• The Korean Journal of Quaternary Research
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• v.10 no.1
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• pp.19-26
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• 1996

This review gives an information on the oxygen isotopic composition of car-bonate and utility of paleotemperature equations to reconstruct the paleoenvironment in the late Quaternary paleoclimatic studies. The introduc-tion of various paleotemperature equations is described with respect to the de-velopment and usefulness. In addition the calculation of paleotemperature in the paleoceanographic and paleoclimatic research is constrained to provide more precise and correct approach in the interpretation of paleotemperature.

• The Journal of the Petrological Society of Korea
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• v.7 no.2
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• pp.77-97
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• 1998

We analyzed geochemical and radiogenic isotope data to investigate the genesis and source characteristics of the Onjeongri granite in the northern part of the Gyeongsang Basin. Field observation and K-Ar ages confirm late Cretaceous intrusion (ca. 87 Ma) of the Onjeongri granite. The hornblende geobarometery gives less than 2 kbar for the emplacement pressure of the Onjeongri granite. Geochemical and isotopic compositions suggest that the Onjeongri granite was formed in a relatively immature arc system. $SiO_2$ contents show a negative linear relationship with initial $^{87}Sr/^{86}Sr$ ratios, and an apparent positive correlation with $^{207}Pb/^{204}Pb$ ratios, suggesting an incomplete mixing or assimilation. However, the isotopic data known for any exposed rocks of the study area do not fit as an endmember, implying that the contaminant might reside in the lower crust. A review of published isotopic ages, geochemical, and Sr and Nd isotopic data for the Cretaceous to Tertiary granites in the Gyeongsang Basin indicates the followings. 1) Granitic magmatism in the Gyeongsang Basin were episodic. 2) Granitic rocks in the basin were derived from young (< 0.9 Ga) lower crust, and their isotopic signatures reflect heterogeneous source region. Geochemical and isotopic signatures of granitic rocks in the basin are difficult to explain by upper crustal contamination. 3) Granites in the Gyeongsang Basin have closely related to those in the San in Belt of the Inner Zone of Southwest Japan in terms of age, petrography, and isotopic and geochemical composition. 4) Sr-Nd isotopic signatures of the Onjeongri granite are relatively primitive compared with granitic rocks in the other parts of the Gyeongsang Basin and in the Inner Zone of Southwest Japan.

• Economic and Environmental Geology
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• v.27 no.2
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• pp.117-130
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• 1994

Titanomagnetite ore bodies in the Yonchon iron mine are closely associated with alkali gabbroic rocks of middle Proterozoic age which intruded Precambrian metasedimentary rocks. The orebodies can be divided into massive ores in gabbroic rock, skarn ores in calcareous xenoliths and banded ores in gneissic gabbro. Gabbroic rocks from the Yonchon iron mine have unusually high content of $TiO_2$ with an average values of 3.46 wt%. Iron ores are ilmenite (42.25~51.56 wt% in $TiO_2$) and titanomagnetite (1.29~6.57 wt% in $TiO_2$) and the former is dominant Small amount of magnetite, hematite, sphene and sulfide minerals are included in the ores. Grandite garnet, titanoaugite and tschermakite are in iron skarn ores. Hornblendes from ores and gabbroic rocks have a relatively homogeneous isotopic composition with ${\delta}D$ between -110.0 and -133.9‰, and ${\delta}^{18}O$ of +4.5 to +6.5‰, and calculated to have formed in fluids with ${\delta}O_{H_2O}$ of + 6.7 to +8.7‰. and ${\delta}_{H_2O}$ of -87.9 to -111.8‰, which has a similar isotopic value of primary magmatic water. Based on intrusive age, occurrence, mineral chemistry and isotopic compositions of magnetite ores and gabroic rocks, it will be concluded that the gabbroic rocks are responsible for the titanomagnetite mineralization. The titaniferous magnetite melt was immiscibly separated from the high titaniferous gabbroic melts of Proterozoic age.

