• Title/Summary/Keyword: Iron scrap

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Study on the Distillation of Magnesium Alloy Scrap (마그네슘 합금 스크랩의 진공증류에 관한 연구)

  • Wi, Chang-Hyun;Yoo, Jung-Min;Jang, Byoung-Lok;You, Byoung-Don
    • Korean Journal of Metals and Materials
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    • v.46 no.1
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    • pp.13-19
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    • 2008
  • To develop a recycling process of magnesium alloy scrap, a fundamental study on the distillation of magnesium alloy melt was carried out. Melt temperature, vacuum degree and reaction time were considered as experimental variables. The amount of vaporized magnesium melt per unit surface area of melt increases with the increase of melt temperature, reaction time and vacuum degree. The vapor condensed at the tip of water cooling Cu-condenser as a form of pine cone. Magnesium and zinc were vaporized easily from the melt. However, It's difficult to separate magnesium and zinc by vacuum distillation because vapor pressure of zinc is similar to one of magnesium. The contents of aluminum, manganese and iron, etc. in residual melt increase due to the decrease of magnesium and zinc content after the distillation of magnesium alloy.

Development of a Methodology for Estimating Radioactivity Concentration of NORM Scale in Scrap Pipes Based on MCNP Simulation

  • Wanook Ji;Yoomi Choi;Zu-Hee Woo;Young-Yong Ji
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.21 no.4
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    • pp.481-487
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    • 2023
  • Concerning the apprehensions about naturally occurring radioactive materials (NORM) residues, the International Atomic Energy Agency (IAEA) and its member nations have acknowledged the imperative to ensure the radiation safety of NORM industries. Residues with elevated radioactivity concentrations are predominantly produced during NORM processing, in the form of scale and sludge, referred to as technically enhanced NORM (TENORM). Substantial quantities of TENORM residues have been released externally due to the dismantling of NORM processing factories. These residues become concentrated and fixed in scale inside scrap pipes. To assess the radioactivity of scales in pipes of various shapes, a Monte Carlo simulation was employed to determine dose rates corresponding to the action level in TENORM regulations for different pipe diameters and thicknesses. Onsite gamma spectrometry was conducted on a scrap iron pipe from the titanium dioxide manufacturing factory. The measured dose rate on the pipe enabled the estimation of NORM concentration in the pipe scale onsite. The derived action level in dose rate can be applied in the NORM regulation procedure for on-site judgments.

Development of Metal Recovery Process for Municipal Incineration Bottom Ash (MIBA)

  • Kuroki, Ryota;Ohya, Hitoshi;Ishida, Kazumasa;Yamazaki, Kenichi
    • Resources Recycling
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    • v.28 no.3
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    • pp.21-25
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    • 2019
  • The utilization of incineration ash from municipal waste must be promoted to solve the social problem on the shortage of final disposal site. In this research, metals should be recovered to avoid the damage of the crushing machine during the utilization of incineration ash in cement industry. In fact, incineration bottom ash from municipal waste contains iron in 3-5%. Nonferrous metal and stainless steel in 1% is also included. The research and development on the physical recovery process was performed not only to remove the metals but also to recover high grade products. Metals were separated from incineration ash in Maruya Co. Ltd.. In fact, iron scrap recovered by magnetic separation can be selled. After that, mixed metal was separated from incineration ash using screen. In this research, mixed metal tried to divided copper, aluminum, brass and stainless steel using drum type magnetic separation, eddy current separation and high magnetic separation. As a result, recovered iron had an 80% for the grade. Aluminum was recovered by eddy current separation without copper and brass.

