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NPS Pollution Loads from Coal Mining in Korea (석탄광산 작업장의 비점오염부하 유출특성)

  • Shin, Min-Hwan;Choi, Young-Hoon;Kim, Ki-Chul;Seo, Ji-Yeon;Lim, Kyoung-Jae;Choi, Joong-Dae
    • Proceedings of the Korea Water Resources Association Conference
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    • 2008.05a
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    • pp.779-784
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    • 2008
  • 환경부에서 추진하고 있는 토지피복 중분류별 비점오염부하원단위를 산정하기 위한 사업 중 나지로 분류되는 채광지역의 비점오염부하를 측정하였다. 비점오염부하는 강원도 삼척시 도계읍의 도계 작업장(석탄)과 태백시 장성동의 태백 저탄소 등 2곳의 채광지역에서 2007년 9월부터 12월까지 2회의 강우유출사상을 대상으로 측정하였다. 2회 강우사상 동안 총강수량은 도계 작업장에서 149 mm이었으며 태백 저탄소에서 201 mm이었다. 유출량은 수위계와 유량계로 5분 단위로 측정하였으며, 수질시료는 자동채수기로 2시간 간격으로 채취하였다. 수질시료는 환경부의 공정시험법에 따라 SS, BOD, CODcr, T-N, T-P, 그리고 TOC 농도를 분석하였다. 그리고 일부의 시료에 대해서는 Zn, Cb, Cu, 그리고 Pb의 농도를 분석하였다. 도계 작업장의 유량가중평균농도는 갱내수의 수질에 많은 영향을 받는 것으로 나타났다. 도계작업장의 일평균유량가중평균농도는 SS $86.3{\sim}94.9\;mg/{\ell}$, BOD $3.8{\sim}7.6\;mg/{\ell}$, COD $26.9{\sim}51.6\;mg/{\ell}$, T-N $1.5{\sim}2.1\;mg/{\ell}$, T-P $0.2\;mg/{\ell}$ 그리고 TOC $1.8{\sim}2.3\;mg/{\ell}$로 나타났다. 태백 저탄소의 일평균유량가중평균농도는 SS $16.5{\sim}66.6\;mg/{\ell}$, BOD $7.4{\sim}9.8\;mg/{\ell}$, COD $41.1{\sim}66.7\;mg/{\ell}$, T-N $0.7{\sim}1.1\;mg/{\ell}$, T-P $0.2\;mg/{\ell}$ 그리고 TOC $1.7{\sim}2.6\;mg/{\ell}$로 나타났다. 중금속의 농도는 모든 시료에서 환경부의 배출허용기준농도보다 낮게 나타나거나 검출되지 않았다. 도계 작업장의 일오염부하는 SS $1,368.8{\sim}1,984.1\;kg/day$, BOD $56.6{\sim}128.9\;kg/day$, COD $385.7{\sim}933.7\;kg/day$, T-N $23.4{\sim}44.5\;kg/day$, T-P $2.1{\sim}4.8\;kg/day$ 그리고 TOC $24.3{\sim}39.3\;kg/day$이었다. 태백 저탄소의 일오염부하는 SS $8.2{\sim}162.1\;kg/day$, BOD $2.6{\sim}15.3\;kg/day$, COD $13.8{\sim}83.6\;kg/day$, T-N $0.2{\sim}3.1\;kg/day$, T-P $0.1{\sim}0.6\;kg/day$ 그리고 TOC $0.7{\sim}4.4\;kg/day$로 나타났다. 본 연구는 2회의 강우유출사상에 대하여 측정한 자료이므로 연평균농도나 연평균오염부하로 활용하기는 어렵다. 그러나 석탄광산지역의 비점오염부하를 이해하는데 활용할 수 있으며 또한 장기적인 연구자료로 활용하여 석탄광산지역의 비점오염원단위의 산정에 유용한 자료로 활용할 수 있다.