• Economic and Environmental Geology
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• v.33 no.6
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• pp.491-504
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• 2000

Environmental isotope $^{18}O$, $^{2}H$, $^{3}H$,$^{13}C$, $^{34}S$and $^{87}Sr/^{86}Sr$) studies on ${CO_2}$-rich waters in the Kangwon Province were carried out to elucidate the origin, residence time, water-rock interaction and mixing process of their. ${\delta}^{18}O$ and ${\delta}D$ data indicate that ${CO_2}$-rich waters were derived from the local meteoric water. It also shows that each type of ${CO_2}$-rich water has distinct isotopic composition and Na-${HCO_3}$ type water (-10.8 to -12.1${\textperthousand}$, ${\delta}^{18}O$ ) is lighter than other type waters. These depleted isotopic values supposedly indicate that, considering the altitude effect of isotope in Korea, the recharge area of Na-${HCO_3}$ type water can be estimated to be relatively higher in elevation than those of Ca-${HCO_3}$ and Ca-Na-${HCO_3}$ type waters. Tritium contents close to zero are observed in the Na-${HCO_3}$ type water, confirming a long residence time and the possibility of a ${CO_2}$ inflow into the aquifer at great depth. These isotope data also show that the Ca-${HCO_3}$ type water has undergone mixing process with surface water during ascending at depth, whereas Na-${HCO_3}$ type water was less mixed with surface waters. The carbon isotope data (-8.8 to ＋0.8 ${\textperthousand}$ ${\delta}^{13}C$) indicate that dissolved carbon in the ${CO_2}$-rich waters was possibly derived from deep seated ${CO_2}$ gas. The high ${\delta}^{34}S$ values (up to 38.1${\textperthousand}$) of dissolved sulfates suggest that sulfate reduction by microbial activity had occurred at depth. Strontium isotopic data ($^{87}Sr/^{86}Sr$) of ${CO_2}$-rich waters indicate that the chemistry of the ${CO_2}$-rich waters is determined by water-rock (granite) interaction.

• Journal of Astronomy and Space Sciences
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• v.15 no.1
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• pp.163-174
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• 1998

To study the origin of organic matter in meteorite, terrestrial rocks which contain or-ganic compounds similar to the ones found in carbonaceous chondrites are studied and compared with Muchison meteorite. Hydrocarbon molecules were extracted by benzene and methanol from bituminous coal and oil shale and the extracts were partitioned into aliphatic, aromatic, and polar fractions by silica gel column chromatography. Carbon isotopic ratios in each fractions were analysed by GC-C-IRMS. Molec-ular compound identifications were carried by GC-MS Engine. Bituminous coal and oil shale show the organic compound composition similar to that of meteorite. Oil shale has a wide range of ${\delta}^{13}C,-20.1%_0~-54.4%_0$ compared to bituminous coal, $-25.2%_0~34.3%_0$. Delta values of several molecular compounds in two terrestrial samples are different. They show several distinct distributions in isotopic ratios compared to those of meteorite; Murchison meteorite has a range of ${\delta}^13C\;from\;-13%_0\;to\;+30%_0$. These results provide interpretation for the source and the formation condition of each rock, in particular alteration and migration processes of organic matter. Especially, they show an important clue whether some hydrocarbon molecules observed in meteorite are indigenous or not.

• Proceedings of the Korean Society of Crop Science Conference
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• 2017.06a
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• pp.263-263
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• 2017

Rice (Oryza sativa L.) is the world's third largest food crop after wheat and corn. Geographic authentication of rice has recently emerged as an important issue for enhancing human health via food safety and quality assurance. Here, we aimed to discriminate rice from six Asian countries through geographic authentication using combinations of elemental/isotopic composition analysis and chemometric techniques. Principal components analysis could distinguish samples cultivated from most countries, except for those cultivated in the Philippines and Japan. Furthermore, orthogonal projection to latent structure-discriminant analysis provided clear discrimination between rice cultivated in Korea and other countries. The major common variables responsible for differentiation in these models were ${\delta}^{34}S$, Mn, and Mg. Our findings contribute to understanding the variations in elemental and isotopic compositions in rice depending on geographic origins, and offer valuable insight into the control of fraudulent labeling regarding the geographic origins of rice traded among Asian countries.

