• Title/Summary/Keyword: Iron surface

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The Effect of Iron Oxides $(Fe_2O_3,\;Fe_3O_4)$ on Tribological Characteristics of Automotive Friction Materials (자동차용 마찰재에서 철산화물이 마찰특성에 미치는 영향에 관한 연구)

  • Cho KeunHyung;Jang Ho
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 2004.11a
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    • pp.289-295
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    • 2004
  • The relationship between friction characteristics and iron oxides at the sliding interface was investigated. Three friction materials containing iron, magnetite $(Fe_3O_4)$ or hematite $(Fe_2O_3)$ were manufactured and friction tests were performed on gray cast iron disks to evaluate the friction coefficient as a function of sliding speed $\mu-\nu$. In-situ noise spectrum analyzer was employed to compare noise propensity during friction tests. Results show that the specimens with magnetite are more sensitive to velocity than those with iron or hematite. The specimens containing magnetite and hematite generated noise with different peaks in the spectrum. The difference in the peak frequency seems attributed to the different surface aggressiveness of iron oxides and intermittent changes of real contact area at the sliding interface during sliding. Surface morphology and roughness of the counter disc after the tests are also consistent with the aggressiveness of iron oxides.

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ESTIMATION OF THE BEHAVIORS OF SELENIUM IN THE NEAR FIELD OF REPOSITORY

  • Kim, Seung-Soo;Min, Jae-Ho;Baik, Min-Hoon;Kim, Gye-Nam;Choi, Jong-Won
    • Nuclear Engineering and Technology
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    • v.44 no.8
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    • pp.945-952
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    • 2012
  • The sorption of selenium ions onto iron and iron compounds as a disposal container material and its corrosion products, and onto bentonite as a buffer material, was studied to understand the behaviors of selenium in a waste repository. Selenite was sorbed onto commercial magnetite very well in solutions at around pH 9, but silicate hindered their sorption onto both magnetite and ferrite. Unlike commercial magnetite and ferrite, flesh synthesized magnetite, green rust and iron greatly decreased selenium concentration even in a silicate solution. These results might be due to the formation of precipitates, or the sorption of selenide or selenite onto an iron surface at below Eh= -0.2 V. Red-colored Se(cr) was observed on the surface of a reaction bottle containing iron powder added into a selenite solution. Silicate influences on the sorption onto magnetite and iron for selenide are the same as those for selenite. Even though bentonite adsorbed a slight amount of selenite, the sorption cannot be ignored in the waste repository since a very large quantity of bentonite is used.

Microstructure investigation of iron artifacts excavated from Kkonmoe relic located in Suwon-si (수원시 꽃뫼 유적 출토 철제유물의 미세조직 분석)

  • Yu, Jae-Eun;Go, Hyeong-Sun;Lee, Jae-Sung
    • 보존과학연구
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    • s.23
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    • pp.131-147
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    • 2002
  • Kkonmoe relic located in Jangan-gu, Suwon-si, Gyeonggi-do Provinceis an example of the wide chronology from the Three Kingdoms Period to Joseon Dynasty. Examinations on a forged iron ax, a cast iron ax and an iron sickle excavated from this relic revealed the microstructure structure of the metal and the manufacturing technologies. Microstructure investigation was carried out with a metallurgical microscope and a Vickers hardness tester was used to measure the hardness of the micro structures. The test results show that the forged iron ax has a ferrite and pearlitestructure. It is made of low carbon steel and then carbonized to increase carbon content. After carbonization, the surface grains are reworked and the surface decarbonized. In case of the iron sickle, it is forged from low carbon steel, then carbonized and hardened, to increase overall strength. The sickle blade is carbonized and quenched after forging, resulting in afirm, solid blade. Heat treatment to remove brittleness is not applied to the cast ironartifact, which is manufactured by solidifing hypo-eutectic cast iron with a3-4% carbon content and white cast iron. All artifacts are produced from steel and subjected to a carbonization process. To increase hardness of the blade, additional heat treatment is applied.

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A study on the restoring method of the abrasives cylinder liner of cast iron using thermal plastic deformation technique (TPD법에 의해 재생된 실린더 라이너의 야금학적 고찰)

  • 이광렬;김종호;김영식
    • Proceedings of the Korean Society of Marine Engineers Conference
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    • 2002.05a
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    • pp.141-146
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    • 2002
  • The cast iron cylinder liner of the marine engine must be scrapped after its inner surface was definitely worn out due to the friction between the surface and piston ring during the operating. In this research, the restoring method of the worn out cast iron cylinder liner are discussed based on the results of experimental work of the thermal plastic deformation technique.