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Contents of Heavy Metals in Soybean Curd and Starch Jelly Consumed in Korea (국내 유통 두부류 및 묵류 중 중금속 함량)

  • Kim, Mee-Hye;Lee, Yun-Dong;Park, Hyo-Jung;Park, Sung-Kug;Lee, Jong-Ok
    • Korean Journal of Food Science and Technology
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    • v.37 no.1
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    • pp.1-5
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    • 2005
  • Contents of heavy metals [mercury (Hg), lead (Pb), cadmium (Cd), and arsenic (As)] in 218 samples including soybean curds (n = 138), processed bean curds (n = 37), starch jellies (n = 33), and mixed starch jellies (n = 10) were determined using mercury analyzer, atomic absorption spectrophotometer (AAS) or inductively coupled plasma spectrometer (ICP). Ranges and means of heavy metals in soybean curds and starch jellies were as follows [min-max (mean) values]: soybean curds -Hg $0.1-8.2(0.3)$, Pb not detectable (ND)-203.9(23.3),\ Cd ND-46.0 (8.1), and As ND-61.3 (0.7)${\mu}g/kg$, starch jellies-Hg 0.1-1.3(0.3)${\mu}g/kg$, Pb ND-90.2(22.4)${\mu}g/kg$, Cd ND-31.0(3.7) and As ND-23.6(1.1)${\mu}g/kg$. Daily intakes of Hg, Pb, and Cd from soybean curds and starch jellies were 0.001-0.3% of Provisional tolerable weekly intake established by FAO/WHO.

Evaluating Soil Respiration as Indicator of Heavy Metal Pollution in Agricultural Field

  • Choi, Won-Suk;Hong, Young-Kyu;Min, Kyung-Jun;Kim, Kwang-Jin;Kim, Sung-Chul
    • Korean Journal of Soil Science and Fertilizer
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    • v.50 no.5
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    • pp.472-481
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    • 2017
  • Agricultural field near at the abandoned metal mine and industrial area has a high possibility to be polluted by heavy metals. However, concern about chemical properties including heavy metal concentration has been increased and biological properties such as soil respiration has been minimal in heavy metal polluted field. Therefore, main objective of this research was to evaluate soil respiration as an indicator of heavy metal pollution in agricultural field. Total of 60 sampling sites including each 30 sites of abandoned metal mine and industrial area were selected and heavy metal concentration, soil respiration, and chemical properties were measured. Results showed that heavy metal concentration in metal mine area was ranged Cu: $6.21~85.23mg\;kg^{-1}$, Pb: $23.84{\sim}1,044.72mg\;kg^{-1}$, As: $1.88{\sim}691.44mg\;kg^{-1}$, Zn: $18.72{\sim}527.55mg\;kg^{-1}$, Cd: $0.58{\sim}4.27mg\;kg^{-1}$, and Cu: $0.29{\sim}30.62mg\;kg^{-1}$, Pb: $4.41{\sim}19.77mg\;kg^{-1}$, As: $2.23{\sim}11.76mg\;kg^{-1}$, Zn $39.98{\sim}109.59mg\;kg^{-1}$, Cd $0.29{\sim}0.57mg\;kg^{-1}$ for industrial area respectively. While no sampling site was exceed the threshold value of each heavy metals in industrial field, metal mine area was highly polluted with Pb, As, Zn, and Cd. Soil respiration in the metal mine and industrial area was ranged $12.05{\sim}299.80mg\;O_2\;kg^{-1}$ and $27.68{\sim}330.94mg\;O_2\;kg^{-1}$, respectively. Correlation analysis between heavy metal concentration in soil and soil respiration showed that negative correlation was observed in metal mine area while no correlation was observed in industrial area. This result might indicate that as heavy metal concentration was increased, microbial activity in soil was decreased resulting decrease of soil respiration rate. Overall, soil respiration can be used as indicator of heavy metal pollution in soil and more biological properties need to be evaluated to better understand heavy metal pollution in soil.

The effect of continuous application of the food waste composts on the paddy field environment (음식물류폐기물 활용 퇴비의 장기시용이 논 농업환경에 미치는 영향)

