• Title/Summary/Keyword: Isothermal Model

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Synthesis and Non-Isothermal Crystallization Behaviors of Maleic Anhydride onto High Density Polyethylene

  • Ahn, Youngjun;Jeon, Jong Hyuk;Baek, Chul Seoung;Yu, Young Hwan;Thenepalli, Thriveni;Ahn, Ji Whan;Han, Choon
    • Journal of the Korean Ceramic Society
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    • v.53 no.1
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    • pp.24-33
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    • 2016
  • The grafting reaction for maleic anhydride (MA) onto high density polyethylene (HDPE) was investigated from solution process with initiators. The chemical modification of neat HDPE was carried out with various contents of MA (3-21 wt.%) and initiator (0.2-1 wt.%) at different temperature ($80-130^{\circ}C$). The grafting degree was obtained from the titration and the highest grafting degree was 3.1%. The grafting degree increased as the content of MA and initiator increased, however, the highest grafting degree was demonstrated for a particular content of MA and initiator. In the non-isothermal crystallization kinetics, the Ozawa model was unsuitable method to investigate the crystallization behavior of MA onto HDPE, whereas the Avrami and Liu models found effective. The crystallization rate was accelerated as the cooling rate increased, but postponed by combination of MA onto neat HDPE backbone.

EFFECTS OF PROCESS PARAMETERS ON GRAIN SIZE DURING ISOTHERMAL FORGING OF A TC6 ALLOY

  • Miaoquan LI;Aiming XIONG;Shankun XUE;Yuanchun LI;Hai LIN;Hairong WANG;Shaobo SU;Lichuang SHEN
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2003.10b
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    • pp.47-50
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    • 2003
  • Grain size of the $\alpha$ phase is computed during isothermal forging of the TC6 aerofoil blade, by combining FE with the Yada's model of grain size. The present results illustrate the grain size and distribution of the $\alpha$ phase during isothermal forging of the TC6 aerofoil blade' in detail. The computed results show that height reduction, deformation temperature, hammer velocity and friction have significant effect on distribution of the equivalent strain, and that height reduction, deformation temperature and hammer velocity have more significant effect on grain size of the $\alpha$ phase than friction between billet and die.

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Process Design of Isothermal Forging for Three-Dimensional Ti-6Al-4V Wing-Shape (Ti-6Al-4V 합금 3D 날개형상의 항온단조 공정설계)

  • Yeom J. T.;Park N. K.;Lee Y. H.;Shin T. J.;Hong S. S.;Shim I. O.;Hwang S. M.;Lee C. S.
    • Transactions of Materials Processing
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    • v.14 no.2 s.74
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    • pp.126-132
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    • 2005
  • The isothermal forging design of a Ti-6Al-4V wing shape was performed by 3D FE simulation. The design focuses on near-net shape forming by the single stage. The process variables such as the die design, pre-form shape and size, ram speed and forging temperature were investigated. The main design priorities were to minimize forging loads and to distribute strain uniformly in a given forging condition. The FE simulation results for the final process design were compared with the isothermal forging tests. The instability of deformation was evaluated using a processing map based on the dynamic materials model(DMM), including flow stability criteria. Finally, a modified process design for producing a uniform Ti-6Al-4V wing product without forming defects was suggested.

Evaluation of early age mechanical properties of concrete in real structure

  • Wang, Jiachun;Yan, Peiyu
    • Computers and Concrete
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    • v.12 no.1
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    • pp.53-64
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    • 2013
  • The curing temperature is known to influence the rate of mechanical properties development of early age concrete. In realistic sites the temperature of concrete is not isothermal $20^{\circ}C$, so the paper measured adiabatic temperature increases of four different concretes to understand heat emission during hydration at early age. The temperature-matching curing schedule in accordance with adiabatic temperature increase is adopted to simulate the situation in real massive concrete. The specimens under temperature-matching curing are subjected to realistic temperature for first few days as well as adiabatic condition. The mechanical properties including compressive strength, splitting strength and modulus of elasticity of concretes cured under both temperature-matching curing and isothermal $20^{\circ}C$ curing are investigated. The results denote that comparing temperature-matching curing with isothermal $20^{\circ}C$ curing, the early age concretes mechanical properties are obviously improved, but the later mechanical properties of concretes with pure Portland and containing silica fume are decreased a little and still increased for concretes containing fly ash and slag. On this basement using an equivalent age approach evaluates mechanical properties of early age concrete in real structures, the model parameters are defined by the compressive strength test, and can predict the compressive strength, splitting strength and elasticity modulus through measuring or calculating by finite element method the concreted temperature at early age, and the method is valid, which is applied in a concrete wall for evaluation of crack risking.

