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Soil Washing of Abandoned Mine Soils Contaminated by Heavy Metals (중금속 오염 폐광산 주변토양의 세정)

  • Lee, Jun-Ho;Nam, Kwon-Chul;Park, Kap-Song
    • Journal of Korean Society on Water Environment
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    • v.22 no.5
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    • pp.871-878
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    • 2006
  • Batch experiments were performed to evaluate the applicability of soil washing for heavy metal contaminated soils at Nacdong and Hamchang abandoned mines. The texture of the Nacdong soil was sandy loam. Nacdong abandoned mine soil was almost neutral (pH=6.5). Contaminations of As, Cd, Pb and Zn for Nacdong mine soils were 12,900 mg/kg, 29 mg/kg, 696 mg/kg and 276 mg/kg, respectively. Hamchang abandoned mine soils were acidic (pH=2.6) and the soil texture was loam. The contaminations of As, Cd, Pb and Zn for Hamchang abandoned mine soils were 6,410 mg/kg, 291 mg/kg, 1,300 mg/kg and 1,110 mg/kg, respectively. For the Nacdong abandoned mine soils, oxalic acid was found to be the most effective soil washing extracter for As and Pb while citric acid was the most effective extracter for Cd. For the Hamchang abandoned mine soils, oxalic acid showed the highest extraction efficiencies for As and Pb, whilst citric acid presented the best soil washing efficiencie for Cd. Oxalic acid and EDTA were found to be the most effective soil washing extracter for the Hamchang abandoned mine contaminated soils.

Calibration and Verification of HSPF Model for Total Maximum Daily Loads (오염총량관리를 위한 HSPF 모형의 보정과 검정)

  • Kim, Sang Min;Park, Seung Woo
    • Proceedings of the Korea Water Resources Association Conference
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    • 2004.05b
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    • pp.527-531
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    • 2004
  • 본 연구에서는 미국 환경청에서 개발하여 유역 오염총량관리를 위한 수질모형으로 이용되고 있는 HSPF 모형을 선정하여 발안 $HP\#6$ 시험유역을 내상으로 모형의 적용성을 분석하였다. HSPF 모형을 이용하여 $HP\#6$ 시험유역에서 모형의 보정기간인 1996년부터 1997년까지 유출량을 모의한 겉과, RMSE는 2.1mm, RMAE는 0.4mm, $R^2$는 0.92로 모의되었으며, 모형의 검정기간인 1999년부터 2000년의 모의 길과 RMSE는 6.03mm, RMAE는 0.49mm, $R^2$는 0.84로 모의되었다. 총질소에 대한 모형의 보정결과 RMSE는 0.086kg/ha/day, RMAE는 0.534kg/ha/day, $R^2$는 0.812로 나타났으며, 모형의 검정결과 RMSE는 0.326kg/ha/day, RMAE는 0.708kg/ha/day, $R^2$는 0.427로 분석되었다. 총인에 대한 모형의 보정결과 RMSE는 0.0117 kg/ha/day, RMAE는 0.622kg/ha/day, $R^2$는 0.70으로 모의되었으며, 모형의 검정결과 RMSE는 0.063kg/ha/day, RMAE는 2.269kg/ha/day, $R^2$는 0.756으로 분석되었다.

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Grading of Fermented and Dried Cocoa Beans Using Fungal Contamination, Ergosterol Index and Ochratoxin a Production

  • Aroyeun, S.O.;Adegoke, G.O.;Varga, J.;Teren, J.
    • Mycobiology
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    • v.37 no.3
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    • pp.215-217
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    • 2009
  • Sixty four samples of cocoa beans replicated in quadruplicates were collected from five warehouses from southwest Nigeria and examined for fungal loads, ergosterol and eohratoxin A The levels of all the variables obtained were further used as indices for cocoa grading into food quality, FoQ (erg < 5 mg/kg; OTA < $1{\mu}g$/kg), feed quality, FeQ (erg = $5{\sim}10\;mg$/kg; OTA in the range of $1.1{\sim}3.11{\mu}g$/kg), Screen for mycotoxin, SFM (erg = $10{\sim}20\;mg$/kg; OTA from $3.12{\mu}g$/kg and above) with fuel quality, FuQ having erg > 20 mg/kg and OTA > $6.12{\mu}g$/kg. Using these ergosterol indices, 18.75% of the cocoa beans examined was classified with the FoQ, 18.75% with the FuQ while 31.25% was classified with both the FeQ and the SFM, respectively. In conclusion, ergosterol can be used as a rapid index to grade fermented, dried cocoa beans meant for export.

