• Title/Summary/Keyword: KIER

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Characterization of Chemical Bath Deposited ZnS Thin Films and Its application to $Cu(InGa)Se_2$ Solar Cells (용액성장법에 의한 황화아연 박막층 분석 및 이의 CIGS 태양전지로의 응용)

  • Shin, Dong-Hyeop;Larina, Liudmila;Yun, Jae-Ho;Ahn, Byung-Tae
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.06a
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    • pp.138-138
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    • 2009
  • Recently, thin-film solar cells of Cu(In,Ga)$Se_2$(CIGS) have reached a high level of performance, which has resulted in a 19.9%-efficient device. These conventional devices were typically fabricated using chemical bath deposited CdS buffer layer between the CIGS absorber layer and ZnO window layer. However, the short wavelength response of CIGS solar cell is limited by narrow CdS band gap of about 2.42 eV. Taking into consideration the environmental aspect, the toxic Cd element should be replaced by a different material. It is why during last decades many efforts have been provided to achieve high efficiency Cd-free CIGS solar cells. In order to alternate CdS buffer layer, ZnS buffer layer is grown by using chemical bath deposition(CBD) technique. The thickness and chemical composition of ZnS buffer layer can be conveniently by varying the CBD processing parameters. The processing parameters were optimized to match band gap of ZnS films to the solar spectrum and exclude the creation of morphology defects. Optimized ZnS buffer layer showed higher optical transmittance than conventional thick-CdS buffer layer at the short wavelength below ~520 nm. Then, chemically deposited ZnS buffer layer was applied to CIGS solar cell as a alternative for the standard CdS/CIGS device configuration. This CIGS solar cells were characterized by current-voltage and quantum efficiency measurement.

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출연(연)의 신기술개발 동향분석 연구

  • 이병민
    • Proceedings of the Korea Technology Innovation Society Conference
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    • 2003.05a
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    • pp.413-425
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    • 2003
  • Information Technology is the kernel technology deciding the industrial standard of one nation, and biotechnology will be the main technology of next generation. Based on this fact, a lot of efforts were made to industrialize them. Nano Technology is beginning to position itself as the kernel fusion technology, and its usage and popularity is expanding. Environmental and Energy Technology is a must-have strategic technology considering the increase demand of new energy development, the international environment correspondence, the environment-friendly production, and so forth. Space Technology is the field, which will contribute to raise the domestic component and system technology to the next level. In 2001, new technology research development costs total of 1 trillion 32 billion won in the following fields; 437.82 billion won in IT, 88.457 billion won in BT, 46.799 billion won in NT, 315.682 billion won in ET, and 112 billion won in ST. from component ratio, IT forms 42% which is the most, 31% for ET and in order of BT, ST and NT. ETRI and KISTI are concentrating on IT, KIBB is on BT, KAERI, KIER, KERI and KBSI are focusing on ET, and KIMM, KRISS, KRICT and KORDI is participating together in 4∼5 new technology such as IT, BT, NT and ET. Funds for research development costs in 5 new technology fields of 13 contribution (year) are consisted as follows; The Office for Government Policy Coordination has contributed 131 billion won (13%), 387 billion won (37%) by MOST, 256 billion won (25%) by Ministry of Information and Communication, 67 billion won (6%) by Ministry of Commerce, Industry and Energy, 19% by others and the industrial world. < Strategy for Technology Advancing > o Promotion of comprehensive contributing (year) new technology development research plan project o Increase research efficiency by promoting new technology development project connected with peculiar projects of organization by contribution (year) o Formation of superior research group by technology and introduction of operation system for research accumulation are needed. o Technology demand-oriented assignment deduction and promotion of research development project connected with intermediate long term objective o National will and investment extension of research development costs, training and popularization of professionals, commercialization promotion with efficient control for research plan and result.

