• Title/Summary/Keyword: Isothermal absorption

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Effective Absorption Capacity of Highly Absorptive Materials using Isothermal Calorimetry, Considering the Effect of Specific Surface Area (등온열량계를 사용한 고흡수성 재료의 유효흡수율 측정: 비표면적의 영향)

  • Lee, Bo Yeon
    • Journal of the Architectural Institute of Korea Structure & Construction
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    • v.34 no.2
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    • pp.49-56
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    • 2018
  • The use of highly absorptive materials in cement-based materials is increasing for internal curing purpose. However, calculation of correct absorption capacity of such materials is not easy, which leads to change in the effective water-to-cement ratio of cement paste by either absorbing or releasing water. In this study, effective absorption capacity of a highly absorptive material was found using isothermal calorimetry. Moreover, the effect of specific surface area was investigated. It was found that the method was capable of finding effective water absorption capacity of activated carbon fiber. For the activated carbon fiber used in this research, the effect of specific surface area was negligible because the high BET surface area was due to micropores less than 1nm, which does not affect the rate of hydration curve. Thus, the effective absorption capacity of such materials can be found successfully using this method.

Absorption Characteristics of Soybean curd Powder by Drying Methods (건조방법에 따른 건조분말두부의 흡습특성)

  • Kim Jin-Sung;Kim Jun-Han;Ha Young-Sun
    • Food Science and Preservation
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    • v.12 no.1
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    • pp.54-61
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    • 2005
  • The absorption characteristics and their physical properties of hot air, vacuum and freeze dried soybean curd powder were investigated. Absorption conditions were at 5, 15, and 25 t with $0.11\~0.93$ water activities. Equilibrium moisture content and the monolayer moisture content determined by prediction models showed highest value in the freeze dried soybean curd powder due to porous structure. Absorption energy decreased with increasing water activity was not affected by drying method. In the comparisons of the isothermal absorption models, Oswin model generally was the best fit model for isothermal adsorption of soybean curd powder.

Study on Regrouping of Gray Gases in spectral WSGGM for Arbitrary Mixtures of CO2 and H2O Gases (이산화탄소-수증기 혼합가스에 대한 파장별 회색가스가중합법에서 회색가스재조합에 대한 연구)

  • Park, Won-Hee;Kim, Tae-Kuk
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.27 no.2
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    • pp.227-235
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    • 2003
  • The WSGG-based narrow band model was employed to solve the radiative transfer equations along isothermal and non-isothermal paths through $CO_2-H_2O-N_2$ gas mixtures at 1 atm. When the WSGGM is applied for arbitrary gas mixtures by considering the multiplication property of transmissivity in overlapping bands, the number of gray gases is significantly increased. To reduce the computation time, three different regrouping methods for the gray gases are tested in obtaining the mean absorption coefficient for each gray gas group. Among them, the regrouping method by minimizing the regrouping error shows the best results. For the isothermal media, 10 gray gases show fairly good agreement with the results by statistical narrow band(SNB) model which are regarded as reference solutions. For non-isothermal media, 20 gray gases show good agreement with reference solutions.

Dyeing Properties and Functionality of Hot-water Extract from Juniperus chinensis Heartwood (향나무 심재 열수추출물의 염색성과 기능성)

  • Nam, Ki Yeon;Lee, Jung Soon
    • Textile Coloration and Finishing
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    • v.25 no.3
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    • pp.181-193
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    • 2013
  • The purpose of this study is to investigate dyeing properties and functionality of cotton and silk fabrics dyed with hot-water extract from Juniperus chinensis heartwood. Water-soluble dye of Juniperus chinensis heartwood extracted with distilled water was expressed YR color series. Dye uptake of cotton continued to increase according to the increase of the dye concentration. Its variation trends were shown to be similar to the isothermal absorption curve of the Freundlich. Dye uptake of silk was better than cotton, increased depending on increasing concentration of the dye, dyeing time and temperature. Its variation trends were shown to be similar to the isothermal absorption curve of the Langmuir. As the pH increased, the dye uptake of fabrics reduced and showed increased on red tinge. Colors of the dyed fabrics were various, depending on dye concentration and the mordant type and mordant concentration. Washing fastness, light fastness and perspiration fastness were not good. However, rubbing and dry cleaning fastness showed relatively good grade. Dyed fabrics of ultraviolet-cut ability and deodorant ability were improved. And dyed fabrics showed antimicrobial abilities of 99.9% against Staphylococcus aureus.