Bioavailability and Comparative Pharmacokinetics of Two Enrofloxacin Formulations in Broiler Chickens (육계에서 경구투여시 enrofloxacin 제제에 따른 생체이용율 및 약물동태)

  • 윤효인;박승춘
    • Journal of Veterinary Clinics
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    • v.14 no.2
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    • pp.195-200
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    • 1997
  • In order to compare the pharmacokinetic profiles of enrofloxacin-HCL)ENFLX-HCL) and enrofloxacin-KOH (ENFLX-KOH) after oral administration in broiler chickens, the study was performed. The chickens used in this study weighed $1.82 {\pm}0.2 kg$ and clinically healthy. The dose of intravenous and lral administration was 5 mg per kg of body weight as enrofloxacin. After intravenous injection of enrofloxacin, it showed two-compartment model with the rapid distribution phase and the slow elimination phase. The mean apparent volume of distribution (Vd) was 2.70 l/kg. The mean half-life of elimination and distribution showed 8.26 h and 0.44 h, respectively. The mean area under curve (AUC) was calculated as $19.7 {\mu} g{\cdot} h/ml$. After oral administration of ENFLX-HCL and ENFLX-KOH with a rate of dose 5 mg of enrofloxacin/kg of body weight, Both of the products were showed one-compartment model unlike that of i.v. enrofloxacin standard solution showed the mean bioavailability of 79.64% for the ENFLX-KOG and 86.24% for the ENFLX-HCL. The mean total body clearance of the former was 0.24 l/kg/h and the latter 0.42 l/kg/h. Both enorfloxacin formulations seemed to have good tissue distribution and penetration as indicated by large volume of distribution : 2.72 l/kg for the -KOH and 4.44 l/kg for the -HCL. With the results obtained in this study, ENFLX-HCL could be used in place of its salt form in chickens.

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Nitrites contents on processed meat products(ham, sausage etc) in market during 2000-2003 (시판 식육가공품(햄류, 소시지류 등)에 대한 최근 4년간(2000-2003) 아질산이온 함량)

  • 함희진;홍인석;임홍규;양윤모;최윤화;김창기;권택부;이정학
    • Korean Journal of Veterinary Service
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    • v.27 no.2
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    • pp.115-120
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    • 2004
  • Contents of nitrites was tested in 2,290 meat products during 2000-2003, in Seoul by Diazoa method. It was detected over 40 ppm NO$_2$$\^$-/ contents in 20 hams, 7 sausages, one bacon, and one crushed meat product respectively. Also, over 20ppm nitrites was 21.8%(240/1,103) in hams, 20.7%(122/589) in sausages, 6.8%(14/205) in crushed meats, and in 6.0%(5/83) bacons respectively. In case of average contents and contents range, 0.012 g/kg, ND-0.116 g/kg in hams, 0.012 g/kg, ND-0.066 g/kg in sausages, 0.010 g/kg, 0.001-0.089 g/kg in bacons, and 0.006 g/kg, ND-0.040 g/kg in crushed meats etc. Specially, in sausages, it was increased continually by years, in not only average nitrites contents but also their contents range, also, in case of bacons, increased continually by years on only average nitrites contents. According to results, the NO$_2$$\^$-/ contents monitoring for the processed meat products must be reinforced to supply safety food for the citizens.