• Nuclear Engineering and Technology
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• v.38 no.4
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• pp.353-358
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• 2006

Alpha track analysis for the determination of the trace amount of alpha emitting nuclides in a very small particle was performed as an efficient and powerful technique during safeguard inspection. Metal particles with well-defined spherical shape, size and isotopic compositions as a reference material were used to correlate the number of tracks or track diameter with an isotopic composition eventually to identify the uranium enrichment in the environmental swipe samples. Slopes in the number of tracks versus the exposure time curve provide a simple insight into the uranium enrichment of an unknown particle. Low enriched uranium metal particles result in slopes still steeper than the depleted or natural uranium metal particles. In addition, a linear relationship between track diameter and particle size Is thought to be a useful first stage analytical tool as an efficient and convenient inspection guide. The significance of the simple linear model was also judged using the usual statistical tests.

• The Journal of the Petrological Society of Korea
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• v.10 no.3
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• pp.133-147
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• 2001

Recently developing method of age determination using stepwise dissolution technique to expand the applicability of absolute age determination significantly is evaluated whether it is applicable to the Korean samples. The materials selected for the study are uranium-bearing black slates from Changni Formation of Ogcheon metamorphic belt, tourmaline separated from Naedeongni granite of Yeongnam massif, garnet and ilmenite separated from ilmenite-bearing anorthositic rock of Yeongnam massif, scheelites from Ogbang mine, and magnetite separated from Gyemyeongsan Formation of Ogcheon metamorphic belt. For the stepwise dissolution, various acid steps with different normalities and different durations were applied to leach the samples. The leachate from each step was analyzed to determine the Pb isotopic composition and concentrations of Pb and U using thermal ionization mass spectrometer. The black slates from the Changni Formation and the tourmaline from the Naedeongni granite reveal significant variation of Pb isotopic composition, which reveals the potential of such stepwise dissolution technique as a dating method. The behaviors of uranium and lead during the each stage of step leaching are different, which seem to reflect the differences in positions within the crystal lattices depending upon mineral species.

• Ocean and Polar Research
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• v.30 no.3
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• pp.249-258
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• 2008

Oxygen isotopic composition(${\delta}^{18}O$) of walleye pollock, Theragra chalcogramma, otoliths were measured to investigate interannual and regional correlation with habitat temperature. Specimens were collected from fishermen in Korea and Japan between $1997{\sim}1999$, while seawater temperatures were obtained from Korean and Japanese Oceanographic Data Centers. Seawater temperature was generally lower off the eastern Korean Peninsula than off eastern Hokkaido(Japan). Sagittal otoliths were removed for measurement of ${\delta}^{18}O$ using a micro-drilling technique. In most cases, ${\delta}^{18}O$ and habitat temperature exhibited negative relationship in Korean and Japanese waters. Higher ${\delta}^{18}O$ was observed in Korean pollock compared to Japanese pollock. The marginal parts of otoliths exhibited higher ${\delta}^{18}O$ than cores from both regions. This is an indication that somatic growth of walleye pollock occurs in deeper and cooler waters. Interannual variation in ${\delta}^{18}O$ was also observed. Mean ${\delta}^{18}O$ values acquired from 1997 otoliths were lower(2.15%) than those of 1998(2.67%) and 1999 (2.65%) in Korean pollock. These measurements coincided with changes in observed temperature in Korean waters, in which mean seawater temperature was warmer in 1997 than in 1998 and 1999. In Japanese waters, mean seawater temperature was lowest in 1997, which coincided with highest ${\delta}^{18}O$ values in the same year.

• The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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• v.3 no.4
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• pp.214-227
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• 1998

This study was carried out to investigate the composition and diagenesis of the carbonate rocks from the seamounts in the Federated States of Micronesia, Central Pacific. Most of the samples were dredged from the water depth of about 1000-3000 m mainly in Chuuk Island, Hunter Bank, Caroline Ridge and Yap Trench. The carbonate rocks are either pelagic sediment mainly of planktonic foraminifera or shallow-marine sediment of corals, calcareous algae, mollusks and echinoderms. The rocks are altered texturally and chemically, except for those from the Hunter Bank and Yap A. The presence of shallow-marine cements suggests that the carbonate sediment has been subsided or reworked to the present water depth after deposition in shallow-marine environments. The texture of the carbonate sediment is reminiscent of meteoric diagenesis; however, the stable carbon isotopic composition of the altered rock samples shows affinity with that of sea water and the oxygen isotopic values are slightly enriched or same as compared to those of unaltered samples. These stable isotopic data suggest that the carbonate sediment of the study area has been diagenetically altered in the present deep-marine environment.