• Nuclear Engineering and Technology
• /
• 제52권6호
• /
• pp.1243-1251
• /
• 2020

Irradiation-induced damage of binderless nanoporous-isotropic graphite (NPIG) prepared by isostatic pressing of mesophase carbon microspheres for molten salt reactor was investigated by 3.0 MeV He⁺ irradiation at room temperature and high temperature of 600 ℃, and IG-110 was used as the comparation. SEM, TEM, X-ray diffraction and Raman spectrum are used to characterize the irradiation effect and the influence of temperature on graphite radiation damage. After irradiation at room temperature, the surface morphology is rougher, the increase of defect clusters makes atom flour bend, the layer spacing increases, and the catalytic graphitization phenomenon of NPIG is observed. However, the density of defects in high temperature environment decreases and other changes are not obvious. Mechanical properties also change due to changes in defects. In addition, SEM and Raman spectra of the cross section show that cracks appear in the depth range of the maximum irradiation dose, and the defect density increases with the increase of irradiation dose.

• 공업화학
• /
• 제26권3호
• /
• pp.280-286
• /
• 2015

유연격자로서 분자 중앙에 부틸렌 또는 펜타메틸렌기를 갖는 두 시리즈의 비대칭 이메소젠 화합물을 합성하고, 이들의 열적성질 및 액정성을 연구하였다. 합성된 화합물의 메소젠기는 콜레스테릴기와 곁 치환기를 포함하고 있는 아조벤젠기로 되어 있으며, 이들 액정화합물의 화학구조와 액정성은 FT-IR, $^1H$-NMR, 시차주사열량분석기(DSC), 편광현미경(POM)에 의하여 조사되었다. 화합물 $D5-OCH_3$를 제외한, 합성된 모든 화합물들은 양방성 액정성을 나타내었고, 유연격자의 탄소수가 짝수인 경우 넓은 액정상 온도구간과 높은 등방성 전이온도를 나타내었다. 곁 치환기가 액정성에 미치는 영향으로, 부피가 큰 치환기를 갖는 화합물들은 좁은 액정상 온도구간과 낮은 등방성 전이온도를 나타내었으며, 극성 치환기를 갖는 화합물들은 스멕틱 액정상의 높은 안정성을 나타내었다.

• 한국전자통신학회논문지
• /
• 제16권3호
• /
• pp.471-476
• /
• 2021

분말 야금 기술에 의한 복합 연자성 재료는 전기기기에 일반적으로 사용되는 종래의 전기강판보다 많은 장점을 가지고 있으며, 그 관련 기술은 최근에 상당한 발전을 거듭하고 있다. 복합 연자성 재료는 일반적으로 분말의 형태로 인해 자기적 등방성 가지므로 3차원 자속 및 복잡한 구조의 전기기기 구성에 적합하다. 하지만 SMC와 같이 등방성 자기 특성을 가지는 재료는 복잡한 벡터 히스테리시스를 가지므로 정확한 손실 특성을 예측하는 것이 매우 어렵다. 따라서 본 논문에서는 전기강판 및 SMC의 링 타입 시편을 제작하고 시편 크기에 따라 자기적 특성을 측정한 후, 측정된 자기적 정보를 이용하여 800Hz 이상에서 구동하는 고속 영구자석 전동기의 전자계 해석을 수행하였다. 또한, 해당 모델의 시작품을 제작하고 효율 측정 및 비교를 통해 본 논문의 신뢰성을 입증하였다.

• 한국세라믹학회지
• /
• 제43권7호
• /
• pp.439-444
• /
• 2006

Artificial graphite generally manufactured by carbonization sintering of shape-body of kneaded mixture using granular cokes as filler and pitch as binder, going through pitch impregnation process if necessary and finally applying graphitization heat treatment. Graphite materials are used for core internal structural components of the High-Temperature Gas-cooled Reactors (HTGR) because of their excellent heat resistibility and resistance of crack progress. The HTGR has a core consisting of an array of stacked graphite fuel blocks are machined from IG-110, a high-strength, fine-grained isotropic graphite. In this study, crack stabilization and micro-structures were measured by bend strength and fracture toughness of isotropic graphite grade IG-110. It is important to the reactor designer as they may govern the life of the graphite components and hence the life of the reactor. It was resulted crack propagation, bend strength, compressive strength and micro-structures of IG-110 graphite by scanning electron microscope and universal test machine.

• Advances in aircraft and spacecraft science
• /
• 제2권3호
• /
• pp.249-261
• /
• 2015

The mechanical characterization of composite materials is nowadays a major interest due to their increasing use in the aeronautic industry. The design of most of these materials is based on their stiffness, which is mainly obtained by means of tensile tests with strain gauge measurement. For thin laminated composites, this classical method requires adequate samples with specific orientation and does not provide all the independent elastic constants. Regarding ultrasonic characterization, especially immersion technique, only one specimen is needed and the entire determination of the stiffness tensor is possible. This paper presents a study of different methods to determine the mechanical properties of transversely isotropic carbon fibre composite materials (gauge and correlation strain measurement during tensile tests, ultrasonic immersion technique). Results are compared to ISO standards and manufacturer data to evaluate the accuracy of these techniques.