한우(암,수,거세) 및 유우 거세우의 산육 특성비교

  • Park, Beom-Yeong;Jo, Su-Hyeon;Kim, Jin-Hyeong;Lee, Seon-Ho;Cha, Jae-Mu;Kim, Dong-Hun;Yun, Yeong-Tak;Lee, Jong-Mun
    • Proceedings of the Korean Society for Food Science of Animal Resources Conference
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    • 2004.05a
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    • pp.279-282
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    • 2004
  • 현재 국내 부분육 상장으로 판매되는 한우와 유우 거세우 558두의 도체 및 산육 특성을 비교한 결과 평균 도체중은 유우 거세우가 396kg으로 가장 높았고, 한우 암소가 326kg으로 가장 낮았다. 거래정육중에서는 유우 거세우와 한우 수소가 각각 253kg, 232kg으로 가장 높았고, 한우 암소가 199kg으로 가장 낮았다. 반면 체지방 생산량에서는 거세우가 94kg으로 가장 높았고, 한우 수소가 65kg으로 가장 낮았다. 350${\sim}$400kg 미만의 도체중범위에 있는 조사축의 도체 특성을 비교한 결과 거래정육율은 한우 수소가 67.8%로 가장 높았고, 유우 거세우 64.5%, 한우거세우 61.3%, 한우 암소 59.2%순으로 나타났다(p<0.05). 한우 거세우와 유우 거세우간의 거래정육율 차이는 한우 거세우가 유우 거세우에 비하여 3.2% 낮은 것으로 조사되었다. 뼈 생산율에 있어서는 유우 거세우가 15.4%로 가장 높고, 한우 암소가11.1%로 가장 낮은 경향을 보였다(p<0.05). 유우 거세우와 한우 수소간의 뼈율 차이는 2.13%, 유우 거세우와 한우 거세우간의 뼈율 차이는 3.45% 차이가 있었다. 체지방율에 있어서는 한우 수소와 유우 거세우가 각각 17.6%, 18.5%로 가장 낮았고, 한우 거세우 24.8%, 한우 암소 27.1% 순이었다(p<0.05).

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Studies on the Concurrent Administration of Medicines(VII) (의약품의 병용투여에 관한 연구 (VII))

  • 변순희;김일혁
    • YAKHAK HOEJI
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    • v.31 no.3
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    • pp.133-139
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    • 1987
  • These studies were attempted to investigate the preventive effect of Ganoderma lucidum extract administered concurrently with glutathione on the liver damage induced by carbon tetrachloride ($CCl_4$) in rats. S-GOT and S-GPT activities of all the pre-treatment groups were significantly decreased, as compared with those of the control intoxicated by $CCl_4$. The concurrent administrations of Ganoderma lucidum extract with glutathione (100+100mg/kg, 200+100mg/kg, and 400+100mg/kg, respectively) were more effective than the individual administrations. i.e., Ganaderma lucidtcm extract (100, 200 and 400mg/kg, respectively) and glutathione (100, 200 and 400mg/kg, respectively). On the determination of lipid-peroxidation in liver, the concurrent administrations of Ganoderma lucidum extract with glutathione (100+100mg/kg, and 200+100mg/kg, respectively) significantly reduced the liver TBA values. Although hepatic cellular necrosis and fatty acid deposit were remarkably increased by $CCl_4$ intoxication, the concurrent administration of Ganoderma lucidum extract with glutathione (200+100mg/kg) reduced the pathological changes of parenchymal cell necrosis and fatty changes around centrilobalar area of the control. These findings indicate that the concurrent administrations of Ganoderma lucidum extract with glutathione showed better improvements than the individual administrations of them in all pathological aspects, in particular, against hepatitis and hepatic necrosis due to the cellular necrosis and fatty infiltration.

