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Synthesis and Characterization of Fluorinated Polybenzimidazole Proton Exchange Membranes for Fuel Cell (연료전지용 불소화 폴리벤즈이미다졸 양성자 교환 멤브레인 합성 및 특성평가)

  • KIM, AE RHAN
    • Transactions of the Korean hydrogen and new energy society
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    • v.28 no.1
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    • pp.24-29
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    • 2017
  • A fluorinated polybenzimidazole (FPBI) was synthesized from 3,3-diaminobenzidine (DAB) of tetraamine, 2,2-bis(4-carboxyphenyl)hexafluoropropane of aromatic biscarboxylic acid, and 4,4-sulfonyldibenzoic acid of aromatic biscarboxylic acid in polyphosphoric acid (PPA). A FPBI was easily cast and made into clear films. The structure of condensation polymers and corresponding membranes were analyzed using GPC (gel permeation chromatography), $^1H$-NMR ($^1H$ nuclear magnetic resonance) and FT-IR (fourier transform infrared). TGA (thermogravimetric analysis) analysis showed that the prepared membranes were thermally stable, so that elevated temperature fuel cell operation would be possible. The proton conductivity of the FPBI membranes increased with increasing temperatures in the polymer. A FPBI membrane has a maximum ion conductivity of 45 mS/cm at $90^{\circ}C$ and 100% relative humidity.

An Economic Analysis of the Hydrogen Station Enterprise Considering Dynamic Utilization (동적 이용률을 고려한 수소충전소 사업의 경제성 분석)

  • GIM, BONGJIN
    • Transactions of the Korean hydrogen and new energy society
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    • v.28 no.1
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    • pp.47-55
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    • 2017
  • This paper deals with the after-tax economic feasibility analysis of the hydrogen fueling station considering dynamic utilization. We selected an off-site hydrogen station in which the hydrogen is supplied by a central by-product hydrogen plant as a case study. Also, we made some sensitivity analysis by changing input factors such as the discount rate, the hydrogen station construction cost, the hydrogen demand and the hydrogen sale price. As a result, the hydrogen station will not be economical in 2020 due to the relatively high price of the hydrogen station construction cost and the low price of hydrogen sale price. In order to realize the economic feasibility of the hydrogen station in the early stage of the hydrogen economy, the subsidies on the annual operating cost as well as the construction cost are needed.

Electrochemical Enhancement of Carbon Felt Electrode for Vanadium Redox Flow Battery with Grephene Oxide (산화그레핀을 이용한 바나듐레독스흐름전지용 카본펠트전극의 표면개질을 통한 전기화학적 활성개선)

  • LEE, KEON JOO;KIM, SUNHOE
    • Transactions of the Korean hydrogen and new energy society
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    • v.28 no.2
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    • pp.206-211
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    • 2017
  • Carbon felt electrode for the vanadium redox-flow battery (VRFB) has been studied to see the effect of grephene oxide (GO) treatment on the surface of the carbon felt electrode. In this paper, surface of carbon felt electrodes were treated with various concentrations of grephene oxide. Electrochemical analysis, cyclic voltammetry (CV), was performed to investigate redox characteristics as electrode for VRFB. Also the effect of GO on the introduction of functional group on the surface of carbon felt electrodes were investigated using X-ray photoelectron spectroscopy (XPS), which discovered increase in the overall functional group content on the surface of carbon felts.

A Study on the Performance Characteristics According to the Compression Ratio of Spark Ignition Engine Fuelled with Coal Oil (Coal Oil을 사용한 스파크 점화기관의 압축비 변화에 따른 엔진 성능에 관한 연구)

  • HAN, SUNG BIN;CHUNG, YON JONG
    • Transactions of the Korean hydrogen and new energy society
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    • v.28 no.2
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    • pp.225-230
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    • 2017
  • Coal oil is widely used as a home heating fuel for portable and installed coal oil heaters. Today, Coal oil is widely used as fuel for jet engines and some rocket engines in several grades. This paper describes the performance characteristics according to the compression ratio of spark ignition engine fuelled with coal oil. As a result, the following knowledge is obtained: As the compression ratio is decreased, there is an increase in torque, indicated mean effective pressure (IMEP), heat release rate, and brake thermal efficiency. Higher compression ratio of the engine decreases the ignition delay period, combustion period, and cooling loss.

Numerical Study on Heat Transfer of Air-cooling PEMFC in HALE UAV (고고도 무인기 내부의 공랭식 PEMFC 열전달 전산 해석 연구)

  • SONG, MYEONGHO;KIM, KYOUNGYOUN
    • Transactions of the Korean hydrogen and new energy society
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    • v.28 no.2
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    • pp.150-155
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    • 2017
  • Proper cooling of PEM fuel cell stack is essential for the high-performance operation of fuel cell system. Insufficient cooling of the stack can cause significant damage to components due to overheating and also can decrease cell performance by dehydration of the polymer electrolyte. In the present study, we performed a computational analysis to assess the condition of the cooling system to secure the proper temperature in fuel cell stack system for high altitude long endurance (HALE) unmanned aerial vehicle (UAV).