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The Wear charactericstics and Machinability to The type of Cast-iron of The Slot part of cylinder for Rotary compressor (로타리압축기 실린더 Slot부의 주조조직에 따른 가공표면 및 마모특성에 관한 연구)

  • 김동한
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 1998.04a
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    • pp.77-82
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    • 1998
  • The Part of slot on rotary compressor which plays an important part of the reliability and performance is studied on machinability and the wear characteristics for the specimen made by sand mold and permanent mold. The experiment are used the face cutter of milling machine which make the processing surface like broaching process and rollblock wear test machine. Permanent-mold casting iron is not affected by variation of RPM of milling machine, but sand-mold cast-iron is improved to increasing RPM. Also sand-mold casting iron shows superior wear characteristic to permanent-mold casting iron. This results from harder matrix of pearlite structure and self-lubrication characteristics of graphite. And wear particles in tested oil show shape and size similar to severe wear particles of oil taken from rotary compressor. The material and surface condition of slot play important part of the reliability and performance.

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A Study of Metal Technology in Ancient Silla Dynasity (고대신라의 금속기술 연구)

  • 강성군;조종수
    • Journal of the Korean institute of surface engineering
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    • v.8 no.1
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    • pp.1-9
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    • 1975
  • The crorosion film of gilt bronz, silver and iron objects, which were excaved from Ancient Tomb of Silla Dynasty, was removed by the electrolytic reduction process. These metallic objects were mainly investigated for microstructure, designs and gilting film etc. Most iron objects might be made by hot forging process. The cold extrusion technique might be used for gold and silver objects, in addition to an amalgam method might be applied for the gilting Au film on Cu-alloy surface. For the gilting on glass surface, first, a Cu alloy was cladded on glass , next, Au-film was obtained on the Cu-ally by the amagum method.

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The study of manganese removal mechanism in aeration-sand filtration process for treating bank filtered water (강변여과수 처리를 위한 포기-모래여과공정에서 망간제거 기작에 관한 연구)

  • Choi, Seung-Chul;Kim, Se-Hwan;Yang, Hae-Jin;Lim, Jae-Lim;Wang, Chang-Keun;Jung, Kwan-Sue
    • Journal of Korean Society of Water and Wastewater
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    • v.24 no.3
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    • pp.341-349
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    • 2010
  • It is well known that manganese is hard to oxidize under neutral pH condition in the atmosphere while iron can be easily oxidized to insoluble iron oxide. The purpose of this study is to identify removal mechanism of manganese in the D water treatment plant where is treating bank filtered water in aeration and rapid sand filtration. Average concentration of iron and manganese in bank filtered water were 5.9 mg/L and 3.6 mg/L in 2008, respectively. However, their concentration in rapid sand filtrate were only 0.11 mg/L and 0.03 mg/L, respectively. Most of the sand was coated with black colored manganese oxide except surface layer. According to EDX analysis of sand which was collected in different depth of sand filter, the content of i ron in the upper part sand was relatively higher than that in the lower part. while manganese content increased with a depth. The presence of iron and manganese oxidizing bacteria have been identified in sand of rapid sand filtration. It is supposed that these bacteria contributed some to remove iron and manganese in rapid sand filter. In conclusion, manganese has been simultaneously removed by physicochemical reaction and biological reaction. However, it is considered that the former reaction is dominant than the latter. That is, Mn(II) ion is rapidly adsorbed on ${\gamma}$-FeOOH which is intermediate iron oxidant and then adsorbed Mn(II) ion is oxidized to insoluble manganese oxide. In addition, manganese oxidation is accelerated by autocatalytic reaction of manganese oxide. The iron and manganese oxides deposited on the surface of the sand and then are aged with coating sand surface.

Corrosion Behavior of Galvanized Steels with Outdoor Exposure Test in Korea for 36 Months (36개월간 국내 옥외폭로시험에 따른 아연도강의 부식거동)

  • Kim, K.T.;Kim, Y.S.
    • Corrosion Science and Technology
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    • v.17 no.5
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    • pp.231-241
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    • 2018
  • Atmospheric corrosion is generally an electrochemical degradation process of metal. It can be caused by various corrosion factors of atmospheric component, weather, and air pollutants. Moisture, particles of sea salts, and sulfur dioxide are major factors in atmospheric corrosion. Galvanizing coating is one of the most efficient ways to protect iron from corrosion by zinc plating on the surface of the iron. Galvanized steels are being widely used in automobiles, building structures, roofing, and other industrial structures due to their high corrosion resistance compared to bare iron. Atmospheric corrosion of galvanized steel has shown complex corrosion behavior depending on coating process, coating thickness, atmospheric environment, and air pollutants. In addition, different types and kinds of corrosion products can be produced depending on the environment. Lifespan of galvanized steels is also affected by the environment. Therefore, the objective of this study was to determine the corrosion behavior of galvanized steel under atmospheric corrosion at six locations in Korea. When the exposure time was increased, content of zinc from GA surface decreased while contents of iron and oxygen tended to increase. On the other hand, content of iron was constant even after 36 months of exposure of GI.