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The Photocatalytic Decomposition of Trichloroethylene(TCE) with $TiO_2$ ($TiO_2$광촉매를 이용한 Trichloroethylene(TCE)의 광분해 반응)

  • 하진욱
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.1 no.2
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    • pp.57-62
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    • 2000
  • The photocatalytic degradation of trichloroethylene(TCE) in water on various types of$TiO_2$ was studied. Surface properties of $TiO_2$were characterized by XRD, SEM, and BET in our previous work(23) . $TiO_2$from Aldrich has 100$\%$pure anatase, TiO$_2$from KIER has 100$\%$ pure rutile structure, and P25-TiO$_2$from Degussa has mixed structure of anatase(75$\%$) and rutile(25$\%$) . Firstly, optimum conditions for TCE degradation were examined in this study. Results showed that optimum loading amount of catalyst was 0.1 wt% and recirculation flow rate of mixture(distilled water and TCE) was 200 cc/min. Secondly, the effect of $TiO_2$structure on TCE degradation was examined. Results revealed that anatase structure generally has better photocatalytic activity than rutile structure. Especially, mixed structure(Degussa P25-$TiO_2$) has the highest activity due to small particle size and large specific surface area.

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The Development and Performance Analysis of Compact Type Solar Thermal/Ground Coupled Heat Pump Hybrid System for Heating, Cooling and Hot water (콤팩트형 태양열/지열히트펌프 하이브리드 냉난방 및 급탕 시스템 개발 및 성능분석)

  • Baek, Nam-Choon;Jeong, Seon-Yeong;Yoon, Eung-Sang;Lee, Kyoung-Ho
    • Journal of the Korean Solar Energy Society
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    • v.32 no.5
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    • pp.59-67
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    • 2012
  • In this study,the compact type solar thermal and ground coupled heat pump hybrid system for space heating/cooling and hot water supply has been developed. This hybrid system was installed in Zero Energy Solar House(ZeSH) in KIER for the demonstration. The thermal performance and operational characteristics of this hybrid system were analysed especially. The results are as follows. (1) This hybrid system was designed in order to address the existing disadvantages of solar thermal/ground coupled heat pump system. For this design, all parts except solar collector and ground coupled heat pump were integrated into a single product in a factory. The compact type unit includes two buffer tanks, an expansion tank, pumps, valves, a controller, etc. This system has an advantage of easy installation with simple plumbing work even in narrow space. (2) The thermal charging and discharging time of the buffer tanks and its characteristics by ground coupled heat pump, and heat pump COP according to geo-source temperature and buffer storage temperature have been studied. This system was found to meet well to the heat load without any other auxiliary heating equipment. (3) The operating hours of the ground coupled heat pump as a backup device of solar thermal can be reduced significantly by using solar heat. It was also found that the minimum heating water supply setting temperature and maximum cooling water supply setting temperature make an influence on the heat pump COP. The lower heating water and the higher cooling water temperature, the higher COP. In this respect, the hybrid system's performance can be improved in ZeSH than conventional house.

The Development of the Solar Tracking System with High Accuracy by using LabVIEW (LabVIEW를 활용한 고정밀도 태양추적장치 개발)

  • Oh, Seung-Jin;Cho, Yil-Sik;Lee, Yoon-Joon;Chun, Won-Gee
    • 한국태양에너지학회:학술대회논문집
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    • 2009.04a
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    • pp.31-36
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    • 2009
  • There have been many solar tracking systems developed for the high accuracy in solar tracking. One of the key components of any motion control system is software. LabVIEW offers an ideal combination of flexibility, ease-of-use and well-integration with other I/O pieces for developing solar tracking system. Real-time solar positions which vary with GPS's data are used simultaneously to control the solar tracker by a chain of operating modes between the open and closed loops. This paper introduces a step by step procedure for the fabrication and performance assessment of a precision solar tracking system. The system developed in this study consists of motion controllers, motor drives, step-motors, feedback devices and application. CRD sensors are applied for the solar tracking system which play a primary role in poor conditions for tracking due to a gear backlash and a strong wind. Mini-dish was used as a concentrator for collecting sun light. The solar position data, in terms of azimuth and elevation, sunrise and sunset times was compared with those of KASI(Korea Astronomy & Space Science Institute). The results presented in this paper demonstrate the accuracy of the present system in solar tracking and utilization.

