• Title/Summary/Keyword: Isotope ratio of uranium

Search Result 19, Processing Time 0.03 seconds

Determination of the Concentration and Isotope Ratio of Uranium in Soil and Water by Thermal Ionization Mass Spectrometry

  • Park, Jong-Ho;Park, Sujin;Song, Kyuseok
    • Mass Spectrometry Letters
    • /
    • v.5 no.1
    • /
    • pp.12-15
    • /
    • 2014
  • Thermal ionization mass spectrometry (TIMS) was used to determine the concentration and isotope ratio of uranium contained in samples of soil and groundwater collected from Korea. Quantification of uranium in ground water samples was performed by isotope dilution mass spectrometry. A series of chemical treatment processes, including chemical separation using extraction chromatography, was applied to the soil samples to extract the uranium. No treatments other than filtration were applied to the groundwater samples. Isotopic analyses by TIMS showed that the isotope ratios of uranium in both the soil and water samples were indistinguishable from those of naturally abundant uranium. The concentration of uranium in the groundwater samples was within the U.S. acceptable standards for drinking water. These results demonstrate the utility of TIMS for monitoring uranium in environmental samples with high analytical reliability.

Feasibility Study of Isotope Ratio Analysis of Individual Uranium-Plutonium Mixed Oxide Particles with SIMS and ICP-MS

  • Esaka, Fumitaka;Magara, Masaaki;Suzuki, Daisuke;Miyamoto, Yutaka;Lee, Chi-Gyu;Kimura, Takaumi
    • Mass Spectrometry Letters
    • /
    • v.2 no.4
    • /
    • pp.80-83
    • /
    • 2011
  • Isotope ratio analysis of nuclear materials in individual particles is of great importance for nuclear safeguards. Although secondary ion mass spectrometry (SIMS) and thermal ionization mass spectrometry (TIMS) are utilized for the analysis of individual uranium particles, few studies were conducted for the analysis of individual uranium-plutonium mixed oxide particles. In this study, we applied SIMS and inductively coupled plasma mass spectrometry (ICP-MS) to the isotope ratio analysis of individual U-Pu mixed oxide particles. In the analysis of individual U-Pu particles prepared from mixed solution of uranium and plutonium standard reference materials, accurate $^{235}U/^{238}U$, $^{240}Pu/^{239}Pu$ and $^{242}Pu/^{239}Pu$ isotope ratios were obtained with both methods. However, accurate analysis of $^{241}Pu/^{239}Pu$ isotope ratio was impossible, due to the interference of the $^{241}Am$ peak to the $^{241}Pu$ peak. In addition, it was indicated that the interference of the $^{238}UH$ peak to the $^{239}Pu$ peak has a possibility to prevent accurate analysis of plutonium isotope ratios. These problems would be avoided by a combination of ICP-MS and chemical separation of uranium, plutonium and americium in individual U-Pu particles.

A Review on Analysis of Natural Uranium Isotopes and Their Application (우라늄 동위원소의 분석과 활용에 대한 고찰)

  • Yeongmin Kim
    • Economic and Environmental Geology
    • /
    • v.56 no.5
    • /
    • pp.547-555
    • /
    • 2023
  • Due to enhanced precision in uranium isotope measurements with MC-ICP-MS, there has been a surge in studies concerning the naturally occurring uranium isotope ratio (238U/235U) and its associated fractionation processes. Several researchers have highlighted that the 238U/235U ratio, previously assumed to be constant, can vary by several per mil depending on different natural fractionation processes. This review paper outlines the uranium isotope values (δ238U) for major terrestrial reservoirs and their variations. It discusses the range of δ238U values and uranium isotope fractionation seen in uranium ore deposits, based on deposit type and ore-forming conditions. In conclusion, this paper emphasizes the importance of studies on uranium ore deposits. Such deposits serve as natural simulation models vital for designing high-level radioactive waste repository sites.

A comparative study of ultra-trace-level uranium by thermal ionization mass spectrometry with continuous heating: Static and peak-jumping modes

