• Journal of the Korean Electrochemical Society
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• v.11 no.1
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• pp.16-21
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• 2008

The key component of a direct methanol fuel cell (DMFC) is the membrane electrode assembly (MEA), which comprises a polymer electrolyte membrane and catalyst layers (anode and cathode electrode). Generally the catalyst layer is coated on the porous electrode supporter (e.g. carbon paper or cloth) using various coating methods such as brushing, decal transfer, spray coating and screen printing methods. However, these methods were disadvantageous in terms of the uniformity of catalyst layer thickness, catalyst loss, and coating time. In this work, we used bar-coating method which can prepare the catalyst layer with uniform thickness for MEA of DMFC. The surface and cross-section morphologies of the catalyst layers were observed by SEM. The performances and resistance of the MEAs were investigated through a single cell evaluation and impedance analyzer.

• Proceedings of the SAREK Conference
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• 2008.06a
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• pp.1273-1278
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• 2008

A sea water source cascade heat pump was designed and tested in this study. The system was designed to perform a single stage operation in summer, as well as a cascade operation in winter to ensure the high temperature lift. A steady-state simulation model was developed to analyze and optimize its performance. The simulation results show that the R717 exhibits best performance among combinations considered in this study. A R410A also exhibits the highest performance among HFCs with the smallest compressor displacement. A 15-RT R410A-R134a pilot system was installed in the 5-story commercial building at Samcheok City by the East Sea. A scroll type R410A compressor, a reciprocating type R134a compressor, plate type condenser/ evaporator/ cascade heat exchanger and two electronic expansion valves were used to build a pilot. A titanium plate type heat exchanger is also used for the heat exchanging with a sea water. The heat source/sink water is supplied from the well below the seashore in the depth of 5 m. In the initial test of the system, supply water temperature was rising up to $67^{\circ}C$ using a sea water heat source of $9^{\circ}C$, while an ambient temperature was $4.5^{\circ}C$.

• Korean Chemical Engineering Research
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• v.49 no.6
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• pp.769-774
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• 2011

Porous carbon nanofibers(CNF) were synthesized via NaOH activation at 700~$900^{\circ}C$, and the porous CNF-supported PtRu catalysts were evaluated for the anode in direct methanol fuel cells. The change of surface characteristics by NaOH activation was examined by analyses of the specific surface area and pore size distribution. The morphological and structural modification was investigated under scanning electron microscopy. The activity of catalysts supported on porous CNFs was examined by cyclic voltammograms and single cell tests. The pore formation on CNF by the NaOH activation was discussed, concerning the catalyst activity, when they were applied as catalyst supports.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.29 no.5
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• pp.239-248
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• 2017

At the $21^{st}$ Conference of the Parties (COP) of the United Nations Climate change Conference, representatives of the 195 member countries reached an agreement requiring all participating countries, including Korea, to establish proactive measures to fight climate change. Under this vision, energy network technologies are deemed as a key site of research towards meeting this goal. Herein, the headquarters of the Korea Institute of Energy Research (KIER) is a worthy site for carrying out energy network technology research insofar as it contains various heat sources. To prepare for this research, a study was conducted analyzing the heat sources at KIER based on measured data. The study also consisted of developeding simulation models to predict the amount of energy savings that could be derived by replacing an absorption chiller/heater with an absorption heat pump during winter seasons. In our simulation results, we observed a primary energy saving ratio of 65~72% based on the water temperature from the heat source of a coal power plant.

• Korean Chemical Engineering Research
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• v.59 no.1
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• pp.127-137
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• 2021

Air emission charge for nitrogen oxide as a precursor of fine dust has been introduced and implemented within the country from 2020. Therefore, the development of economical combustion technology for NOx reduction has got more needed urgently. This study investigated the air-staging effect as a way to reduce the NOx during combustion of domestic unused forest biomass, recently possible to secure REC (Renewable Energy Certification) as a substitute for overseas wood pellets in a 0.1 MWth circulating fluidized bed combustion test-rig. Operating conditions were comparison with and without air-staging, the supply position of tertiary air (6.4 m, 8.1 m, 9.4 m in the combustor) and variation of air-staging ratio (Primary air:Secondary air:Tertiary air=91%:9%:0%, 82%:9%:9%, 73%:9%:18%). NO and CO concentrations in flue gas, profiles of temperature and pressure at the height of the combustion, unburned carbon in sampled fly ash and combustion efficiency on operating conditions were evaluated. As notable results, NO concentration with air-staging application under tertiary air supply at 9.4 m in the combustor reduced 100.7 ppm compared to 148.8 ppm without air-staging while, CO concentration increased from 52.2 ppm without air-staging to 99.8 ppm with air-staging. However, among air-staging runs, when tertiary air supply amount at 6.4 m in the combustor increased by air-staging ratio (Primary air:Secondary air:Tertiary air=73%:9%:18%), NO and CO concentrations decreased the lowest 90.8 ppm and 66.1 ppm, respectively. Furthermore, combustion efficiency at this condition was improved to 99.3%, higher than that (98.3%) of run without air-staging.

• 한국신재생에너지학회:학술대회논문집
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• 2007.11a
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• pp.234-234
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• 2007

• Proceedings of the SAREK Conference
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• 2005.06a
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• pp.194-194
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• 2005

• Proceedings of the SAREK Conference
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• 2005.06a
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• pp.197-197
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• 2005

• Proceedings of the SAREK Conference
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• 2004.06a
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• pp.232-232
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• 2004

• Korean Chemical Engineering Research
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• v.57 no.3
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• pp.400-407
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• 2019

Oxy-combustion with a circulating fluidized bed (Oxy-CFBC) technology has been paid attention to cope with the climate change and fuel supply problem. In addition, Oxy-CFBC technology as one of the methods for carbon dioxide capture is an eco-friendly that can reduce air pollutants, such as $SO_2$, NO and CO through a flue gas recirculation process. The newly developed $100kW_{th}$ pilot-scale Oxy-CFBC system used for this research has been continuously utilizing to investigate oxy-combustion characteristics for various fuels, coals and biomasses to verify the possibility of fuel diversification. The anthracite is known as a low reactivity fuel due to a lot of fixed carbon and ash. Therefore, this study aims not only to improve combustion efficiency of an anthracite, but also to capture carbon dioxide. As a result, compared to air-combustion of sub-bituminous coal, oxy-combustion of anthracite could improve 2% combustion efficiency and emissions of $SO_2$, CO and NO were reduced 15%, 60% and 99%, respectively. In addition, stable operating of Oxy-CFBC could capture above 94 vol.% $CO_2$.