Performance Degradation of Mea with Cation Contamination in Polymer Electrolyte Membrane Water Electrolysis (고분자 전해질막 수전해 막전극접합체의 양이온 오염에 따른 성능 저하)

  • JUNG, HYEYOUNG;CHOI, NAKHEON;IM, SUHYUN;YOON, DAEJIN;MOON, SANGBONG
    • Transactions of the Korean hydrogen and new energy society
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    • v.28 no.4
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    • pp.331-337
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    • 2017
  • Proton Exchange Membrane Water Electrolysis (PEMWE) is one of the most popular and widely used methods for hydrogen production. PEMWE contributes to eco-friendly system via its energy storage system application, hence making it environmentally friendly to use. However, its main drawback is contamination of proton exchange membrane during water electrolysis. Existing cation such as magnesium, calcium and the likes are the cause for membrane contamination. As a result, the cation contamination give rise to degradation of performance of electrolysis and the reverse electrolysis is effective method to remove cation.

A Study on Behavior of Steel Surface Oxidation with Characteristics of the Combustion (연소 특성에 따른 강판 표면 산화거동에 관한 연구)

  • KIM, SEULGI;KANG, KIJOONG;LEE, KEEMAN
    • Transactions of the Korean hydrogen and new energy society
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    • v.28 no.4
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    • pp.392-400
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    • 2017
  • An experimental study was conducted to investigate behavior of steel surface oxidation with characteristics of the combustion. The excess entalphy combustion in porous media system was applied to implement the direct radiation heating system. The surface oxidation thickness (SOT) of fuel-lean was thicker than the SOT of fuel-rich. Also, the SOT was increased by increasing residence time. Detailed explanations were given by SEM and EDS analysis.

Hydrogen Evolution Properties of Alanate-based Hydrogen Storage Materials (알라네이트 계 수소 저장 물질의 수소 방출 특성)

  • JEONG, HEONDO
    • Transactions of the Korean hydrogen and new energy society
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    • v.28 no.4
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    • pp.361-368
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    • 2017
  • Alanate-based materials, which were known to have high hydrogen storage capacity, were synthesized by mechanochemically metathesis reaction of metal chloride and sodium alanate without solvent. XRD patterns of synthesized materials showed that metathesis reaction of cations between metal chloride and sodium alanate was progressed favorably without any solvent. Magnesium alanate showed that 3.2 wt.% of hydrogen was evolved by the thermal decomposition. The addition of a small amount of Ti to the magnesium alanate greatly reduced hydrogen evolution temperature. Also, Ti doped magnesium alanate had a good regeneration property. Both the calcium and lithium-magnesium alanate showed the lower starting temperature of the two step hydrogen evolution and fast kinetics for the hydrogen evolution.

Thermodynamic Performance Analysis of Ammonia-Water Rankine Cycle and Organic Rankine Cycle Using Cold Energy of LNG (LNG 냉열을 이용하는 암모니아-물 랭킨 사이클과 유기 랭킨 사이클의 열역학적 성능 특성 해석)

  • KIM, KYOUNG HOON
    • Transactions of the Korean hydrogen and new energy society
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    • v.31 no.4
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    • pp.363-371
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    • 2020
  • Recently, the technologies to utilize the cold energy of liquefied natural gas (LNG) have attracted significant attention. In this paper, thermodynamic performance analysis of combined cycles consisting of ammonia Rankine cycle (AWR) and organic Rankine cycle (ORC) with LNG Rankine cycle to recover low-grade heat source and the cold energy of LNG. The mathematical models are developed and the effects of the important system parameters such as turbine inlet pressure, ammonia mass fraction, working fluid on the system performance are systematically investigated. The results show that the thermal efficiency of AWR-LNG cycle is higher but the total power production of ORC-LNG cycle is higher.

Governance Leadership for Hydrogen Economy Revitalization (수소경제 활성화를 위한 거버넌스 리더십)

  • YIM, DONG WOOK
    • Transactions of the Korean hydrogen and new energy society
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    • v.31 no.3
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    • pp.265-275
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    • 2020
  • The hydrogen economy is still a niche market and a new system. If we believe in the optimism and the hope of human history of technological progress, the hydrogen economy will be a new paradigm to replace the carbon economy. The research question is what kind of leadership the government should show in order to revitalize the hydrogen economy. In response to the research question, this study highlights the governance leadership. The new economy must be newly recognized before they can find a solution. This research can be the first step in finding the way.