• Title/Summary/Keyword: Isotope separation

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Hydrogen Perm-Selectivity Properties of the Pd-Ni-Ag Alloy Hydrogen Separation Membranes with Various Surface Nickel Composition (표면 니켈 조성에 따른 팔라듐-니켈-은 합금 수소분리막의 수소투과선택 특성)

  • Lim, Da-Sol;Kim, Se-Hong;Kim, Do-Hui;Cho, Seo-Hyun;Kim, Dong-Won
    • Journal of the Korean institute of surface engineering
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    • v.51 no.5
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    • pp.277-290
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    • 2018
  • In this study, Pd-Ni-Ag alloy hydrogen separation membranes were fabricated by Pd/Ag/Pd/Ni/Pd multi-layer sputter deposition on the modified MIM(Metal Injection Molding)-PSS(Porous Stainless Steel) support and followed heat treatment. Nickel, used as an alloying element in Pd alloy membranes, is inexpensive and stable material in a hydrogen isotope environment at high temperature up to 1123 K. Hydrogen perm-selectivity of Pd-Ni-Ag alloy membranes is affected not only by composition of membrane films but also by other factors such as surface properties of PSS support, microstructure of membrane films and inter-diffused impurities from PSS support. In order to clarify the effect of surface Ni composition on hydrogen perm-selectivity of Pd-Ni-Ag alloy membranes, the other effects were significantly minimized by the formation of dense and homogeneous Pd-Ni-Ag alloy membranes. Hydrogen permeation test showed that hydrogen permeability decreased from $7.6{\times}10^{-09}$ to $1.02{\times}10^{-09}mol/m{\cdot}s{\cdot}Pa^{0.5}$ as Ni composition increased from 0 to 16 wt% and the selectivity for $H_2/N_2$ was infinite.

A STUDY ON THE SIMULTANEOUS MEASUREMENTS OF BETA EMITTING ISOTOPES

  • Lee, Goung-Jin;Kim, Seoung-Pyung
    • Journal of Radiation Protection and Research
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    • v.26 no.3
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    • pp.155-159
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    • 2001
  • Beta radiation is measured for an environmental monitoring purpose or for an internal radiation exposure monitoring of nuclear power plant's worker. In korea, strontium 89 and strontium 90 is measured for an environmental monitoring purpose. Also tritium and carbon 14 contained in urine is measured for an internal radiation exposure monitoring of nuclear power plant's worker. Because above isotopes emits low energy beta radiations having a wide range of energy, very complicated isotope separation preprocess is needed. In this study, two mixed beta emitting isotopes are measured simultaneously using a liquid scintillation counter(LSC) and analyzed by using a developed statistical method. Banded least square method is used to analyze the mixed spectrum, and the goodness-of-fitness test is proposed. Test results show that the developed procedure can be very useful for analyzing a mixed beta emitting isotopes.

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Optics in China: past, present and future

  • Gan, Fuxi
    • Proceedings of the Optical Society of Korea Conference
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    • 2000.02a
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    • pp.68-68
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    • 2000
  • In this paper a very brief review of historical development of optical science and technology in China is presented. More attention has been pain on Modem Optics, which developed since 1950s. The recent development of optical science and technology in following fields are introduced. 1. Optical engineering and instrumentation (tracking theodolites, high speed cameras, satellite laser ranging systems, satellite flying attitude control, cameras for remote sensing, astronomical optical instrument) 2. Applied optics (adaptive optics, optical metrology, infrared optics, optical processing, optical holography) 3. Laser science and technology (ultrashort pulse lasers, UV-X ray lasers, high power laser facilities and laser fusion, laser isotope separation) 4. Laser and nonlinear materials (rare earth elements doped laser glasses and crystals, tunable laser crystals, borate series and organic nonlinear crystals) 5. Optoelectronic science and technology (Optical communication, optical data storage, optical computing) The current situation and developing prospect of optical and optoelectronic industry in China are presented. Furthermore it points out that the optical industry could be developed vigorously only if products development capacity is enhanced and new products industrialization is heightened. The main research and education institutions in the optics field in China, as well as the Chinese Optical Society (COS) are introduced.