Non-isothermal Crystallization Behaviors of Ethylene-Tetrafluoroethylene Copolymer (에틸렌-테트라플르오르에틸렌 공중합체의 비등온 결정화 거동)

  • Lee, Jaehun;Kim, Hyokap;Kan, Ho-Jong
    • Polymer(Korea)
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    • v.36 no.6
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    • pp.803-809
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    • 2012
  • The non-isothermal crystallization behavior of ethylene-tetrafluoroethylene (ETFE) copolymer was investigated by DSC and imaging FTIR analysis. Modified non-isothermal Avrami analysis was applied to interpret the crystallization behavior of ETFE. It was found that the less linearity in ln[-ln(1-X(t))] vs. ln(t) plot was obtained in thermal analysis comparison with imaging FTIR due to relatively small crystallization enthalpy change in ETFE. It means that imaging FTIR measured by overall IR absorption intensity change due to the crystallization was found to be effective to understand the non-isothermal crystallization kinetics of ETFE. In addition, the optical transmittance of ETFE was studied. The crystallite developed by slow cooling caused the light scattering and resulted in the increase of haze and the lowering of transmittance up to 8%. From our results, it was confirmed that cooling rate is an important processing parameter for maintaining optical transmittance of ETFE as a replacement material for glass.

Crystallization Mechanism of Lithium Dislicate Glass with Various Particle Sizes (Lithium disilicate 유리의 입자크기에 따른 결정화 기구)

  • Choi, Hyun Woo;Yoon, Hae Won;Yang, Yong Suk;Yoon, Su Jong
    • Korean Journal of Materials Research
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    • v.26 no.1
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    • pp.54-60
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    • 2016
  • We have investigated the crystallization mechanism of the lithium disilicate ($Li_2O-2SiO_2$, LSO) glass particles with different sizes by isothermal and non-isothermal processes. The LSO glass was fabricated by rapid quenching of melt. X-ray diffraction and differential scanning calorimetry measurements were performed. Different crystallization models of Johnson-Mehl-Avrami, modified Ozawa and Arrhenius were adopted to analyze the thermal measurements. The activation energy E and the Avrami exponent n, which describe a crystallization mechanism, were obtained for three different glass particle sizes. Values of E and n for the glass particle with size under $45{\mu}m$, $75{\sim}106{\mu}m$, and $125{\sim}150{\mu}m$, were 2.28 eV, 2.21 eV, 2.19 eV, and ~1.5 for the isothermal process, respectively. Those values for the non-isothermal process were 2.4 eV, 2.3 eV, 2.2 eV, and ~1.3, for the isothermal process, respectively. The obtained values of the crystallization parameters indicate that the crystallization occurs through the decreasing nucleation rate with a diffusion controlled growth, irrespective to the particle sizes. It is also concluded that the smaller glass particles require the higher heat absorption to be crystallized.

Experimental study on the consolidation of saturated silty clay subjected to cyclic thermal loading

  • Bai, Bing;Shi, Xiaoying
    • Geomechanics and Engineering
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    • v.12 no.4
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    • pp.707-721
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    • 2017
  • The objective of this paper is to experimentally study the consolidation of saturated silty clay subjected to repeated heating-cooling cycles using a modified temperature-controlled triaxial apparatus. Focus is placed on the influence of the water content, confining pressure, and magnitudes and number of thermal loading cycles. The experimental results show that the thermally induced pore pressure increases with increasing water content and magnitude of thermal loading in undrained conditions. After isothermal consolidation at an elevated temperature, the pore pressure continues to decrease and gradually falls below zero during undrained cooling, and the maximum negative pore pressure increases as the water content decreases or the magnitude of thermal loading increases. During isothermal consolidation at ambient temperature after one heating-cooling cycle, the pore pressure begins to rise due to water absorption and finally stabilizes at approximately zero. As the number of thermal loading cycles increases, the thermally induced pore pressure shows a degrading trend, which seems to be more apparent under a higher confining pressure. Overall, the specimens tested show an obvious volume reduction at the completion of a series of heating-cooling cycles, indicating a notable irreversible thermal consolidation deformation.