• Composites Research
• /
• 제30권3호
• /
• pp.193-201
• /
• 2017

탄소나노튜브와 폴리에스터 계면 간 그래프팅이 나노복합재의 역학적 거동과 하중전달에 미치는 영향을 고찰하기 위해 분자동역학 전산모사를 수행하고 그 결과를 Mori-Tanaka 모델 예측해와 비교하였다. 각 방향으로의 인장과 전단 전산모사를 통해 응력-변형률 선도를 도출한 후, 가교 유무에 따른 탄성거동 변화를 관찰하였다. 또한 가로등방성 강성행렬을 방향 평균하여 나노튜브가 랜덤분포하는 경우의 등방성 영률과 전단계수를 구하였다. 그 결과 가로방향 영률과 전단계수는 그래프팅 가공에 의해 향상되었으나, 길이방향 영률의 경우 나노튜브의 물성감소로 인해 오히려 물성이 저하되었다. 나노튜브의 랜덤분포를 고려한 예측 결과에서는 그래프팅 가공에 의해 물성이 약간 감소하였다.

• Fibers and Polymers
• /
• 제2권4호
• /
• pp.178-183
• /
• 2001

A pitch precursor for a general purpose carbon fiber was prepared by condensation of pyrolized fuel oil (petroleum residual oil) with bromine under nitrogen blowing. such a condensation raised the softening point of the pitch from 4$0^{\circ}C$ to $265^{\circ}$ with a yield of 43%. The pitch precurosr showed an enhanced aromaticity and enlarged molecular size, which led to a reduction in molecular mobility and optical isotropy. The precursor was spun into fibers of $20\mu\textrm{m}$ diameter at a take-up speed of 700m/min. The fiber was stepwise stabilized in air and carbonized in Ar gas to obtain an isotropic carbon fiber. The carbon fiber exhibited tensile strengths of 500-800 ㎫though the fiber was formed via a crude method. The electric conductivity of the carbon fiber was relatively high, 2.2$\times$$10^2$S/cm, sufficient to be used as electrode materials.

• 한국소음진동공학회:학술대회논문집
• /
• 한국소음진동공학회 1997년도 춘계학술대회논문집; 경주코오롱호텔; 22-23 May 1997
• /
• pp.687-694
• /
• 1997

The anisotropy and shape of distributed piezopolymer actuator have advantages over isotropic piezo ceramic materials, since these features of PVDF can be utilized as another design variable in control application. This study is interested in the reduction of sound transmission through elastic plate into interior space by using the PVDF actuator. The plate-cavity system is adopted as a test problem. The vibration of composite plate and the sound fields through plate are analyzed by using the coupled finite element and boundary element method. Some numerical simulations are performed on sound transmission through elastic plates. To investigate the effects of anisotropy and shape of distributed piezopolymer actuator, various kinds of distributed PVDF actuators are applied in sound control simulation for isotropic and anisotropic plates. The PVDF actuators applied are different from each other in their shapes and laminate angles. The results of control simulation show that the control effectiveness of distributed PYDF actuator can be enhanced by using the coupling between shape of actuator and vibration modes of structure and the anisotropy of piezoelectric properties of PVDF.

• Carbon letters
• /
• 제16권3호
• /
• pp.135-146
• /
• 2015

Graphite can be classified into natural graphite from mines and artificial graphite. Due to its outstanding properties such as light weight, thermal resistance, electrical conductivity, thermal conductivity, chemical stability, and high-temperature strength, artificial graphite is used across various industries in powder form and bulk form. Artificial graphite of powder form is usually used as anode materials for secondary cells, while artificial graphite of bulk form is used in steelmaking electrode bars, nuclear reactor moderators, silicon ingots for semiconductors, and manufacturing equipment. This study defines artificial graphite as bulk graphite, and provides an overview of bulk graphite manufacturing, including isotropic and anisotropic materials, molding methods, and heat treatment.

• Journal of Magnetics
• /
• 제8권3호
• /
• pp.118-120
• /
• 2003

As an alternative promising way of producing high coercivity Sr-ferrite for a permanent magnet application, intensive mechanical milling process was applied to the raw materials of the Sr-ferrite with different composition. Synthesising reactivity for the Sr-ferrite of the mechanically milled raw material containing $SrCO_3$, $La_2O_3$, $Fe_2O_3$, $Co_3O_4$, and $SiO_2$ was inferior to that of the raw material containing $SrCO_3$ and $Fe_2O_3$, The Sr-ferrite prepared from mechanically milled raw materials had profoundly improved magnetic properties compared to the Sr-ferrite prepared by conventional method. Beneficial effect of the substituting ($La_2O_3$, $Co_3O_4$) and additive ($SiO_2$) oxides for improving the magnetic properties was not exploited in the Sr-ferrite prepared from the mechanically milled raw material. The Sr-ferrite powder prepared from the mechanically milled raw materials was magnetically isotropic in nature.