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40-W 200-ns 300-kHz Thulium-doped Fiber Laser at 2050 nm

  • Shin, Jae Sung;Cha, Yong-Ho;Chun, Byung Jae;Park, Hyunmin
    • Current Optics and Photonics
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    • v.5 no.5
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    • pp.544-553
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    • 2021
  • A 40-W 200-ns 300-kHz thulium-doped fiber laser at 2050 nm with a master oscillator power amplifier configuration was developed, for application to lithium-isotope separation. The master oscillator generated a 5.35 W continuous-wave beam, which the pulse generator then broke into 200-ns pulses at 300 kHz. Then, the laser beam was amplified by passing through a two-stage amplifier. The output power finally obtained was 42.0 W at 2050 nm, and was stable for a long time, over 2 hours. In spite of this achievement, mode instability was observed in the output beam. This can be solved in the future by using a method such as tight coiling.

Burnup Measurement of Irradiated Uranium Dioxide Fuel by Chemical Methods (화학적 방법에 의한 핵연료의 연소도 측정)

  • Kim, Jung-Suk;Han, Sun-Ho;Suh, Moo-Yul;Joe, Kih-Soo;Eom, Tae-Yoon
    • Nuclear Engineering and Technology
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    • v.21 no.4
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    • pp.277-286
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    • 1989
  • Destructive methods are used for the turnup determination of an irradiated PWR fuel. One of the methods includes U, Pu, Nd-148 and Nd-(145+146) determination by an isotope dilution mass spectrometry using triple spikes (U-233, Pu-242 and Nd-150). The method involves two sequential ion exchange resin separation procedures. Pu is eluted from the first anion exchange resin column (Dowex AG 1$\times$8) with 12 M HCl-0.1 M HI mixed solution, followed by U elution with 0.1 M HCl. Nd is isolated from other fission products on the second anion exchange resin column (Dowex AG 1$\times$4) with a nitric acid-methanol eluent. Each fraction is analysed by thermal ionization mass spectrometry. The difference between Nd-148 and Nd-(145+146) method is found with an average 2.07%. The results are compared with those by the heavy element method using U and Pu isotopes and by the destructive y-spectrometric measurement of Cs-137. The dependences of isotope composition of U and Pu on burn-up, and correlation between those isotopes are illustrated graphically.

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Comprehensive proteome analysis using quantitative proteomic technologies

  • Kamal, Abu Hena Mostafa;Choi, Jong-Soon;Cho, Yong-Gu;Kim, Hong-Sig;Song, Beom-Heon;Lee, Chul-Won;Woo, Sun-Hee
    • Journal of Plant Biotechnology
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    • v.37 no.2
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    • pp.196-204
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    • 2010
  • With the completion of genome sequencing of several organisms, attention has been focused to determine the function and functional network of proteins by proteome analysis. The recent techniques of proteomics have been advanced quickly so that the high-throughput and systematic analyses of cellular proteins are enabled in combination with bioinformatics tools. Furthermore, the development of proteomic techniques helps to elucidate the functions of proteins under stress or diseased condition, resulting in the discovery of biomarkers responsible for the biological stimuli. Ultimate goal of proteomics orients toward the entire proteome of life, subcellular localization, biochemical activities, and their regulation. Comprehensive analysis strategies of proteomics can be classified as three categories: (i) protein separation by 2-dimensional gel electrophoresis (2-DE) or liquid chromatography (LC), (ii) protein identification by either Edman sequencing or mass spectrometry (MS), and (iii) quanitation of proteome. Currently MS-based proteomics turns shiftly from qualitative proteome analysis by 2-DE or 2D-LC coupled with off-line matrix assisted laser desorption ionization (MALDI) and on-line electrospray ionization (ESI) MS, respectively, to quantitative proteome analysis. Some new techniques which include top-down mass spectrometry and tandem affinity purification have emerged. The in vitro quantitative proteomic techniques include differential gel electrophoresis with fluorescence dyes, protein-labeling tagging with isotope-coded affinity tag, and peptide-labeling tagging with isobaric tags for relative and absolute quantitation. In addition, stable isotope labeled amino acid can be in vivo labeled into live culture cells through metabolic incorporation. MS-based proteomics extends to detect the phosphopeptide mapping of biologically crucial protein known as one of post-translational modification. These complementary proteomic techniques contribute to not only the understanding of basic biological function but also the application to the applied sciences for industry.

