• Title/Summary/Keyword: KLN

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분광학적 방법을 이용한 LN 및 KLN 단결정의 조성분석

  • 김태훈;유영문;노지현
    • Proceedings of the Optical Society of Korea Conference
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    • 2002.07a
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    • pp.92-93
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    • 2002
  • 선형 및 비선형 광학 특성이 뛰어난 것으로 잘 알려진 LiNbO$_3$ (LN) 및 $K_3$Li$_2$Nb$_{5}$O$_{15}$ (KLN) 단결정을 원료분말의 조성 등과 같은 결정성장 조건을 달리하여 Czochralski 방법으로 성장시켰다. LN과 KLN 단결정의 경우 성장온도가 고온이기 때문에 Li, K 이온의 휘발에 의해 성장된 결정의 조성은 원료분말의 조성과 다르다. 따라서 성장된 단결정의 조성을 분석하는 것은 응용을 위해 매우 중요한 일이다. (중략)

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The Effect of Deposition Parameters on the Morphology of KLN Thin Films (증착 조건이 KLN 박막의 형상에 미치는 영향)

  • Park, Seong-Geun;Jeon, Byeong-Eok;Kim, Jin-Su;Kim, Ji-Hyeon;Choe, Byeong-Jin;Nam, Gi-Hong;Ryu, Gi-Hong;Kim, Gi-Wan
    • Korean Journal of Materials Research
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    • v.11 no.1
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    • pp.27-33
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    • 2001
  • The growth characteristics of 4-fold grain which was appeared in KLN deposition on $Pt/Ti/SiO_2/Si(100)$ substrate was studied by varying process variables. Substrate temperature, sputtering pressure, rf power were selected as process variables, and experiment was carried out near optimum fabrication condition. When using K and Li enriched target, the optimum fabrication conditions were substrate temperature of $600^{\circ}C$, sputtering pressure of 150mTorr, rf power of 100 W and its surface morphology is sensitively varied by small deposition condition changes. KLN is composed of elements which have large difference of boiling point. And it is difficult to fabricate thin film at high temperature and high vacuum deposition condition. Furthermore the phenomenon during deposition process can not be explained by using Thorton's model which explains the relation between thin film structure and melting point of thin film materials. These phenomenon can be explained using boiling point of elements which consist of thin film material.

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Mapping Heterogenous Ontologies for the HLP Applications - Sejong Semantic Classes and KorLexNoun 1.5 - (인간언어공학에의 활용을 위한 이종 개념체계 간 사상 - 세종의미부류와 KorLexNoun 1.5 -)

  • Bae, Sun-Mee;Im, Kyoung-Up;Yoon, Ae-Sun
    • Korean Journal of Cognitive Science
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    • v.21 no.1
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    • pp.95-126
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    • 2010
  • This study proposes a bottom-up and inductive manual mapping methodology for integrating two heterogenous fine-grained ontologies which were built by a top-down and deductive methodology, namely the Sejong semantic classes (SJSC) and the upper nodes in KorLexNoun 1.5 (KLN), for HLP applications. It also discusses various problematics in the mapping processes of two language resources caused by their heterogeneity and proposes the solutions. The mapping methodology of heterogeneous fine-grained ontologies uses terminal nodes of SJSC and Least Upper Bounds (LUB) of KLN as basic mapping units. Mapping procedures are as follows: first, the mapping candidate groups are decided by the lexfollocorrelation between the synsets of KLN and the noun senses of Sejong Noun Dfotionaeci(SJND) which are classified according to SJSC. Secondly, the meanings of the candidate groups are precisely disambiguated by linguistic information provided by the two ontologies, i.e. the hierarchicllostructures, the definitions, and the exae les. Thirdly, the level of LUB is determined by applying the appropriate predicates and definitions of SJSC to the upper-lower and sister nodes of the candidate LUB. Fourthly, the mapping possibility ic inthe terminal node of SJSC is judged by che aring hierarchicllorelations of the two ontologies. Finally, the ituorrect synsets of KLN and terminologiollocandidate groups are excluded in the mapping. This study positively uses various language information described in each ontology for establishing the mapping criteria, and it is indeed the advantage of the fine-grained manual mapping. The result using the proposed methodology shows that 6,487 LUBs are mapped with 474 terminal and non-terminal nodes of SJSC, excluding the multiple mapped nodes, and that 88,255 nodes of KLN are mapped including all lower-level nodes of the mapped LUBs. The total mapping coverage is 97.91% of KLN synsets. This result can be applied in many elaborate syntactic and semantic analyses for Korean language processing.

