• Title/Summary/Keyword: JISHA

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Electrochemical characterization of supercapacitors based on carbons derived from Sorona activated by ZnCl2

  • Jisha, M.R.;Christy, Maria;Kim, Ae Rhan;Nahm, Kee Suk;Yoo, Dong Jin
    • Journal of Energy Engineering
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    • v.21 no.3
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    • pp.309-314
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    • 2012
  • Carbons derived by the pyrolysis of Sorona activated by $ZnCl_2$ in the ratio of 1:20 and non-porogen Sorona carbons are used as the electrode materials in asymmetric electrochemical supercapacitors and electrochemical behavior is investigated. Scanning electron microscopy (SEM) reveals the porogen free carbons show a flake-like structure and the $ZnCl_2$-treated Sorona carbons have a loose, disjoint structure without any particular shape. Cyclic voltammetric (CV) studies show specific prolate rectangular shape and gives good capacitive properties.

Rho-dependent Transcription Termination: More Questions than Answers

  • Banerjee Sharmistha;Chalissery Jisha;Bandey Irfan;Sen Ranjan
    • Journal of Microbiology
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    • v.44 no.1
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    • pp.11-22
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    • 2006
  • Escherichia coli protein Rho is required for the factor-dependent transcription termination by an RNA polymerase and is essential for the viability of the cell. It is a homohexameric protein that recognizes and binds preferably to C-rich sites in the transcribed RNA. Once bound to RNA, it utilizes RNA-dependent ATPase activity and subsequently ATPase-dependent helicase activity to unwind RNA-DNA hybrids and release RNA from a transcribing elongation complex. Studies over the past few decades have highlighted Rho as a molecule and have revealed much of its mechanistic properties. The recently solved crystal structure could explain many of its physiological functions in terms of its structure. Despite all these efforts, many of the fundamental questions pertaining to Rho recognition sites, differential ATPase activity in response to different RNAs, translocation of Rho along the nascent transcript, interactions with elongation complex and finally unwinding and release of RNA remain obscure. In the present review we have attempted to summarize 'the knowns' and 'the unknowns' of the Rho protein revealed by the recent developments in this field. An attempt has also been made to understand the physiology of Rho in the light of its phylogeny.

Lithium Insertion Behavior of Nanoscopic Co3O4 Prepared with Avian Egg Membrane as a Template

  • Christy, Maria;Jisha, M.R;Kim, Ae-Rhan;Nahm, Kee-Suk;Yoo, Dong-Jin;Suh, E.K.;Kumari, T. Sri Devi;Kumar, T. Prem;Stephan, A. Manuel
    • Bulletin of the Korean Chemical Society
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    • v.32 no.4
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    • pp.1204-1208
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    • 2011
  • Nanoscopic $Co_3O_4$ particles were prepared using avian egg membrane as a template at $800^{\circ}C$. The prepared materials were subjected to XRD, SEM, TEM and Raman spectroscopic studies. Cyclic voltammetry study shows a single step oxidation and reduction process. Electrochemical lithium insertion behavior of the materials was examined in coin cells of the 2032 configuration. The material showed a discharge capacity 600mAh/g even after 20 cycles.

A Comparative Study on Laws and Policies of Advanced Countries to Prevent Fall Accident (건설현장 추락재해 방지를 위한 해외 선진국간의 법령비교연구)

  • Oh, June-Seok;Lee, Joo-Hyeong;Jeon, Sang-Sub;Son, Ki-Young
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2019.11a
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    • pp.199-200
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    • 2019
  • Although accidents in the domestic construction industry have been decreased gradually, deaths in the construction sites have been occupied 49.9 percent of the total industry and deaths from fall accident have been accounted for 59.7 percent of the construction industry. In order to prevent fall accident, Occupation Safety and Health Act(OSHA) was enacted for setting management standards and detailed regulations was designed by the Ministry of Employment and Labor. Although government has been pushed for companies and workers to comply the regulations, currently, many domestic construction sites have been violated. On the other hand, in safety-advanced countries such as the United States, Japan, and the EU, industrial accidents have been decreased due to continual application of adapted safety policies according to characteristic in each country. Therefore, it is necessary to analyze laws and polices of advanced countries and apply them to domestic construction sites in order to reduce fall accidents. Therefore, the objective of this study is to compare domestic laws related fall accident with advanced countries laws. In the future, the results of this study will be utilized as a reference to reinforce Occupation Safety and Health Act(OSHA).

