to determine how smartphone use posture affects biomechanical variables and muscle activities. Eleven university students(age: $22.2{\pm}2.6$ yrs, height: $176.6{\pm}4.7$ cm, weight: $69.5{\pm}7.5$ kg) who have no musculoskeletal disorder were recruited as the subject according to having experience in using the smartphone for more than one year. Angular velocity, muscle activity, and thumb finger pressure were determined for each trial. For each dependent variable, a one-way analysis of variance (ANOVA) with repeated measures was performed to test if significant difference existed among different three conditions (p<.05). The result showed that rotational angular velocity of the first metacarpal were increased in DESK posture compared with STAND posture during SU phase. The average nEMG values of FDI(First dorsal interosseous) were less in SIT and DESK posture compared with STAND posture during SR phase. These indicated that smartphone postures may effect the thumb ROM(Range of motion) and muscle activity. This has led to suggestions of the need for further kinetic and EMG analyses to evaluate best assess and characterize with smartphone use.