Characterization of Hydrogen Adsorption for the Silicalite-Supported Platinum Catalysts (실리카라이트에 담지된 백금촉매의 수소흡착특성 연구)

  • Ahn, Do Hee;Paek, Seung Woo;Lee, Han Soo;Chung, Hongsuk
    • Applied Chemistry for Engineering
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    • v.7 no.3
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    • pp.410-415
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    • 1996
  • It is well known that the heavy water separation process using hydrogen isotope exchange reaction over the platinum catalyst is the most efficient. In this study, the Pt/silicalite catalysts were prepared and characterized by hydrogen adsorption in order to develop the hydrophobic platinum catalyst for hydrogen isotope exchange reaction. Silicalite was synthesized as support material and it was verified that silicalite is more hydrophobic than activated carbon and ZSM-5. Also the platinum was loaded on silicalite by conventional impregnation and ion-exchange method respectively. The platinum dispersion of Pt/silicalite catalysts was measured through hydrogen adsorption experiment. The dispersion is very low in the catalyst prepared by the impregnation method while it is very high with limited platinum content in the catalyst prepared by the ion-exchange method.

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Automated Cold Volume Calibration of Temperature Variation in Cryogenic Hydrogen Isotope Sorption Isotherm (극저온(20K) 수소동위원소 흡착 등온선의 온도 변화에 대한 자동 저온 부피 교정)

  • Park, Jawoo;Oh, Hyunchul
    • Korean Journal of Materials Research
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    • v.29 no.5
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    • pp.336-341
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    • 2019
  • The gas adsorption isotherm requires accurate measurement for the analysis of porous materials and is used as an index of surface area, pore distribution, and adsorption amount of gas. Basically, adsorption isotherms of porous materials are measured conventionally at 77K and 87K using liquid nitrogen and liquid argon. The cold volume calibration in this conventional method is done simply by splitting a sample cell into two zones (cold and warm volumes) by controlling the level sensor in a Dewar filled with liquid nitrogen or argon. As a result, BET measurement for textural properties is mainly limited to liquefied gases (i.e. $N_2$ or Ar) at atmospheric pressure. In order to independently investigate other gases (e.g. hydrogen isotopes) at cryogenic temperature, a novel temperature control system in the sample cell is required, and consequently cold volume calibration at various temperatures becomes more important. In this study, a cryocooler system is installed in a commercially available BET device to control the sample cell temperature, and the automated cold volume calibration method of temperature variation is introduced. This developed calibration method presents a reliable and reproducible method of cryogenic measurement for hydrogen isotope separation in porous materials, and also provides large flexibility for evaluating various other gases at various temperature.

Study of the Discharge in a TEA Pulse $CO_2$ Laser (TEA Pulse $CO_2$ Laser에서의 방전연구)

  • Kim, K.W.;Roh, Y.S.;Cho, Y.O.;Oh, C.W.;Roh, H.K.
    • Proceedings of the KIEE Conference
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    • 1989.07a
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    • pp.439-442
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    • 1989
  • $CO_2$ lasers are used in the various industrial fields since the development of $CO_2$ laser in 1964 It is because $CO_2$ laser is more efficient, more powerful than other lasers and $CO_2$ laser light of wavelength $10.6{\mu}m$ interacts with materials well. Thus $CO_2$ laser is used for industrial application such as cutting, punching, welding, surface treatment of metal and nonmetalic materials, isotope separation, etc. Already other research institutes including some universities have recognized the advantages and importance of the $CO_2$ laser, and studied it. However, its technology is in elementary state yet Therefore,we started this study to develop present $CO_2$ laser technology more highly and to fit it. The main purposes of this study are to acquire various technologies such as high voltage, high pressure glow discharge, vaccum and optical cavity design.

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