  • Kwon, Soon-Ik;So, Kyu-Ho;Hong, Seung-Gil;Kim, Gun-Yeob;Lee, Jeong-Taek;Seong, Ki-Seog;Kim, Kwon-Rae;Lee, Deog-Bae;Jung, Kwang-Yong
    • Journal of the Korea Organic Resources Recycling Association
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    • v.17 no.3
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    • pp.55-70
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    • 2009
  • The long-term effects and the soil environmental changes were examined to ensure the safety of food waste compost in agricultural use. Based on conventional nitrogen application rate of chemical fertilizer, Pig manure compost with $24g\;N\;kg^{-1}$, $8g\;P_2O_5\;kg^{-1}$, and $10.4g\;K_2O\;kg^{-1}$ and food waste compost with $20g\;N\;kg^{-1}$, $20.1g\;P_2O_5\;kg^{-1}$, and $6.5g\;K_2O\;kg^{-1}$ were applied to the paddy soil in $2{\times}2{\times}2m$ lysimeter in which paddy rice (Oryza sativa L. var Chucheong) were grown. The rice grown where food waste compost applied showed better growth responses than control, whereas less yield rate than chemical fertilizer applied. The contents of organic matter, nitrogen, and phosphorus after experiment were increased with compost applied. In addition, it improved soil aeration by the application of food waste compost, while little difference was observed in the quality of surface, infiltrated, and ground water compared to chemical fertilizer applied or control.

Fermentable Sugar Contents of Commercial Medical Foods and Carbohydrate Ingredients (상업용 메디컬푸드 및 탄수화물 급원의 발효성 당류 함량에 관한 연구)

  • Shin, Hee-Chang;Kang, Nam-Hee;Lee, Jang-Woon;Lee, Yoon-Bok;Lee, Kyun-Hee;Oh, Seung-Hyun
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.44 no.8
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    • pp.1200-1205
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    • 2015
  • Medical foods are enteral nutrition for patients, but they cause maladaptation symptoms like diarrhea. Although the cause of diarrhea remains unknown, some studies have indicated that the cause of diarrhea is fermentable oligosaccharides, disaccharides, monosaccharides, and polyols (FODMAP). This is a consideration for medical foods since they are easily fermented by intestinal bacterial. In this study, we estimated the FODMAP contents of commercial medical foods and carbohydrate ingredients. We measured the concentrations of FODMAP in 13 types of different medical foods and five types of carbohydrate ingredients by using high performance liquid chromatography with an evaporative light scattering detector (HPLC-ELSD). The limits of detection of FODMAP were fructose, 0.002; lactose, 0.010; raffinose, 0.003; stachyose, 0.032; 1-kestose, 0.005; nystose, 0.012; and 1-fructofuranosylnystose, 0.003 mg/kg. Limits of quantitation of FODMAP were fructose, 0.008; lactose, 0.033; raffinose, 0.009; stachyose, 0.107; 1-kestose, 0.015; nystose, 0.042; and 1-fructofuranosylnystose, 0.011 mg/kg, respectively. Concentration of FODMAP ranged from 0.428~2.968 g/200 mL. Concentrations of carbohydrate ingredients in FODMAP were chicory fiber, 278.423; soy fiber, 27.467; indigestible maltodextrin, 52.384; maltodextrin (DE10~15), 32.973; and maltodextrin (DE15~20), 50.043 g/kg. Contents of carbohydrates were 19.0~41.0 g/200 mL in commercial medical foods. We expected a correlation between contents of carbohydrates and FODMAP, as carbohydrates included FODMAP. However, we detected a low correlation (r=0.55). Since most commercial medical foods have a similar carbohydrate ingredients and nutritional values, the difference between products was determined by FODMAP contents of carbohydrate ingredients. In this study, we analyzed FODMAP contents of commercial medical foods and carbohydrate ingredients. These results are expected to be utilized as basic data for product development and minimizing maladaptation of medical foods.

Decentralized Composting of Garbage in a Small Composter for Dwelling House I. Laboratory Composting of the Household Garbage in a Small Bin (가정용 소형 퇴비화용기에 의한 부엌쓰레기의 분산식 퇴비화 I. 실험실 조건에서 퇴비화 연구)