  • Lee, Chi-Gyu;Park, Ranhee;Park, Jinkyu;Lim, Sang Ho
    • Nuclear Engineering and Technology
    • /
    • v.52 no.7
    • /
    • pp.1532-1536
    • /
    • 2020
  • For ensuring nuclear safeguards, we report the analytical signal-detection performance of thermal ionization mass spectrometry (TIMS) with continuous heating for the measurement of isotopic ratios in samples containing ultra-trace amounts of uranium. As methods for detecting uranium signals, peak-jumping mode using a single detector and static mode using multiple detectors were examined with U100 (10% 235U-enriched) uranium standard samples in the femtogram-to-picogram range. Uranium isotope ratios, n(235U)/n(238U), were measured down to levels of 1 fg and 3 fg in static and peak-jumping modes, respectively, while n(234U)/n(238U) and n(236U)/n(238U) values were measured down to levels of 100 fg in both modes. In addition, the dependency of the 238U signal intensity on sample quantity exhibited similar tendencies in both modes. The precisions of the isotope ratios obtained in the static mode over all sample ranges used in this study were overall slightly higher than those obtained in peak-jumping mode. These results indicate that isotope ratio measurements by TIMS with continuous heating are almost independent of the detection method, i.e., peak-jumping mode or static mode, which is characteristic of isotope-ratio measurements using the TIMS method with continuous heating. TIMS with continuous heating is advantageous as it exhibits the properties of multiple detectors within a single detector, and is expected to be used in various fields in addition to ensuring nuclear safeguards.

Uranium Isotopic Ratio Analysis of U-Bearing Particulates By SIMS in CIAE

  • Yonggang, Zhao
    • Proceedings of the Korean Radioactive Waste Society Conference
    • /
    • 2004.02a
    • /
    • pp.257-259
    • /
    • 2004
  • In this paper measurement method of uranium isotope ratio of uranium-bearing particles in swipe samples was introduced; Swipe sample screening program was proposed on the basis of studying various destructive assay and non-destructive assays. Scanning electron microscope(SEM) equipped with an energy dispersive X-ray fluorescence(XRF) system was applied to locate the deposited uranium-containing particles on the graphite support, particle's composition and size can be identified. Some isotope ratio results were compared with those of other bulk analytical methods; By measuring the same prepared sample, we got the U-particle isotopic ratio data similar to those from IAEA NWAL, indicating that our operation parameters and experimental conditions are viable and can be used for measurement of U-particle isotopic ratio from swipe samples.

  • PDF

A Technique to Minimize Impurity Signal from Blank Rhenium Filaments for Highly Accurate TIMS Measurements of Uranium in Ultra-Trace Levels

  • Park, Jong-Ho;Choi, In-Hee;Song, Kyu-Seok
    • Mass Spectrometry Letters
    • /
    • v.1 no.1
    • /
    • pp.17-20
    • /
    • 2010
  • As background significantly affects measurement accuracy and a detection limit in determination of the trace amounts of uranium, it is necessary to minimize the impurities in the filaments used for thermal ionization mass spectrometry (TIMS). We have varied the degassing condition such as the heating currents and duration times to reduce the backgrounds from the filaments prepared with zone-refined rhenium tape. The most efficient degassing condition of the heating current and the duration time was determined as 3.5 A and 60 min, respectively. The TIMS measurement combined with the isotope dilution mass spectrometry (IDMS) technique showed that the uranium backgrounds were determined to be in a few fg level from blank rhenium filaments. The background minimized filaments were utilized to measure the uranium isotope ratios of a U030 (NIST) standard sample. The excellent agreement of the measurement with the certified isotope ratios showed that the degassing procedure optimized in this study efficiently reduced the impurity signals of uranium from blank rhenium filaments to a negligible level.

Uranium Particle Identification with SEM-EDX for Isotopic Analysis by Secondary Ion Mass Spectrometry

  • Esaka, Fumitaka;Magara, Masaaki
    • Mass Spectrometry Letters
    • /
    • v.7 no.2
    • /
    • pp.41-44
    • /
    • 2016
  • Secondary ion mass spectrometry (SIMS) is a promising tool to measure isotope ratios of individual uranium particles in environmental samples for nuclear safeguards. However, the analysis requires prior identification of a small number of uranium particles that coexist with a large number of other particles without uranium. In the present study, this identification was performed by scanning electron microscopy - energy dispersive X-ray analysis with automated particle search mode. The analytical results for an environmental sample taken at a nuclear facility indicated that the observation of backscattered electron images with × 1000 magnification was appropriate to efficiently identify uranium particles. Lower magnification (less than × 500) made it difficult to detect smaller particles of approximately 1 μm diameter. After identification, each particle was manipulated and transferred for subsequent isotope ratio analysis by SIMS. Consequently, the isotope ratios of individual uranium particles were successfully determined without any molecular ion interference. It was demonstrated that the proposed technique provides a powerful tool to measure individual particles not only for nuclear safeguards but also for environmental sciences.