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Single crystal growth of potassium lithium niobate for nonlinear optics (비선형광학재료 Potassium lithium niobate 단결정 육성)

  • 강길영;윤종규
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.7 no.3
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    • pp.384-392
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    • 1997
  • Potassium lithium niobate(KLN) single crystal for a nonlinear-optic material, which changes the wavelength of lasers, has a ferroelectric tetragonal tungsten bronze structure at room temperature. It has been very hard to get single crystals of good quality due to the cracks during cooling process. In order to investigate the composition change due to the evaporation of solution during the growth, the thermogravimetric analysis was carried out. In atmospheric condition at $1000^{\circ}C$ which is about $10^{\circ}C$ higher than the crystal growing temperature, the weight change was negligible amount of $1.46{\times}10^{-5}$g/($\textrm{cm}^2$hr). By using both the Pt plate as the nucleation site and the slow cooling method with temperature fluctuation, KLN single crystal of good quality of size 1 cm could be obtained. The phase transition temperature was $490^{\circ}C$, which was higher than that reported by other researchers of the other composition. The optical anisotropy due to the absorption of OH-band exists in the range of IR.

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$K_3Li_2(Nb_xTa_{1-x})_5O_{15}$ 세라믹스의 Nb/Ta비에 따른 전기적 특성 변화

  • Kim, Yeong-Seop;Lee, Jun-Hyeong;Kim, Jeong-Ju;Lee, Hui-Yeong;Jo, Sang-Hui
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.08a
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    • pp.39-39
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    • 2003
  • 텅스텐브론즈 세라믹스의 결정구조는 산소 팔면체를 뼈대로 각각 다른 형태의 A, C, B 양이온 자리로 이루어져 있다. A, C의 양이온 자리는 알카리 이온 또는 알카리 토금속 이온으로 채워지며, B 자리는 Nb 또는 Ta 이온으로 채워지게 된다. 이 중 A와 C 자리가 채워지는 정도로 unfilled, filled, completely filled 텅스텐브론즈로 나누어지게 된다. completely filled 텅스텐브론즈의 대표적인 물질인 $K_3Li_2Nb_5O_{15}$(KLN)는 전광특성, 비선형 광학특성으로 인하여 다양한 광소자로의 응용과 압전 특성, 초전 특성을 이용한 압전 소자로의 응용이 가능한 재료로 보고되고 있다. 하지만 이러한 꽉 찬 결정구조로 인하여 KLN의 경우 한정된 고용영역을 가지고 있어 물리적 성질의 변화가 제한되어 있는데, 이를 극복하기 위한 여러 가지 시도가 있었다. 이 중 A 자리와 C 자리를 치환하는 연구는 많이 알려져 있으나 치환시 빈 자리를 수반하는 경우가 대부분이다. 반면, B 자리를 치환하는 연구는 Nb를 Ta로 치환하는 경우가 알려져 있는데 이 경우 결정내에 빈자리가 생성되지 않는다. 이들 연구는 모두 단결정의 경우에 국한되어 있으며 단결정 제조시에는 조성을 정확히 조정하기 어렵고, 냉각시 crack이 발생하는 등의 문제를 가지고 있어 그 응용이 제한되고 있다. 따라서 본 연구에서는 KLN 다결정 세라믹스에서 Nb를 Ta으로 치환하여 치환에 따른 상변화와 치밀화 거동, 그리고 이에 따른 전기적 특성을 조사하여 이들 간의 상관관계를 조사하였다.