  • Seo, Jeoung-Yoon;Joo, Woo-Hong
    • Korean Journal of Environmental Agriculture
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    • v.13 no.3
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    • pp.321-337
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    • 1994
  • The garbage from the dwelling houses was composted in two kinds of small composter in laboratory to investigate the possibility of garbage composting. They were general small composters. One (type 1) was insullated but the other (type 2) was not. Because it was found that type 2 was not available for composting under our meteorological conditions through winter experiment, only type 1 was tested in spring and summer. The experiment was performed for 8 weeks in each season. The seasonal variation of several compounds in compost was evaluated and discussed. The result summarized belows are those taken at the end of the experiment, if the time was not specified. 1) The maximum temperature was $58^{\circ}C$ in spring, $57^{\circ}C$ in summer and $41^{\circ}C$ in winter. This temperature was enough to destroy the pathogen except for winter. 2) The mass was reduced to average 62.5% and the volume reduction was avergae 74%. 3) The density was estimated as 0.7kg/l in spring, 0.8kg/l in summer and 1.1kg/l in winter. 4) The water content was not much changed for composting periods. It had 75.6% in spring and 76.6% in summer and winter. 5) There was a great seasonal difference in pH value. It was reached to pH 6.13 in spring, pH 8.62 in summer and pH 4.75 in winter. 6) The faster organic matter was decomposed, the greater ash content was increased. Cellulose and lignin content were increased, but hemicellulose content was reduced during composting period. 7) Nitrogen contents were in the range of 3.1-5.6% and especially high in summer. After ammonium nitrogen contents were increased at the early stage of composting period, they were decreased. The maximum ammonium nitrogen content was 3,243mg/kg after 2 weeks in winter, 6,053mg/kg after 3 weeks in spring and 30,828mg/kg after 6 weeks in summer. C/N-ratios were not much changed. Nitrification occurred actively in spring and summer. 8) The contents of volatile and higher fatty acids were increased in early stage of composting and reduced after that. The maximum content of total fatty acid was 10.1% after 2 weeks in winter, 5.8% after 2 weeks in spring and 15.7% after 4 weeks in summer. 9) The contents of inorganic compounds were not accumulated as composting was proceeded. They were in the range of 0.9-4.4% $P_2O_5$, 1.6-2.9% $K_2O$, 2.4-4.6% CaO and 0.30-0.80% MgO. 10) CN and heavy metal contents did not show any tendency. They were in the range of 0.11-28.99mg/kg CN, 24-166mg/kg Zn, 5-129mg/kg Cu, 0.8-14.3mg/kg Cd, 7-42mg/kg Pb, ND-30mg/kg Cr and $ND-132.16\;{\mu}g/kg$ Hg.

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The Effects of Slurry and Urea Fertilization Levels Application on Productivity of Orchardgrass and NO$_3$-N Content of Soil (액상구비 및 요소의 시용수준이 Orchardgrass 초지의 생산성과 토양중 NO$_3$-N 함량에 미치는 영향)

  • Jeong, Ho Seok;Yuk, Wan Bang;Bang, Hyo Beom
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.13 no.4
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    • pp.278-285
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    • 1993
  • This experiment was conducted to investigate the productivity in permanent orchardgrass grassland according to the urea fertilization levels of 0, 100, 200 kg N/ha and the animal excreta fertilization levels of 0. 40, 80, 160 kg N/ha on the basis of N contents respectively and NO$_3$-N content of the soil. The results were obtained as follows; 1. The productivity of grassland was significantly increased by the increase of the excreta fertilization levels until the urea-N level fertilization of 100 kg/ha but repressed and reduced by the increase to 160 kg/ha level of the animal excreta fertilization at urea-N fertilization level of 200 kg/ha. 2. Averaged seasonal productivity of the animal excreta N was decreased in first and third cutting time and was increased in second cutting time according to the increase of urea-N fertilization. 3. The increase of urea-N and animal excreta N increased the content of crude protein but the fertilization effect of urea-N was higher than that of animal excreta N. 4. The total yield of N was continuously increased at both of the urea-N and animal excreta N but the pure yield of N was decreased according to the increase of N fertilization and showed -63.1 kg/ha at the fertilization of the urea-N of 200 kg N/ha and animal excreta N of 160 kg/ha. 5. NO$_3$-N content of the soil of orchardgrass glassland established one year previously was no difference among the N variety and fertilization levels but was increased to the order of summer, autumn and winter. The highest content of NO$_3$-N was measured in winter with the value of 34.9 ppm.