Effect of Heat-treatment Temperature on the Physical Properties of Iron Oxide Nanoparticles Synthesized by Using Permanent Magnet Scrap (영구자석 스크랩으로 합성한 산화철 나노입자의 물성에 미치는 열처리 온도의 영향)

  • Hong, Sung-Jei;Hong, Sang Hyeok;Jo, Ajin;Kim, Young-Sung;Kim, ByeongJun;Yang, Suwon;Lee, Jae-Yong
    • Clean Technology
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    • v.28 no.2
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    • pp.110-116
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    • 2022
  • In this study, iron oxide (FeOx) nanoparticles were synthesized using iron (Fe) by-products recovered from NdFeB permanent magnet scraps, and the effect of heat-treatment temperature on the physical properties of the FeOx nanoparticles was investigated. In order to prepare the FeOx nanoparticles, 2.0 M ammonia (NH4OH) solution was added to an iron by-product solution diluted to c.a. 10 wt% in D.I. water, which led to the precipitation of the iron oxide precursor. Then, the FeOx nanoparticles were synthesized by heat-treatment at 300 ℃, 400 ℃, 500 ℃ and 600 ℃. After that, the physical properties of the FeOx nanoparticles were investigated in order to understand the effect of the heat-treatment temperature. The results of the X-ray diffraction (XRD) analysis showed that the diffraction peak in accordance with the <104> direction increased as the heat-treatment increased, and a diffraction peak indicating the α-Fe2O3 crystal structure was detected at heat-treatment temperatures above 500 ℃. The BET specific surface area analysis revealed that the specific surface area decreased as the heat-treatment temperature increased to above 400 ℃. Observation with a high resolution transmission electron microscope (HRTEM) showed that rod-shaped nanoparticles were formed, and the size of the nanoparticles showed a tendency to increase as the heat-treatment temperature increased.

Production of Fine Cobalt Metal Powders from Stellite Scrap (Stellite 스크랩으로 부터 Co 미분말의 제조)

  • 박문경;신동성
    • Resources Recycling
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    • v.3 no.1
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    • pp.9-16
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    • 1994
  • Fine cobalt metal powders was produced from domestic Stellite scrap by decomposing it with molten sodium hydroxide. Complete decomposition of the scrap could be obtained with the weigth ratio of sodium hydroxide to Stellite being about 2 at the temperature ranges of $750~800^{\circ}C$ for an hour. The cobalt-bearing compound was identified as $Co_2O_3{\dot}H_2O$ by X-ray analysis and D.T.-T.G.a.. The compound was then digested in HCI to form cobalt chloride, and after iron removal by adjusting the pH of the solution, cobaltous or cobaltic hydroxide was precipitated at the pH of about 13 or 4, respectively. The precipitates were reduced by hydrogen in the temperatures of $400~500^{\circ}C$ to fine cobalt powders of high purity with the size of 1.0 to $1.5\mu\textrm{m}$. The recovery of cobalt from Stellite scrap was about 75~86% by weight.

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A Test of Individual Firm's Collusive Behavior: The Case of Purchase Price Fixing in the Iron Scrap Market (담합 사례 연구: 철스크랩 구매가격 담합 사건에서 개별 기업의 담합 실행 여부에 대한 실증적 검증)

  • Yangsoo Jin
    • Journal of Industrial Convergence
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    • v.22 no.5
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    • pp.11-21
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    • 2024
  • In the steel industry, there is a perception that "collusion has become a long-standing practice" and it is expected that the authorities' legal response to collusion will be strengthened in the future. This necessarily requires improving the accuracy of the legal response, the most important of which is to accurately identify whether the allegedly colluding firms actually did collude. This study focuses on the recent iron scrap price-fixing case and examines whether a single accused firm actually engaged in price-fixing in a situation where there is a mix of firms that acted independently of the collusion and firms that actually engaged in price-fixing. The results of the analysis allow us to infer that the accused steelmaker did not actually collude, which is consistent with the authorities' final judgment against the steelmaker. In the real world, some collusions are carried out by only a subset of firms in a market, and in these cases, there are often disputed firms as to whether or not they carried out the collusion. This study can serve as an analytic guide for industries, including the steel industry, to verify the behavior of individual firms, especially those whose collusive practices are disputed.

