• Title/Summary/Keyword: Isotopic composition

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제주도 한라산 남북측 사면 용천수의 수리지구화학

  • 이광식;박원배;현승규;김용제;문덕철;김구영
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2004.04a
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    • pp.408-412
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    • 2004
  • A total of 23 springs distributed in the southern and northern sides of Mt. Hala in Jeju Island were seasonally sampled and analyzed for their major ion chemistry and oxygen and hydrogen isotope compositions to investigate their hydrogeochemical and isotopic characteristics. Dissolved ion concentrations of the south-side springs slightly increase with decreasing altitude. This indicates that dissolved ion concentrations of groundwater recharged at higher altitudes increase by water-rock interaction during the downgradient migration of groundwater through highly permeable volcanic aquifer. Dissolved ion concentrations of the north-side springs also slightly increase with decreasing altitude, but dramatically increase at ~300 m.a.s.l. This may indicate a sudden input of contaminants to the north-side groundwater system around ~300 m.a.s.l. Springs located in areas above ~300 m.a.s.l. have very low concentrations of dissolved ions, showing little seasonal variations. Whereas springs located in areas below ~300 m.a.s.l. show a big seasonal variation in the concentration of dissolved ions. Seasonal variation of oxygen isotope compositions of springs is ~3$\textperthousand$ for high-altitude springs (~1700 m.a.s.l.) and is ~2$\textperthousand$ near shore, indicating an attenuation of the variation through mixing with other groundwater bodies during migration.

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Studies on Fluid Inclusion and Stable Isotope of the Namsan Gold-Silver Mine (남산 금-은광산의 유체포유물 및 안정동위원소 연구)

  • Kim, Se-Hyun;Choi, Sang-Hoon
    • Economic and Environmental Geology
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    • v.29 no.2
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    • pp.119-127
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    • 1996
  • Electrum-sulfide minerals of the Namsan Au-Ag mine were deposited in two stages of quartz and calcite veins that fill fault planes in Mesozoic granitic rocks (230~155 Ma). The K/Ar radiometric dating of hydrothermal sericite indicates that mineralization is early Cretaceous age ($127{\pm}3.0Ma$). Mineralogic, fluid inclusion and sulfur isotopic data show that ore minerals were deposited at temperatures between $340^{\circ}C$ and $200^{\circ}C$ from fluid with salinities of 3 to 6 equiv. wt % NaCl. Evidence of fluid boiling (and $CO_2$ effervescence) indicates a maximum pressures of 100 bars. The formation temperature and $fs_2$, of Au-mineralization from the Namsan mines are mainly $280{\sim}230^{\circ}C$ and $10^{-11}{\sim}10^{-13}$ atm, respectively. Au deposition was likely a result of boiling caused to chemical change (pH, $f_{O2}$, ${\Sigma}_{H_2S{\cdot}{\cdot}}$) of ore-fluids. Sulfur isotope composition of sulfide minerals (${\delta}^{34}S=5.1$ to 8.2‰) are consistent with ${\delta}^{34}S_{{\Sigma}{H2S}}$ value of +6 to +7‰, suggesting an igneous source of sulfur partially mixed with wall-rock sulfur.

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Geochemistry and K-Ar Age of Alkali Basalts from Weno Island, Caroline Islands, Western Pacific (서태평양 캐롤라인군도 웨노섬 알칼리 현무암류의 지구화학 및 K-Ar 연대)

  • Lee, Jong-Ik;Hur, Soon-Do;Park, Byong-Kwon;Han, Sang-Jun
    • Ocean and Polar Research
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    • v.23 no.1
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    • pp.23-34
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    • 2001
  • Geochemical and Sr-Nd isotopic compositions and K-Ar ages are analyzed in volcanic rocks from Weno Island, Caroline Islands. Seven Weno lava samples of alkali basalt and basaltic trachyandesite are aphyric or sparsely phyric comprising olivine, plagioclase, and clinopyroxene phenocrysts. Whole-rock geochemical variation of Weno lavas reflects main fractional crystallization of olivine and Cr-spinel phenocrysts. Newly determined K-Ar ages of Weno lavas range from 6.7 to 11.3 Ma (late Miocene), indicating their formation during primary volcanic stage of Chuuk Islands. Trace element compositions of Weno lavas are very similar to those of typical ocean island basalts (OIBs), suggesting their formation during intra-plate mantle plume activity. The plume composition is isotopically very similar to that of Hawaiian hot spot. However, the age span of Chuuk volcanism is longer than that of the other individual volcanoes in the Pacific.