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A Sensitivity Analysis about Solar Heat Gain and Heating Load of ZeSH According to Optical Characteristics of Window system (창호의 광학적 특성에 따른 ZeSH의 일사취득 및 난방부하에 관한 민감도 분석)

  • Son, Sun-Woo;Baek, Nam-Choon;Suh, Seung-Jik
    • 한국태양에너지학회:학술대회논문집
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    • 2009.04a
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    • pp.66-71
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    • 2009
  • To reduce the building energy consumption, the major advanced nations are conducting actively many researches on so called a "self-sufficient building(or other words zero energy building)" which can support its required energy by itself. Given this background, KIER(Korea Institute of Energy Research) built full size test-bed of the zero energy solar house in early 2002, and has studied on the self-sufficient heating load up to now. We analyse the sensitivity between the heating load and the solar radiation gain according to the change the effective transmittance of windows. The authors classified 9 cases by solar transmittance of glass. The results demonstrate the solar radiation amount is 0.466 MWh from the eastern zone of Fl.,1(the first floor), 0.332 MWh from Fl.,2(the second floor), 1.194 MWh form the southern zone of F1., and 0.822 MWh from the southern zone of Fl.,2 on the case 1(each cases are classified by window types). On the case 9, the solar radiation amount is 3.127 MWh, 2.662 MWh, 8.799 MWh and 6.078 MWh from the same condition. For the Fl.,1, the amount of Heat Load that is saved per year ranged 10.5 to 48 %, and the reduction was anywhere from 0.2 to 17.9% for Fl.,2

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Study of Stirling Engine Receiver for Solar Thermal Power (태양열 발전용 스터링엔진 흡수기 특성연구)

  • Kim, Jong-Kyu;Lee, Sang-Nam;Kang, Yong-Heack
    • 한국태양에너지학회:학술대회논문집
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    • 2008.04a
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    • pp.227-232
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    • 2008
  • Stirling engine for solar thermal power is an essential part of Dish-Stirling system which generates electricity by using direct normal irradiation and will go into commercialization in near future. For the Stirling engine used in this study is Solo 161 model the capacity of which is 10 kWe and was already used for the Dish-Stirling system of KIER in Jinhae. The receiver of Stirling engine absorbes concentrated solar radiation and transfer it to working fluid of Hydrogen. The working condition of striling engine is high temperature and high pressure to make high efficiency. Therefore the receiver should stand against high temperature of above 800 $^{\circ}C$ and high pressure of max. 150 bar with good performance of heat transfer. The receiver is composed of 78 Inconel tubes of 1/8" with thickness of 0.71 mm and two reserviors which is connected with two cylinders. In order to know the charaterristics of heat transfer of Stirling engine receiver, simulation on the heat transfer of the receiver of Solo 161 is conducted by using CFD code of Fluent. The heat flux on the receiver surface has a shape of Gaussian distribution so, it is necessary to simulate a whole receiver. However, It is difficult and time consuming to simulate the whole receiver that one tube with different heat flux conditions are considered in this study. From the simulation results, heat transfer charateristics of receiver are observed and tube wall and fluid temperature and heat transfer coefficient are obtained and compared with the calculated results from Dittus-Boelter's correlation.