Effects of Ti on Mechanical Property and Damping Capacity in Hot-rolled Fe-17%Mn Alloy (열간압연한 Fe-17wt%Mn 합금의 기계적 성질과 진동감쇠능에 미치는 티타늄 첨가의 영향)

  • Kim, Tai-Hoon;Kim, Jung-Chul
    • Journal of Korea Foundry Society
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    • v.29 no.2
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    • pp.59-63
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    • 2009
  • Effects of Ti on damping capacity and mechanical properties are investigated in hot rolled Fe-17%Mn alloy. The existing damping alloy with Fe-Mn binary system was limited the use by high production cost, however in case of using scrap iron instead of pure iron although the content of carbon is higher it is possible to be applied wider field especially construction items because the production cost is lower. However, the excellent specific damping capacity is dropped due to the high content of carbon, we developed advanced type of damping alloy included Ti. TiC is formed with added Ti and it holds the specific damping capacity similar to existing damping alloy. The effect of Ti on damping capacity is found to be beneficial in carbon-containing alloy, which is attributed to the depletion of carbon solute due to the formation of TiC.

Process Technology of the Direct Separation and Recovery of Iron and Zinc Metals Contained in High Temperature EAF Exhaust Gas

  • Furukawa, Takeshi;Sasamoto, Hirohiko;Isozaki, Shinichi;Tanno, Fumio
    • Proceedings of the IEEK Conference
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    • 2001.10a
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    • pp.393-397
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    • 2001
  • The innovatory process, that is the direct separation and recovery of the iron and zinc metals contained in the high temperature exhaust gas generated from the electric arc furnace fer the inn scrap melting and/or the dust treatment, has been proposed. This proposed process consists of the moving coke bed filter that is directly connected to the electric furnace, and the following heavy metal condenser. The exhaust gas passes through the filter and the condenser right after exhausting from the electric furnace. The moving coke bed filter is being controlled at about 1000℃ and collects iron and slag components contained in the high temperature exhaust gas. Heavy metals such as zinc and lead pass through the filter as vapor. Based on the thermodynamic considerations, the iron oxide and the zinc oxide are reduced in the filter. The solution loss reaction rate is comparatively low at about 1000℃ in the coke bed filter by the analysis using the mathematical simulation model. The heavy metal condenser is installed in the position after the coke bed filter, and rapidly cools the gas from about 1000℃ to 450℃ by a full of the cooling medium like the solid ceramic ball in addition to the cooling from the wall. The zinc and lead vapor condense and separate f개m the gas in a liquid state. The investigation of the characteristics of the exhaust gas of the commercial electric arc furnace, the fundamental experiments of the laboratory scale and the bench scale ensured the formation of this proposed process. A small-scale pilot plant examination is carrying out at present to confirm the formation of the process. It is certain that the dust generation of the electric arc furnace is extremely decreased, and it can save the energy consumption of usual dust treatment processes by the realization of this process.

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Electrochemical Corrosion Characteristics of the Iron-based Damping Alloy (철기제진합금의 전기화학적 부식특성)

  • Shim, Hyun Yee;Jee, Choong Soo;Lee, Jin Hyung;Lee, Kyu Hwan;Shin, Myung Chul
    • Analytical Science and Technology
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    • v.8 no.1
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    • pp.85-90
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    • 1995
  • Corrosion characteristics of 4 kinds of the Fe-Al damping alloys has been studied in the 3.5% NaCl solution and compared with a cold rolled mild steel and pure Ti, No passivation, besides Ti, was observed in the Fe-Al damping alloys and a cold rolled mild steel. Corrosion rate was decreased with lower carbon concentration. In the case of Mn addition for improving damping capacity, corrosion rate was decreased in scrap iron but was not decreased in electrolytic iron. It has been shown that corrosion rate of Fe-Al damping alloys lays between that of the pure Ti and that of a cold rolled mild steel.

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