• Title/Summary/Keyword: Irreversible degradation

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Transport and Degradation of Benzene affected by Hydrogen Peroxide and Microorganism in a Sandy Soil (사질토양에서의 과산화수소 및 미생물에 의한 Benzene의 이동 및 분해특성)

  • 백두성;박춘화;김동주;김희성;이한웅;박용근
    • Journal of Soil and Groundwater Environment
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    • v.6 no.2
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    • pp.49-56
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    • 2001
  • Benzene, one of the aromatic hydrocarbons, can be degraded by physical, chemical and biological processes in aquifers. This study aimed at analyzing separately the three different forms of degradation by performing column tests. Column tests using KCl and benzene as tracers were conducted for four different cases: 1) no hydrogen peroxide and no microorganism, 2) hydrogen peroxide only; 3) microorganism only; 4) hydrogen peroxide and microorganism to investigate the sorption and degradation of benzene. The observed BTCs of KCl and benzene in all cases showed that the arrival times of the peaks of both tracers coincided well but the peak concentration of benzene was much lower than that of KCl. This reveals that a predominant process affecting the transport of benzene in a sandy soil is an irreversible sorption and/or degradation rather than retardation. Decay of benzene through sorption and degradation increased with the addition of hydrogen peroxide and/or microorganism. Dissolved oxygen decreased with the increase of benzene in all cases indicating that degradation of benzene was also influenced by dissolved oxygen. For BTCs with the addition of microorganisms (case 3 and case 4), microorganism showed much lower concentrations compared to the initial levels and an increasing tendency with time although concentrations of benzene returned to zero, indicating a possible retardation of microorganism due to reversible and irreversible sorption to the particle surfaces.

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Study on stiffness deterioration in steel-concrete composite beams under fatigue loading

  • Wang, Bing;Huang, Qiao;Liu, Xiaoling;Ding, Yong
    • Steel and Composite Structures
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    • v.34 no.4
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    • pp.499-509
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    • 2020
  • The purpose of this paper is to investigate the degradation law of stiffness of steel-concrete composite beams after certain fatigue loads. First, six test beams with stud connectors were designed and fabricated for static and fatigue tests. The resultant failure modes under different fatigue loading cycles were compared. And an analysis was performed for the variations in the load-deflection curves, residual deflections and relative slips of the composite beams during fatigue loading. Then, the correlations among the stiffness degradation of each test beam, the residual deflection and relative slip growth during the fatigue test were investigated, in order to clarify the primary reasons for the stiffness degradation of the composite beams. Finally, based on the stiffness degradation function under fatigue loading, a calculation model for the residual stiffness of composite beams in response to fatigue loading cycles was established by parameter fitting. The results show that the stiffness of composite beams undergoes irreversible degradation under fatigue loading. And stiffness degradation is associated with the macrobehavior of material fatigue damage and shear connection degradation. In addition, the stiffness degradation of the composite beams exhibit S-shaped monotonic decreasing trends with fatigue cycles. The general agreement between the calculation model and experiment shows good applicability of the proposed model for specific beam size and fatigue load parameters. Moreover, the research results provide a method for establishing a stiffness degradation model for composite beams after fatigue loading.

A Constitutive Model for Plastic Damage of Ductile Materials

  • Nho, In-Sik;Yim, Sahng-Jun;Shin, Jong-Gye
    • Selected Papers of The Society of Naval Architects of Korea
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    • v.2 no.1
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    • pp.106-128
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    • 1994
  • An elasto-plastic-damage constitutive model for ductile materials is proposed within the framework of a thermodynamic approach of continuum damage mechanics (CDM) in which internal irreversible thermodynamic changes of micro-structure of materials such as plastic deformation and damage evolution are considered as thermodynamic state variables. The new constitutive model can predict not only the elasto-plastic behaviors but also the sequential stiffness degradation process of ductile materials more rationally.

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A Viscoelastic Study of Glass Transition and Degradation Processes of Phenolic Resin/Carbon Fiber Composites (페놀수지/탄소섬유 열경화성 복합재료의 유리전이와 고온 분해과정에서 관찰되는 점탄성 특성 연구)

  • ;J. C. Seferis
    • The Korean Journal of Rheology
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    • v.11 no.1
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    • pp.9-17
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    • 1999
  • Viscoelastic characteristics of cured phenolic resin/carbon fiber composite materials were investigated through glass transition and degradation reaction processes in the high temperature region up to $400^{\circ}C$. A typical glass transition of the cross-linked thermoset polymer was followed by irreversible degradation reactions, which were exhibited by the increasing storage modulus and loss modulus peak. A degradation master curve was constructed by using the vertical and horizontal shift factors, both of which complied well with the Arrhenius equation in light of the kinetic expression of degradation rate constants. Using an analogy to the Havriliak-Negami equation in dielectric relaxation phenomena, a viscoelastic modeling methodology was developed to characterize the frequency- and temperature-dependent complex moduli of the degrading thermoset polymer composite systems. The temperature-dependent relaxation time of the degrading composites was determined in a continuous fashion and showed a minimum relaxation time between the glass transition and degradation reaction regions. The capability of the developed modeling methodology was demonstrated by describing the complex behavior of the viscoelastic complex moduli of reacting phenolic resin composite systems.

