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Synthesis and Characterization of Tin-Pyrolyzed Carbon Composites as Anode Material for Lithium Ion Secondary Batteries  

Hwang, Yun-Ju (Department of Hydrogen and Fuel Cells Engineering, Specialized Graduate School, Chonbuk National University)
Park, Sang-Ho (Energy Business Division Development Team, Samsung SDI)
Kim, Ae-Rhan (Department of Hydrogen and Fuel Cells Engineering, Specialized Graduate School, Chonbuk National University)
Jisha, M.R. (Department of Hydrogen and Fuel Cells Engineering, Specialized Graduate School, Chonbuk National University)
Christy, Maria (Division of Semiconductor and Chemical Engineering, Chonbuk National University)
Suh, Eun-Kyung (Division of Semiconductor and Chemical Engineering, Chonbuk National University)
Nahm, Kee-Suk (Department of Hydrogen and Fuel Cells Engineering, Specialized Graduate School, Chonbuk National University)
Publication Information
Abstract
In present work, tin-carbon mixtures by using carbon from pyrolyzed coffee seeds were synthesized. Synthesis methods includes simple mixing and chemical mixing. X-ray diffraction pattern indicated carbon and tin mixture peaks and scanning electron microscope images showed particles size of $12{\sim}85\;{\mu}m$ and shape. Charge discharge test were carried out. Tin-carbon mixture by chemical mixing indicated higher discharge capacity of 191 mAh/g than commercial carbon black(105 mAh/g) for 15cycles. Tin-carbon mixture by simple mixing indicated similar performance to carbon black.
Keywords
lithium ion secondary batteries; pyrolytic carbon; tin; anode material; conductive additive;
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1 M.A. Ferro-García; J. Rivera-Utrilla; J. Rodriguez- Gordillo; I. Bautista-Toledo. Adsorption of zinc, cadmium, and copper on activated carbons obtained from agricultural by-products, Carbon, 1988, 26, 363-373.   DOI   ScienceOn
2 Tao Zhang; W. R. Mckinnon; J. R. Dahn, Hysteresis during lithium insertion in hydrogen-containing carbons, Journal of electrochemical society, 1996, 143, 2137-2145.   DOI   ScienceOn
3 Carlos Moreno-Castilla; Francisco Carrasco-Marin; M.Victoria Lopez-Ramon; Miguel A. Alvarez-Merino. Chemical and physical activation of olive-mill waste water to produce activated carbons, Carbon, 2001, 39, 1415-1420.   DOI   ScienceOn
4 Victory V. Avdeev; Alevtina P. Savch enkova; Ludumila A. Monyakina; Irina V. Nikol'sk aya; Alexey V. Khvostov. Intercalation reactions and carbide formation in graphite-lithium system, Journal of Physical Chemistry Solids, 1995, 57, 947-949.
5 Suna Balci. Thermal decomposition of sepiolite and variations in pore structure with and without acid pre-treatment, Journal of Chemical Technology & Biotechnology, 1996, 66, 72-78.   DOI   ScienceOn
6 Jim Yang Lee; Ruifen Zhang; Zhaolin Liu. Dispersion of Sn and SnO on carbon anodes, 2000, 90, 70-75.
7 A. Ahmadpour; D. D. Do. The preparation of active carbons from coal by chemical and physical activation, Carbon, 1996, 34, 471-479.   DOI   ScienceOn
8 Zhonghua Hu; M. P. Srinivasan; Yaming Ni. Novel activation process for preparing highly microporous and mesoporous activated carbons, Carbon, 2001, 39, 877-886.   DOI   ScienceOn
9 Yun Ju Hwang; Soo Kyung Jeong; Kee Suk Nahm; Jae Sun Shin; A. Manuel Stephan. Pyrolytic carbon derived from coffee shells as anode materials for lithium batteries, 2007, 68, 182-188.
10 Yun Ju Hwang; Soo Kyung Jeong; Jae Sun Shin; Kee Suk Nahm; A. Manuel Stephan. High capacity disordered carbons obtaind from coconut shells as anode materials for lithium batteries, 2008, 448, 141-147.
11 M. Endo; C. Kim; K. Nishimura; T. Fujino; K. Miyashita. Recent development of carbon materials for Li ion batteries, Carbon, 2000, 38, 183-197.   DOI   ScienceOn
12 Qingtang Zhang; Gongchan Peng; Guoping Wang; Meizhen Qu; Zuo Long Yu. Effect of mesoporous carbon containing binary conductive additives in lithium ion batteries on the electrochemical performance of the LiCoO2 composite cathodes, Solid State Ionics, 2009, 180, 698-702.   DOI   ScienceOn
13 Shintaro Kuroda; Norio Tobori; Mio Sakuraba; Yuichi Sato. Charge-discharge properties of a cathode prepared with ketjen black as the electro-conductive additive in lithium ion batteries, 2003, 119-121, 924-928.