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Stable Nitrogen Isotopes in a Forested Watershed in Taiwan

  • Owen, Jeffrey S.
    • Journal of Forest and Environmental Science
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    • v.29 no.2
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    • pp.116-124
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    • 2013
  • Differences in rates and patterns of nitrogen cycling have been correlated with nitrogen stable isotope measurements in forest ecosystems of tropical and temperate regions, but limited similar work has been conducted in sub-tropical forests. This study investigated patterns in stable N isotopic composition in a subtropical forest in Taiwan by sampling three soil profiles and overstory and understory foliage. Soil ${\delta}^{15}N$ in the forest floor ranged from -1.8 to -1.8‰. Mineral soils had higher ${\delta}^{15}N$ (4.1 to 6.0‰). Foliage ${\delta}^{15}N$ in overstory trees ranged from -6.6 to -2.0‰, and understory foliage ${\delta}^{15}N$ ranged from -5.0 to -1.2‰. There was a weak correlation between foliar % N and ${\delta}^{15}N$ ($r^2=0.214$). Compared to results from similar surveys in tropical and temperate forests, foliar ${\delta}^{15}N$ values were generally lower. These results help highlight the need for improved knowledge regarding the relationships between patterns in N stable isotopes and processes affecting rates of N cycling, especially as related to wider scale patterns in forest ecosystems within the east-Asia region.

Variation Pattern of ${\delta}^{13}C_{DIC}$ of the Odaecheon Stream Water

  • Shin, Woo-Jin;Chung, Gong-Soo
    • 한국지구과학회:학술대회논문집
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    • 2005.02a
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    • pp.115-125
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    • 2005
  • Carbon isotopic composition of a stream (Odaecheon Stream) monitored over 7 months from July 2004 to January 2005 in Gangweon Province ranges from -9.24 to -4.69‰. Strong negative correlation between ${\delta}^{13}C_{DIC}$ and water temperature suggests that temperature is a dominant factor controlling ${\delta}^{13}C_{DIC}$ in the Odaecheon Stream. The variation pattern of ${\delta}^{13}C_{DIC}$ was thought to be caused by fractionation of C isotope between stream water and atmosphere and more fractionation at reduced temperature. More fractionation of C isotope between stream water and atmosphere at reduced temperature resulted in increase of ${\delta}^{13}C_{DIC}$ of stream water in winter compared to summer. Photosynthesis and respiration of aqueous biota seem to affect little in ${\delta}^{13}C_{DIC}$ as indicated by little variation of dissolved oxygen and reverse variation pattern of Eh in the stream and scarce aqueous biota in stream water. pH seems to be controlled by $CO_2{2}$ exchange between stream water and atmosphere. During summer more $CO_2{2}$ exchange between stream water and atmosphere resulted in decrease in pH value.

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Measurement of triple point of water temperature for improvement of the national standards and key comparison (국가표준향상과 핵심국제비교를 위한 물의 삼중점 온도 측정)

  • Yang, Inseok;Lee, Young Hee
    • Journal of Sensor Science and Technology
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    • v.30 no.5
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    • pp.349-356
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    • 2021
  • The Korea Research Institute of Standards and Science (KRISS), a National Metrology Institute of Korea, participated in the second-round of the international key comparison CCT-K7.2021 of triple point of water (TPW) cells. For the key comparison, three TPW cells, one of which had been used in the old CCT-K7 comparison, were assigned as the national standard of the TPW. The temperature difference (ΔT) between the average of the new and old national standards and ΔT between the new national standard and the transfer standard were measured. The comparison between the new and old national standards indicated a temperature increase of 69.5 µK after both the standards were corrected for the isotopic composition. The uncertainty of the national standard of the TPW temperature was 28 µK, and the uncertainty of ΔT was 14 µK. Three aspects of improvements in the new comparison compared to the old one were noted: (1) inclusion of two quartz cells in the national standard strengthens its long-term stability; (2) the standard deviation associated with the measurement of ΔT was reduced from 21 µK to 9.6 µK; (3) and the measured immersion profile of the TPW cells was much closer to the theoretically predicted dependence.