A Study on Ventilation Effectiveness in the Non-isothermal Supply using Mixing and Displacement Ventilation Systems (비등온 급기조건에서 환기방식에 따른 환기효율 특성에 관한 연구)

  • 이재근;강태욱;윤석구;구재현;한정균;조민철
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.13 no.8
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    • pp.739-745
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    • 2001
  • The objective of this research is to analyze the ventilation effectiveness in the non-isothermal air supply using mixing and displacement ventilation systems for indoor air quality control and management. In this study, a ventilation effectiveness is evaluated in a simplified model chamber using a tracer gas technique of $CO^2$ gas injected into a supply duct as a function of ventilation rates, supply/extract sites and cooling/heating air supply. The ventilation effectiveness decreased with increasing ventilation rate on the cooling and heating conditions. And the ventilation effectiveness of case 3 (down supply and upper extract) was better thant that of case 1(upper supply and upper extract) and case 2(upper supply and down extract) with the cooling supply conditions. but for the heating supply air conditions, the ventilation effectiveness of case 2 was better than that of case 3 and case 1.

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Cure Behavior of a DGEBF Epoxy using Asymmetric Cycloaliphatic Amine Curing Agent (비대칭 고리형 지방족 아민 경화제를 이용한 DGEBF 계열 에폭시의 경화 거동)

  • Kim, Hongkyeong
    • Korean Chemical Engineering Research
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    • v.46 no.1
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    • pp.200-204
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    • 2008
  • The curing kinetics of diglycidyl ether of bisphenol F (DGEBF) with an asymmetric cycloaliphatic amine curing agent were examined by thermal analysis in both isothermal and dynamic curing conditions. From the residual curing of the samples partially cured in isothermal condition and from the dynamic curing with various heating rates, it was found that there exist two kinds of reactions such as at low temperature and at high temperature regions. It was thus also found that the cure parameters obtained from the isothermal curing kinetic model hardly estimate experimental results for a degree of cure larger than 0.6. The activation energies and frequency factors of these two kinds of reactions were obtained from the dynamic curing experiments with various heating rates. From the curing analysis, it was verified that the total cure kinetics for low degrees of cure is dominated by the cure reaction in the low temperature region.

DENSITY STRUCTURE AND STABILITY OF THE SUBCOMPONENTS IN GIANT MOLECULAR CLOUD COMPLEXES

  • Yoo, Chin-Woo;Hong, Seung-Soo
    • Journal of The Korean Astronomical Society
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    • v.19 no.1
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    • pp.33-49
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    • 1986
  • Radial distribution of internal density has been determined for thirteen subclouds in the three giant molecular cloud complexes accompanying Mon OB1, Mon OB2 and CMa OB1 associations, We modeled their radial density structures with the density distribution of isothermal gas spheres. Most of the subclouds, nine out of the thirteen, are well described by isothermal spheres of single component; while the rest four require an additional component. Total mass and potential energy of each subcloud are also derived from the radial density structure; thermal energy and internal velocity dispersion required for sustaining the density structure are deduced from the isothermal gas model. Our derived masses of the clouds are comparable to the values determined by Blitz (1978) under LTE assumption. This agreement suggests that the correction factor for non-LTE effect on mass-estimate is not far from unity. The ratio of the gravitational potential energy to the kinetic energy of thermal motion is as large as 250; hence the thermal motion alone cannot support these clouds against the gravity. Being supported by turbulence motion with velocities of six to seven times the thermal velocity, the clouds of one-component type seem to be in equilibrium with the gravity; while the clouds of two-component type are likely to be in the stage of gravitational collapse.