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Studies on Methanolic Extract of Lepidagathis keralensis as Green Corrosion Inhibitor for Mild Steel in 1M HCl

  • Leena, Palakkal;Zeinul Hukuman, N.H.;Biju, A.R.;Jisha, Mullapally
    • Journal of Electrochemical Science and Technology
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    • v.10 no.2
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    • pp.231-243
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    • 2019
  • The methanolic extracts of the leaves and stem of the plant Lepidagathis keralensis were evaluated for anticorrosion behavior against mild steel in 1M HCl. Corrosion inhibition studies were done by gravimetric method, electrochemical impedance spectroscopy and potentiodynamic polarization methods. Surface morphology of mild steel in the presence and absence of inhibitors were studied using SEM analysis. UV-Vis studies were also done to evaluate the mechanism of inhibition. Both the extracts showed good inhibition efficiency which increased with increase in concentration of the inhibitor and decreased with increase in temperature. The mechanism of inhibition was explained by adsorption which obeyed Langmuir adsorption isotherm. Thermodynamic calculations revealed a combination of both physisorption and chemisorption of the inhibitor on the surface of mild steel. The extracts behaved as mixed type inhibitors as determined by polarization studies. Quantum chemical studies on Phenoxyethene, one of the major components in the leaf extract of the plant was also carried out to support the experimental results.

Synthesis and Characterization of Tin-Pyrolyzed Carbon Composites as Anode Material for Lithium Ion Secondary Batteries (리튬이온이차전지 음극활물질로써 주석을 첨가한 열분해탄소의 합성과 특성평가)

  • Hwang, Yun-Ju;Park, Sang-Ho;Kim, Ae-Rhan;Jisha, M.R.;Christy, Maria;Suh, Eun-Kyung;Nahm, Kee-Suk
    • Journal of Energy Engineering
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    • v.19 no.1
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    • pp.16-20
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    • 2010
  • In present work, tin-carbon mixtures by using carbon from pyrolyzed coffee seeds were synthesized. Synthesis methods includes simple mixing and chemical mixing. X-ray diffraction pattern indicated carbon and tin mixture peaks and scanning electron microscope images showed particles size of $12{\sim}85\;{\mu}m$ and shape. Charge discharge test were carried out. Tin-carbon mixture by chemical mixing indicated higher discharge capacity of 191 mAh/g than commercial carbon black(105 mAh/g) for 15cycles. Tin-carbon mixture by simple mixing indicated similar performance to carbon black.

Synthesis, Spectral and Thermal Studies of Lanthanide(III) Complexes of Phenylbutazone (Phenylbutazone의 란탄(III) 착물에 대한 합성, 스펙트럼 및 열적 연구)

  • Anoop, M.R.;Binil, P.S.;Jisha, K.R.;Suma, S.;Sudarsanakumar, M.R.
    • Journal of the Korean Chemical Society
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    • v.55 no.4
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    • pp.612-619
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    • 2011
  • Lanthanide(III) complexes of 1,2-diphenyl-4-butyl-3,5-pyrazolidinedione(phenylbutazone, PB) have been synthesized and characterized by elemental analyses, molar conductance measurements, IR, UV-Vis. and NMR spectra. The spectral data reveal that the PB acts as a bidentate and mono-ionic ligand coordinating through both the carbonyl oxygens of the pyrazolidinedione ring. The molar conductance data suggest that the complexes are non-electrolytes. The thermal behaviour of the complexes was studied by TG and DTG in air atmosphere and the results provide information about dehydration, thermal stability and thermal decomposition. The final products are found to be the corresponding metal oxides. The thermodynamic parameters and kinetic parameters were evaluated for the dehydration and decomposition stages. The negative entropy values of the decomposition stages indicate that the activated complexes have a more ordered structure than the reactants and that the reactions are slower than normal. Based on these studies, the complexes have been formulated as $[Ln(PB)_3]{\cdot}5H_2O$(Ln=La and Ce) and $[Ln(PB)_3(H_2O)_2]{\cdot}2H_2O$(Ln=Pr, Nd and Sm).