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Numerical simulation of concrete slab-on-steel girder bridges with frictional contact

  • Lin, Jian Jun;Fafard, Mario;Beaulieu, Denis
    • Structural Engineering and Mechanics
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    • v.4 no.3
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    • pp.257-276
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    • 1996
  • In North America, a large number of concrete old slab-on-steel girder bridges, classified noncomposite, were built without any mechanic connections. The stablizing effect due to slab/girder interface contact and friction on the steel girders was totally neglected in practice. Experimental results indicate that this effect can lead to a significant underestimation of the load-carrying capacity of these bridges. In this paper, the two major components-concrete slab and steel girders, are treat as two deformable bodies in contact. A finite element procedure with considering the effect of friction and contact for the analysis of concrete slab-on-steel girder bridges is presented. The interface friction phenomenon and finite element formulation are described using an updated configuration under large deformations to account for the influence of any possible kinematic motions on the interface boundary conditions. The constitutive model for frictional contact are considered as slip work-dependent to account for the irreversible nature of friction forces and degradation of interface shear resistance. The proposed procedure is further validated by experimental bridge models.

Fracture Analysis of Concrete using Plastic-Damage Model (소성-손상 모델을 이용한 콘크리트의 파괴해석)

  • 남진원;송하원;김광수
    • Proceedings of the Computational Structural Engineering Institute Conference
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    • 2004.10a
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    • pp.534-541
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    • 2004
  • The modeling of crack initiation and propagation is very important for the failure analysis of concrete. The cracking process in concrete is quite different from that of other materials, such as metal and glass, in that it is not a sudden onset of new free surface but a continuous forming and connecting of microcracks. The failure process of concrete by cracking causes irreversible deformations and stiffness degradation. Those phenomenon can be modeled using plasticity and damage theory in macroscopic aspect. In this study, a plastic-damage model based on homogenized crack model considering velocity discontinuity and damage variable which is a function of plastic strain is proposed for fracture analysis of concrete. Finally, the plastic-damage model is verified with experimental data.

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Direct-Current Based Remedial Technologies for Contaminated Soils and Groundwaters

  • Lee, Suk-Young;Lee, Chae-Young;Yoon, Jun-Ki;Kim, Kil-Hong
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2002.09a
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    • pp.3-6
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    • 2002
  • Electron transfer is the major natural process governing the behavior of contaminants in soils and groundwaters. Biological degradation of contaminants, i.e., microbial transformation of hazardous compounds, is a well known irreversible electron transfer process. Although it is not well defined as a separate process, abiotic electron-transfer is also an important process for mobilizing/demobilizing inorganic contaminants in soils and groundwaters. Therefore, numerous remedial technologies have been developed on the basis of electron transfer concept. Among them,

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A Study on Angiographgy Coding Using Subband-VQ (Subband-VQ를 이용한 심장조영상 부호화에 관한 연구)

  • Han, Young-Oh;Park, Hyun-Soo;Shin, Joong-In;Kim, Hyung-Suk;Park, Sang-Hui
    • Proceedings of the KOSOMBE Conference
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    • v.1993 no.05
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    • pp.33-37
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    • 1993
  • Medical imagies with high resolution are coded to be archived and communicated in MPACS. In this paper, we have studied on coding of Cardio-Angiography. Our coding technique is Subband-Vecter Quantization. This techniquec is irreversible coding method. This technique's advantages are removing blocking effect and edge degradation, adapting for drastic image change because of dye injection and fast decoding. We achieved good results fur Cardio-Angiography data, but the study on more sophiscated motion estimation techniques and VQ techniques must be performed.

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Constitutive Model for Plastic Damage of Ductile Materials (연성재료의 소성손상 구성방정식에 관한 연구)

  • I.S. Nho;S.J. Yim;J.G. Shin
    • Journal of the Society of Naval Architects of Korea
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    • v.29 no.4
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    • pp.179-192
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    • 1992
  • An elasto-plastic-damage constitutive model for ductile materials was derived under the framework of thermodynamic approach of contimuum damage mechanics(CDM) in which internal irreversible thermodynamic change of micro-structure of materials such as plastic deformation and damage evolution were considered as thermodynamic state variables. New constitutive model can predict not only the elasto-plastic behaviors but also the sequential degradation process of ductile materials more rationally.

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A Study on Angiographgy Coding (심장조영상 부호화에 관한 연구)

  • Park, Sang-Hui;Han, Young-Oh;Park, Hyun-Soo;Kim, Hyung-Suk;Shin, Joong-In
    • Journal of Biomedical Engineering Research
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    • v.14 no.2
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    • pp.177-183
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    • 1993
  • Medical imagies with high resolution are coded to be archived and communicated in MPACS. In this paper, we have studied on coding of Cardio-Angiography. Our coding technique is Subband-Vector Quantization. This techniques is irreversible coding method. This technique's advantages are removing blocking artifact and edge degradation, adapting for drastic image change because of dye injection, and fast decoding. We achieved good results for Cardio-Angiography data, but the study on more sophiscated motion estimation techniques and VQ techniques must be performed.

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