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The wave stability of the nonparallel natural convection flows adjacent to an inclined isothermal surface submerged in water at $4degC$ ($4degC$ 물에 잠겨있는 경사진 등온 벽주위 비평행 자연대류의 파형 안정성)

  • 황영규;장명륜
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.15 no.2
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    • pp.644-653
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    • 1991
  • A wave instability problem is formulated for natural convection flows adjacent to a inclined isothermal surface in pure water near the density extremum. It accounts for the nonparallelism of the basic flow and temperature fields. Numerical solutions of the hydrodynamic stability equations constitute a two-point boundary value problem which are accurately solved using a computer code COLSYS. Neutral stability results for Prandtl number of 11.6 are obtained for various angles of inclination of a surface in the range from-10 to 30 deg. The neutral stability curves are systematically shifted toward modified Grashof number G=0 as one proceeds from downward-facing inclined plate(.gamma.<0.deg.) to upward-facing inclined plate (.gamma.>0.deg.). Namely, an increase in the positive angle of inclination always cause the flows to be significantly more unstable. The present results are compared with the results for the parallel flow model. The nonparallel flow model has, in general, a higher critical Grashof number than does the parallel flow model. But the neutral stability curves retain their characteristic shapes.

Prediction Model for the Microstructure and Properties in Weld Heat Affected Zone: V. Prediction Model for the Phase Transformation Considering the Influence of Prior Austenite Grain Size and Cooling Rate in Weld HAZ of Low Alloyed Steel (용접 열영향부 미세조직 및 재질 예측 모델링: V. 저합금강의 초기 오스테나이트 결정립크기 및 냉각 속도의 영향을 고려한 용접 열영향부 상변태 모델)

  • Kim, Sang-Hoon;Moon, Joon-Oh;Lee, Yoon-Ki;Jeong, Hong-Chul;Lee, Chang-Hee
    • Journal of Welding and Joining
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    • v.28 no.3
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    • pp.104-113
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    • 2010
  • In this study, to predict the microstructure in weld HAZ of low alloyed steel, prediction model for the phase transformation considering the influence of prior austenite grain size and cooling rate was developed. For this study, six low alloyed steels were designed and the effect of alloying elements was also investigated. In order to develop the prediction model for ferrite transformation, isothermal ferrite transformation behaviors were analyzed by dilatometer system and 'Avrami equation' which was modified to consider the effect of prior austenite grain size. After that, model for ferrite phase transformation during continuous cooling was proposed based on the isothermal ferrite transformation model through applying the 'Additivity rule'. Also, start temperatures of ferrite transformation were predicted by $A_{r3}$ considering the cooling rate. CCT diagram was calculated through this model, these results were in good agreement with the experimental results. After ferrite transformation, bainite transformation was predicted using Esaka model which corresponded most closely to the experimental results among various models. The start temperatures of bainite transformation were determined using K. J. Lee model. Phase fraction of martensite was obtained according to phase fractions of ferrite and bainite.

Three-Dimensional Thermohydrodynamic Analysis of Journal Bearings Operating in Turbulent Region Using $kappa-varepsilon$ Model (난류상태로 운전되는 저어널베어링에서의 $kappa-varepsilon$ 모델을 이용한 3-차원 THD해석)

  • 이득우;김경웅
    • Tribology and Lubricants
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    • v.3 no.1
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    • pp.39-46
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    • 1987
  • Frictional loss in turbulent regime is abnormally increased compared with in laminar regime. Thus the consideration of temperature rise across fluid film is significant in analysis and conventional isothermal theory loses its usefulness for performance prediction. This paper proposes to the three-dimensional thermohydrodynamic analysis of finite journal bearings operating under turbulent condition using two-equation model($\kappa-\varepsilon$ model) proposed by Hassid & Poreh. The equations are solved numerically by finite difference method. We make the analysis applicable even at large eccentricity when back flow of the lubricants occurs and axial flow is no longer ignored compared to circumferential flow.