Control of Working Temperature of Isothermal Magnetic Entropy Change in La0.8Nd0.2(Fe0.88Si0.12)13 by Hydrogen Absorption for Magnetic Refrigerants

  • Fujieda, S.;Fujita, A.;Fukamichi, K.;Suzuki, S.
    • Journal of Magnetics
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    • v.18 no.2
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    • pp.150-154
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    • 2013
  • $La_{1-z}Nd_z(Fe_{0.88}Si_{0.12})_{13}$ and their hydrides were investigated to obtain large magnetocaloric effects (MCEs) in a wide temperature range, including room temperature, for applications in magnetic refrigents. Since the magnetization change due to the itinerant-electron metamagentic (IEM) transition for $La_{1-z}Nd_z(Fe_{0.88}Si_{0.12})_{13}$ becomes larger with increasing z, the isothermal magnetic entropy change ${\Delta}S_m$ and the relative cooling power (RCP) are enhanced. In addition, the Curie temperatrue $T_C$ of $La_{0.8}Nd_{0.2}(Fe_{0.88}Si_{0.12})_{13}$ is increased from 193 to 319 K by hydrogen absorption, with the IEM transition. The maximum value of $-{\Delta}S_m$, $-{\Delta}S{_m}^{max}$, in a magnetic field change of 2 T for $La_{0.8}Nd_{0.2}(Fe_{0.88}Si_{0.12})_{13}H_{1.1}$ is about 23 J/kg K at $T_C$ = 288 K, which is larger than that of 19 J/kg K at $T_C$ = 276 K for $La(Fe_{0.88}Si_{0.12})_{13}H_{1.0}$. The value of RCP = 179 J/kg of the former is also larger than 160 J/kg of the latter. It is concluded that the partial substitution of Nd improves MCEs in a wide temperautre range, including room temperature.

Absorption Characteristics of Persimmon Powder Depending on Temperature Changes and Drying Methods (건조방법과 온도변화에 따른 감 분말의 흡습특성)

  • 이원영;김종국
    • Journal of the East Asian Society of Dietary Life
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    • v.11 no.6
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    • pp.479-484
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    • 2001
  • The absorption characteristics of persimmon powder related to different drying methods and various storage temperatures was investigated. The physical properties of persimmon powder by different drying methods displayed the largest amount of porosity in the freeze-dried sample, and the smallest in hot air dried sample. Equilibrium moisture was reached in 6 days. Monolayer moisture contents were predicted to 0.09687~0.19712(freeze drying), 0.07820~0.18617(vacuum drying) and 0.07715~0.18056(hot air drying) g H2O/g solid respectively using the BET equation. BET equation for isothermal absorption curve showed over 0.95 R-square for all dried methods. Monolayer moisture contents were increased as storage temperature was incremented because water molecular movement was more active and there was a greater chance to clash with the absorption surface area.

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Absorption Characteristics of Korean Yam Powder by Different Drying Methods (건조방법에 따른 분말마의 흡습특성)

  • 차원섭;박준희;오상룡;조영제;이원영
    • Journal of Life Science
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    • v.10 no.3
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    • pp.229-235
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    • 2000
  • The absorption characteristics of Korean yam powder according to different drying methods were investigated. The physical properties of yam powder by different drying methods were showed the biggest porosity in freeze drying sample, while the smallest in hot air drying sample. No difference was founded in proximate compositions of yam powder by various drying methods. The amount of total phenolic compound and Vit C were showed the bigger decrement in freeze dried sample than other drying methods. The time reaching to equilibrium moisture content were determined in 12 days. Monolayer moisture contents were predicted to 0.0508∼0.0588 by BET equation and 0.0705∼0.0811 g H2O/g solid by GAB equation. BET equation for isothermal absorption curve showed over 0.95 R-square for every drying methods. GAB equation showed over 0.99 in vacuum and freeze drying but a poor R-square in hot air drying.

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