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Studies on the Phosphatic Fertilizer Application in Grassland III. Effects of phosphatic fertilization levels on the yield and nutrient contents of grasses (초지에 대한 인산질비료의 시용에 관한 연구 III. 인산질비료의 시용수준이 목초의 수량 및 양분함량에 미치는 영향)

  • 박근제;이필상;최기준;정재두
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.14 no.1
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    • pp.13-17
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    • 1994
  • To find out the effects of phosphatic fertilizer application level on the dry matter yield and nutrient contents of grasses, this experiment was arranged as a randomized complete block design with six treatments(0, 50, 100, 150, 200 and 250kg $P_2O_5$/ ha) and conducted at hill land in Gwangju, Gyeonggi Province from September, 1989 to October, 1992. The results obtained are summarized as follows : 1. As the phosphatic fertilization level increase, the early growth and cover degree of grasses wintered were more favorable and plant length was higher. 2. With 150kg $P_2O_5$/ ha application for three years, the average dry matter yield of grasses, 10,112kgl ha was sirnilared to that of 200kg $P_2O_5$/ ha and the yield was composed of 77.2% grasses(7,808kg/ ha), 19.2% legumes(l,937kg 1 ha) and 3.6% weeds(367kg / ha). 3. The crude protein and energy productivity of grasses increase as phosphatic fertilization level was increased, but those were not different between 150 and 250kg $P_2O_5$ 1 ha. Therefore, phosphatic fertilization level must be applied with 150kg / ha for a reasonable management in hilly grassland.

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Heavy Metal Content and distribution of Bioorganisms in Mankyeong.Dongjin River Area (만경강 . 동진강 하구역 생물체(벼, 패류, 망둑어) 중 중금속 함량 및 분포)

  • 권용훈;황갑수;장재철
    • Journal of Environmental Health Sciences
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    • v.26 no.2
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    • pp.116-121
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    • 2000
  • This study was performed to investigate the heavy metal contents and distribution in bioorganisms from the estuary area of Mankyeong-Dongjin river. In paddy plant, the average contents of heavy metals were in order of Zn>Cu>Pb>Cr>Cd in all parts. Those of Cd, Cr, Pb and Cu were all highest in the leaf while lowest in the brown rice. The average content of Zn was almost similar in all parts. In the dried muscular parts of shellfish, the average contents of heavy metals were in the range of 1.06~1.95 mg/kg for Cd, 2.93~4.98 mg/kg for Cr, 0.90~1.17 mg/kg for Pb, 8.41~18.58 mg/kg for Cu and 29.81~67.31 for Zn, respectively, In fish(Acanthogobius hasta), the average contents of heavy metals in the dried body parts were in the range of 0.05~0.43 mg/kg for Cd, 0.65~4.59 mg/kg for Cr, 1.01~4.75 mg/kg for Pb and 1.34~4.19 mg/kg for Cu, with high accumulation in bone and head overally.

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Toxicity of Mixtures of Diazinon, Toxaphene and/or Endrin in Mice (Diazinon, Toxaphene, Endrin과 그 혼합물의 독성효과)

  • 김종수;하대식;손성기
    • Toxicological Research
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    • v.12 no.2
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    • pp.231-236
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    • 1996
  • The toxicity of the mixture of diazinon, toxaphene(TOX) and/or endrin was studied in ICR male mice(18-22 g) by oral intubation, in corn oil, daily for up to 14 days. On day 15, the exposure was discontinued and animals were monitored for an additional period of 7 days for the possible reversibility of the toxicity. The body weight gain decreased with the mixtures, as well as with the individual pesticides, during the 14-day period. TOX and TOX containing mixtures significantly increased the liver/body weight ratio. The serum glutamic pyruvic transaminase level increased at 23~374% in diazinon, TOX, and endrin or their mixture group. The cholinesterase(ChE) activity in the serum and brain was inhibited in the animals of the group of diazinon(5, 10 mg/kg) and diazinon(5 mg/kg) containing mixtures. TOX(40, 80 mg/kg) caused initial inhibitory effects on the serum ChE Day 1. but there is little effects on the brain ChE levels. endrin(5,10 mg/kg) results in significantly elevated levels of the serum ChE, with substantial decreases in the brain ChE activity. TOX and TOX containing mixtures decreased the pentobarbital(60 mg /kg, ip., in saline) induced sleep. The effects produced by this pesticides singly, as well as by their mixtures, appeared to be reversible in nature. The toxic effects exhibited by the mixtures of diazinon(5 mf/kg), TOX(40 mg/kg), and /or endrin(5 mg/kg) were found to be the resultant of the effect showed by their components individually.

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