A Correction Method for the Peak Tailing Backgrounds for Accurate Isotope Ratio Measurements of Uranium in Ultra Trace Levels using Thermal Ionization Mass Spectrometry

  • Park, Jong-Ho;Choi, In-Hee;Park, Su-Jin;Lee, Myung-Ho;Song, Kyu-Seok
    • Bulletin of the Korean Chemical Society
    • /
    • v.32 no.12
    • /
    • pp.4327-4331
    • /
    • 2011
  • A new method in thermal ionization mass spectrometry (TIMS) was developed to correct peak tailing backgrounds in the isotope ratio measurements of uranium in ultra trace levels for higher accuracy. Two different uranium standard reference materials (U005 and U030) were used to construct databases of signal intensities at mass 234 u and mass 236 u, which correspond to the two uranium minor isotopes, and signal intensity of $^{238}U$. Correlations between peak tailing backgrounds and $^{238}U$ were obtained by least-squares regression on calculated backgrounds at mass 234 u and mass 236 u with respect to the signal intensity of $^{238}U$ followed by separation of the peak tails of the two major isotopes of uranium ($^{235}U$ and $^{238}U$), which enables us to obtain a master equation for peak tailing background correction on all kinds of samples. Verification of the correction method was carried out using U010 and IRMM-040a.

Isotope Measurement of Uranium at Ultratrace Levels Using Multicollector Inductively Coupled Plasma Mass Spectrometry

  • Oh, Seong-Y.;Lee, Seon-A.;Park, Jong-Ho;Lee, Myung-Ho;Song, Kyu-Seok
    • Mass Spectrometry Letters
    • /
    • v.3 no.2
    • /
    • pp.54-57
    • /
    • 2012
  • Mass spectrometric analysis was carried out using multicollector inductively coupled plasma mass spectrometry (MC-ICP-MS) for the precise and accurate determination of the isotope ratios of ultratrace levels of uranium dissolved in 3% $HNO_3$. We used the certified reference material (CRM) 112-A at a trace level of 100 pg/mL for the uranium isotopic measurement. Multiple collectors were utilized for the simultaneous measurement of uranium isotopes to reduce the signal uncertainty due to variations in the ion beam intensity over time. Mass bias correction was applied to the measured U isotopes to improve the precision and accuracy. Furthermore, elemental standard solution with certified values of platinum, iridium, gold, and thallium dissolved in 3% $HNO_3$ were analyzed to investigate the formation rates of the polyatomic ions of $Ir^{40}$ $Ar^+$, $Pt^{40}$ $Ar^+$, $Tl^{40}$ $Ar^+$, $Au^{40}$ $Ar^+$ for the concentration range of 50-400 pg/mL. Those polyatomic ions have mass-to-charge ratios in the 230-245 m/z region that it would contribute to the increase of background intensity of uranium, thorium, plutonium, and americium isotopes. The effect of the polyatomic ion interference on uranium isotope measurement has been estimated.

A study of activity ratios of uranium isotope in the groundwater using liquid scintillation counter (액체섬광계수기를 이용한 지하수 내 우라늄 동위원소 측정법에 관한 연구)

  • Cho, Soo-Young;Song, Kyung-Sun;Lee, Kil-Yong;Yoon, Yoon-Yeol;Kim, Won-Baek;Ko, Kyung-Sok
    • Analytical Science and Technology
    • /
    • v.25 no.2
    • /
    • pp.146-151
    • /
    • 2012
  • An analytical method was developed for the measurement of uranium isotope in ground water using the liquid scintillation counting technique. A LKB Wallac Quantulus 1220 liquid scintillation counter (LSC) equipped with pulse shape analyzer (PSA) and a solvent extraction method were used for the measurement of uranium isotope in ground water samples. The effect of solution volume on the extraction efficiency was evaluated for 100 to 1000 mL solutions using a NIST standard reference material (NIST SRM 4321C). The effect of groundwater pH on the extraction efficiency was also investigated for pH ranging from 0.5 to 10. It was found that the extraction efficiency had a strong dependence on pH showing a maximum at pH 2. In contrast, the effect of groundwater volume on the extraction efficiency was negligible in the range investigated. According to the method, the extraction efficiency of uranium isotopes was near 96% and the lower detection limit for uranium was 0.018 Bq/L with the counting time of 300 min. The result of this study was also verified by the conventional ICP-MS measurement. It is demonstrated that the suggested method is valuable to the determination of the optimum extraction and measurement conditions for uranium in ground water. The method was successfully applied to the ground water at four locations near the Daejeon province. It was found that the uranium content and the isotopic ratio of $^{234}U/^{238}U$ at the locations ranged 0.59~6.69 Bq/L and 0.72~1.40, respectively.