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Growth and Characteristic Infrared Raman Spectra of Potassium Lithium Niobate Single Crystals

  • Youbao Wan;Yoo, Sang-Im
    • Proceedings of the Korea Crystallographic Association Conference
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    • 2002.11a
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    • pp.15-15
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    • 2002
  • Homogeneous and crack-free potassium lithium niobate (K₃Li/sub 2-x/Nb/sub 5+x/O/sub 15/, 0<x<0.5, KLN) single crystals were successfully grown by the Czochralski technique. The KLN single crystals of several different compositions were employed for the investigation of the lattice vibration spectra using infrared Raman spectroscopy. The characteristic Raman spectra of the [NbO/sub 6/]/sup 7-/ octahedral ions were strikingly influenced by the Li ion content. The symmetric stretch vibrational modes V₁, V₂ are broadened, and the symmetric bend vibration mode V/sub 5/ is broadened and even split into three peaks with increasing the Li content, supporting that the bend vibration modes of the [NbO/sub 6/]/sup 7-/ octahedrons are obviously perturbed by Li ions in the C site. Enhanced Raman peak intensities after the post annealing at 900℃ and for 24 h evidenced that a residual stress in as-grown crystals was negligible and only a defect concentration might be reduced.

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The growth and characteristics $K_3$$Li_2$$Nb_5$$O_{15}$ of single crystals ($K_3$$Li_2$$Nb_5$$O_{15}$ 단결정의 성장과 특성에 관한 연구)

  • 김진수;김정남;김태훈;노지현;진병문
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.9 no.5
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    • pp.463-469
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    • 1999
  • The potassium lithium niobate $K_3$$Li_2$$Nb_5$$O_{15}$ single crystals were growing in $K_x$$Li_{1-x}$$NbO_3$ (x = 0.4~0.6) chemical formular by the Czorchralski method. Crystal growth is studied in two orientations with growth along a-axis and c-axis. We have subjected this crystal to x-ray diffraction studies and found that they are single-crystalline and belong to tetragonal system with the lattice parameters a = b = 12.577 $\AA$ and c = 3.997$\AA$. The temperature dependence of dielectric constant was measured in the region of the phase transition. Curie temperature and diffuseness of phase transition are influenced by composition concentration. The composition and cation distribution of ferroelectric TB-type niobate crystals has a strong influence on the ferroelectric properties. Growth condition, optical transmittance, etching pattern and dielectric properties are presented and discussed.

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Cross-Enrichment of the Heterogenous Ontologies Through Mapping Their Conceptual Structures: the Case of Sejong Semantic Classes and KorLexNoun 1.5 (이종 개념체계의 상호보완방안 연구 - 세종의미부류와 KorLexNoun 1.5 의 사상을 중심으로)

  • Bae, Sun-Mee;Yoon, Ae-Sun
    • Language and Information
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    • v.14 no.1
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    • pp.165-196
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    • 2010
  • The primary goal of this paper is to propose methods of enriching two heterogeneous ontologies: Sejong Semantic Classes (SJSC) and KorLexNoun 1.5 (KLN). In order to achieve this goal, this study introduces the pros and cons of two ontologies, and analyzes the error patterns found during the fine-grained manual mapping processes between them. Error patterns can be classified into four types: (1) structural defectives involved in node branching, (2) errors in assigning the semantic classes, (3) deficiency in providing linguistic information, and (4) lack of the lexical units representing specific concepts. According to these error patterns, we propose different solutions in order to correct the node branching defectives and the semantic class assignment, to complement the deficiency of linguistic information, and to increase the number of lexical units suitably allotted to their corresponding concepts. Using the results of this study, we can obtain more enriched ontologies by correcting the defects and errors in each ontology, which will lead to the enhancement of practicality for syntactic and semantic analysis.

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