Monitoring and control of multiple fraction laws with ring based composite structure

  • Khadimallah, Mohamed A.;Hussain, Muzamal;Naeem, Muhammad Nawaz;Taj, Muhammad;Tounsi, Abdelouahed
    • Advances in nano research
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    • v.10 no.2
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    • pp.129-138
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    • 2021
  • In present article, utilizing the Love shell theory with volume fraction laws for the cylindrical shells vibrations provides a governing equation for the distribution of material composition of material. Isotopic materials are the constituents of these rings. The position of a ring support has been taken along the radial direction. The Rayleigh-Ritz method with three different fraction laws gives birth to the shell frequency equation. Moreover, the effect of height- and length-to-radius ratio and angular speed is investigated. The results are depicted for circumferential wave number, length- and height-radius ratios with three laws. It is found that the backward and forward frequencies of exponential fraction law are sandwich between polynomial and trigonometric laws. It is examined that the backward and forward frequencies increase and decrease on increasing the ratio of height- and length-to-radius ratio. As the position of ring is enhanced for clamped simply supported and simply supported-simply supported boundary conditions, the frequencies go up. At mid-point, all the frequencies are higher and after that the frequencies decreases. The frequencies are same at initial and final stage and rust itself a bell shape. The shell is stabilized by ring supports to increase the stiffness and strength. Comparison is made for non-rotating and rotating cylindrical shell for the efficiency of the model. The results generated by computer software MATLAB.

Fissile Measurement in Various Types Using Nuclear Resonances

  • YongDeok Lee;Seong-Kyu Ahn
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.21 no.2
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    • pp.235-246
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    • 2023
  • Neutron resonance transmission technique was applied for assaying isotopic fissile materials produced in the pyro-process. In each process of the pyro-process, a different composition of the fissile material is produced. Simulation was basically performed on 235U and 239Pu assay for TRU-RE product, hull waste, and uranium addition. The resonance energies were evaluated for uranium and plutonium in the simulation, and the linearity in the detection response was examined on the fissile content variation. The linear resonance energies were determined for the analysis of 235U and 239Pu on the different fissile materials. For enriched TRU-RE assay, the sample condition was suggested; The sample density, content, and thickness are the key factors to obtain accurate fissile content. The detection signal is discriminated for uranium and plutonium in neutron resonance technique. The transmitted signal for fissile resonance has a direct relation with the content of fissile. The simulation results indicated that the neutron resonance technique is promising to analyze 235U and 239Pu for various types of the pyro-process material. An accurate fissile assay will contribute toward safeguarding the pyro-processing system.

High-resolution Stable Isotope Analyses of the Otolith of Argyrosomus argentatus (고해상 시료 채취를 통한 보구치 이석의 안정동위원소 분석)

  • Khim, Boo-Keun;Lee, Tae-Won
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.13 no.1
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    • pp.83-88
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    • 2008
  • Using micromill, discrete carbonate powders from the otolith of Argyrosomus argentatus were sampled along the growth band, and high-resolution stable isotope profiles were obtained. The ${\delta}^{18}O$ and ${\delta}^{13}C$ values are increasing gradually from the core to the margin. However, such increases do not seem to be attributed to the environmental property changes during the growth, but to the dominant effect of metabolic carbons during the early growth, and then, the isotopic composition seems to be equilibrium to the environmental condition. This paper allows the diverse applicability of high-resolution isotope research to the fish otoliths in the future.

Ginseng authenticity testing by measuring carbon, nitrogen, and sulfur stable isotope compositions that differ based on cultivation land and organic fertilizer type

  • Chung, Ill-Min;Lee, Taek-Jun;Oh, Yong-Taek;Ghimire, Bimal Kumar;Jang, In-Bae;Kim, Seung-Hyun
    • Journal of Ginseng Research
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    • v.41 no.2
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    • pp.195-200
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    • 2017
  • Background: The natural ratios of carbon (C), nitrogen (N), and sulfur (S) stable isotopes can be varied in some specific living organisms owing to various isotopic fractionation processes in nature. Therefore, the analysis of C, N, and S stable isotope ratios in ginseng can provide a feasible method for determining ginseng authenticity depending on the cultivation land and type of fertilizer. Methods: C, N, and S stable isotope composition in 6-yr-old ginseng roots (Jagyeongjong variety) was measured by isotope ratio mass spectrometry. Results: The type of cultivation land and organic fertilizers affected the C, N, and S stable isotope ratio in ginseng (p < 0.05). The ${\delta}^{15}N_{AIR}$ and ${\delta}^{34}S_{VCDT}$ values in ginseng roots more significantly discriminated the cultivation land and type of organic fertilizers in ginseng cultivation than the ${\delta}^{13}C_{VPDB}$ value. The combination of ${\delta}^{13}C_{VPDB}$, ${\delta}^{15}N_{AIR}$, or ${\delta}^{34}S_{VCDT}$ in ginseng, except the combination ${\delta}^{13}C_{VPDB}-^{34}S_{VCDT}$, showed a better discrimination depending on soil type or fertilizer type. Conclusion: This case study provides preliminary results about the variation of C, N, and S isotope composition in ginseng according to the cultivation soil type and organic fertilizer type. Hence, our findings are potentially applicable to evaluate ginseng authenticity depending on cultivation conditions.