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Mineral Content and Nitrate-N of Oats, and Soil Characteristics as Affected by Different Types and N Rates of Liquid Manure (액상분뇨의 종류 및 N 시용량이 연맥의 무기물 함량, 질산태질소 및 토양특성에 미치는 영향)

  • Shin, D.E.;Kim, D.A.;Seo, S.;Lee, J.K.;Chung, E.S.;Shin, J.S.;Kim, W.H.
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.19 no.3
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    • pp.203-210
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    • 1999
  • Of all the nutrients in liquid manure, N has the greatest potential both for the environment and for increasing forage yields. This experiment was carried out to determine the effect of different types and N rates of liquid manure on mineral content and nitrate-N of oats(Avena sativa L.), soil chemical characteristics in Suweon. Seven treatments consisting of chemical fertilizer $120kg\;N\;ha^{-1}$, liquid cattle manure 120, 240 and $360kg\;N\;ha^{-1}$, liquid swine manure 120, 240 and $360kg\;N\;ha^{-1}$ were arranged in a randomized complete block design with three replications. Compared with the plot of chemical fertilizer, increasing liquid manure N rates increased mineral contents of oats. Nitrate-N contents of oats were ranged from 1,881 to $2,605mg\;kg^{-1}$ in all treatments, which was orderly ranked as chemical fertilizer>liquid cattle manure $360kg\;N\;ha^{-1}$> liquid swine manure $240kg\;N\;ha^{-1}$. Contents of exchangeable cation of the soil were appeared to be higher with increasing liquid manure N rates. Amount of total-N and inorganic-N in soil affected by increasing liquid manure N rates, and there was the highest at liquid swine manure $360kg\;N\;ha^{-1}$ among the treatments. Nitrate-N concentration in infiltration water was not remarkably variable during the experimental period. Based on the results of this experiment, it is suggested that the amount of nitrogen in soil was orderly ranked as liquid swine manure $360kg\;N\;ha^{-1}$, followed by liquid swine manure $240kg\;N\;ha^{-1}$.

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금속 폐광산 주변 토양과 식물체 내 중금속 오염

  • 서상우;임정훈;최철만;홍성철;박연규
    • Proceedings of the Korean Environmental Sciences Society Conference
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    • 2004.05a
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    • pp.255-257
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    • 2004
  • 오염 토양 개선사업이 완료된 밀양시 구운동 광산의 이.화학적 성분을 기초로 하여 비경작지의 일부 야생식물 중 축적된 중금속 함량을 분석한 결과, 토양의 각 지점별 평균 함량은 유기물 13.18g/kg, 유효인산 40.65mg/kg, 석회 5.06, 칼슘 6.85, 고토 1.94cmol/kg으로서 우리나라 밭 토양의 평균보다 낮았고 중금속 함량은 아연(Zn)이 평균 383.1mg/kg, 구리(Cu) 135.2mg/kg, 납(Pb) 105.4mg/kg로 조사되었다. 조사 지점 중 광미의 퇴적으로 인한 오염이 있는 광산 위 st. 3에서 아연(945mg/kg)과 구리(535mg/kg)의 함량이 가장 높았고 다음이 광미가 많이 잔재하고 있는 광구 앞인 st. 4였으며 이곳은 납(289.5mg/kg)의 함량이 가장 높은 지점이었다. 식물체 내의 중금속 함량은 차즈기>쑥>억새>싸리 순이었고 특히 차즈기의 경우는 다량의 중금속이 축적되어 있어 중금속 오염 지역에 대한 내성이 있는 지표종으로 추측되어 이에 대한 중금속 축적 능력 확인 실험이 필요할 것으로 판단된다.

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A Study on the Distribution Characteristics of Heavy Metal Concentrations in Environment around Abandoned Mines (폐금속광산 주변환경의 중금속 오염분포특성 연구)

  • 이강혁;정연훈;김병록;박진호;정종필;박현구;김요용
    • Journal of environmental and Sanitary engineering
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    • v.19 no.1
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    • pp.17-23
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    • 2004
  • This study was investigated the distribution characteristics of heavy metal concentrations in soils around abandoned mines in Pochon city. The abandoned mines were Youngjung, Yongsog and Pochon. The results were as follows: 1) Heavy metal mean concentrations in minewastes were detected Cr 100.119 mg/kg, Cu 189.400 mg/kg in Youngjung mine, Cr 198.440 mg/kg, As 160.480 mg/kg in Yongsog mine and Cr 84.680 mg/kg, Zn 50.280 mg/kg in Pochon mine. 2) The mean concentrations in soils which is around mines were Cu 62.351 mg/kg in Youngjung mine, and As 95.024 mg/kg, Hg 11.279 mg/kg in Yongsog mine. All materials in Pochon mine were detected low level. 3) The concentrations of heavy metal showed low or not detected in water system (groundwaters, streams and sediments).