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Luminescence Characteristics and Crystal Structure of CaWO4-Li2WO4-Eu2O3 Phosphors (CaWO4-Li2WO4-Eu2O3계 형광체의 PL 특성과 결정구조)

  • Kim, Jeong-Seog;Choi, Jin-Ho;Jeong, Bong-Man;Kang, Hyun-Ju
    • Journal of the Korean Ceramic Society
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    • v.43 no.1 s.284
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    • pp.10-15
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    • 2006
  • Photoluminescence (PL) and crystal structures of the $(l-x)CaWO_4-xLi_2WO_4$ binary system added with $Eu_2O_3$ activator have been characterized. The $CaWO_4\;and\;Li_2WO_4$ have the scheelite and phenakite structures respectively. The $CaWO_4-Li_2WO_4-Eu_2O_3$ phosphors show the red luminescence of 613 nm peak wavelength. The wavelength range of excitation spectral band is $380\~470$ nm with the peak wavelength of 397 nm. The $0.88(0.5CaWO_4-0.5Li_2WO_4)-0.12Eu_2O_3$ showed the most superior luminescence characteristics. The effect of co-doping elements such as $Al_2O_3$ and rare-earth oxides on PL has been characterized. The co-doping elements deteriorated the luminescence intensity except the $Al_2O_3$ and $Gd_2O_3$. The PL characteristics of $CaWO_4-Li_2WO_4-Eu_2O_3$ phosphors have been compared to those of the alkali europium double molybdates (tungstates) of scheelite-related structure such as $LiEu(MoO_4)_2$ and $CsEu(MoO_4)_2$. The crystal structures of $(l-y)[(l-x)CaWO_4-xLi_2WO_4]-yEu_2O_3$ phosphors have been characterized using XRD data and rietveld refinement.

Particle Stabilized Wet Foam to Prepare SiO2-SiC Porous Ceramics by Colloidal Processing

  • Bhaskar, Subhasree;Park, Jung Gyu;Han, In Sub;Lee, Mi Jai;Lim, Tae Young;Kim, Ik Jin
    • Journal of the Korean Ceramic Society
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    • v.52 no.6
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    • pp.455-461
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    • 2015
  • Porous ceramics with tailored pore size and shape are promising materials for the realization of a number of functional and structural properties. A novel method has been reported for the investigation of the role of SiC in the formation of $SiO_2$ foams by colloidal wet processing. Within a suitable pH range of 9.9 ~ 10.5 $SiO_2$, particles were partially hydrophobized using hexylamine as an amphiphile. Different mole ratios of the SiC solution were added to the surface modified $SiO_2$ suspension. The contact angle was found to be around $73^{\circ}$, with an adsorption free energy $6.8{\times}10^{-12}J$. The Laplace pressure of about 1.25 ~ 1.6 mPa was found to correspond to a wet foam stability of about 80 ~ 85%. The mechanical and thermal properties were analyzed for the sintered ceramics, with the highest compressive load observed at the mole ratio of 1:1.75. Hertzian indentations are used to evaluate the damage behavior under constrained loading conditions of $SiO_2$-SiC porous ceramics.

A case study for installing of Energy Metering Systems in an Office Building (사무소 건물의 에너지 미터링 시스템 구축에 관한 사례연구)

  • Han, Hye-Sim;Lee, Na-Eun;Lee, Jin-Sook;Jeong, Hak-Geun;Jang, Cheol-Yong
    • KIEAE Journal
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    • v.13 no.5
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    • pp.51-57
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    • 2013
  • Energy saving starts by knowing how much energy is being consumed. A building factor is easier than any other things in energy saving. Since, especially, it is closely connected with user's space-use-patterns and manager's utility-operation-style. An energy metering system lets building users know about energy consumption pattern in buildings and measure energy in real time. Development and materialization of metering systems need more careful plans, so that they depend on a demand of individual facilities and available infrastructures they used to use. But, so far, there is no guidelines how to install metering systems. This paper suggested how to install meters and researched a method for how to analyze by using metered data. For that, Green Building in KIER is used as a test bed. As the results, nevertheless the smallest number of meters is basically one for the whole building energy measuring, it is too limited in analysis. So we needed to add the sort of fuel and utility types and found that it depends on all cases. For this reasons, a guideline should be created in order to install meters as soon as possible. It would be suggest a way to save more energy in building factor.