• Title/Summary/Keyword: Iron film

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A Behavior of the Wet Etching of CoNbZr/Cu/CoNbZr Multi-Layer Films (CoNbZr/Cu/CoNbZr 다층막의 습식 식각 거동)

  • 김현식;이영생;송재성;오영두;윤재홍
    • Electrical & Electronic Materials
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    • v.10 no.7
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    • pp.645-650
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    • 1997
  • We manufactured CoNbZr/Cu/CoNbZr multi-layer films by rf magnetron sputtering methods and formed the patterns on the deposited multi-layer films. In this study, we fabricated a new etchant for forming the patterns by the wet etching with etchant and we searched for the best etching conditions and the etchant composition. Cu was etched selectively independent on the concentration of iron chloride solution, but amorphous CoNbZr thin film did not. The etchant was achieved by iron chloride solution(17.5 mol%) mixed with HF (20 mol%) during 150 sec, which etched CoNbZr/Cu/CoNbZr multi-layer films at the same time. Also, the etchant etched CoNbZr/Cu/CoNbZr multi-layer films by the three-step. It was shown that the cross-section had the isotropic structure and excellent etching characteristics with the above etchant.

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Research on Iron-coated Seeds on a Rice Seedling Raising Nursery in Machine Transplanting (벼 건묘육성을 위한 볍씨 철분코팅기술 연구)

  • Park, K.H.;Kang, Y.K.;Oh, D.G.;Kim, Y.S.;Chang, J.T.
    • Journal of Practical Agriculture & Fisheries Research
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    • v.13 no.1
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    • pp.19-26
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    • 2011
  • The machine transplanted rice has highly extended in the Republic of Korea due to a wage rise since 1976 and thus rice seedling raising nursery method has shifted from field into polyethylene film house. The rice seedling grown under a polyethylene film house was weak and tall because of limited sunlight and wind and so there was so complained among rice growing farmers in terms of missing hill and broken seedling after machine transplanting. In recent iron-coated seedling has reported on healthier and stronger than that of polyethylene film house. These seedlings were more stiff and thus more easy to handle during transplanting and less missing hills. The Iron-coated seed was proven to more stiff like seedling height, root growth and weight of shoot and root growth. This was more convenient during transfer of seedling raising box im machine transplanting. Thus, this study was carried out to grow a stiff and healthy seedling growth and development for machine transplanting. There were a normal seed germination and sprouting after iron-coated seeds treatment and this seedling was smaller and stiffer than that of untreated control. The leaf number and root growth of seedling which was iron-coated seeds would be better and total seedling fresh weight was greater than that of untreated control.

Magnetic Properties of Electrodeposited Iron and Cobalt on Porous Aluminum Oxide Layer (다공성 알루미늄 양극산화 피막에 도금된 철 및 코박트의 자기적 성질)

  • Kim, K. H.;Kang, T.;Sohn, H. J.
    • Journal of the Korean institute of surface engineering
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    • v.23 no.3
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    • pp.150-159
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    • 1990
  • The magnetic properties of electrodeposited iron and cobalt films on porous aluminum oxide film were examined. There exists perpendicular magnetic anisotropy due to the shape anisotropy. The coercivity and squareness ratio of films were strongly dependent on deposited particle diameter. The effect of packing fraction on squareness ratio was also apprecible. Unlike the iron-deposited films, the magnetic properties of cobalt films were changed by preferred orientation because of it's large crystal ansotropy constant.(about 10 times of Fe) The Fe deposited films were found to be more suitable for perpendicular magenetic recording media bacause perpendicular coercivity, squareness ratio and the ratio of perpendicular coercivity to horizontal ones of iron films are greater than those of cobalt films.

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Iron(II) Tris(3-bromo-1,10-phenanthroline) Complex: Synthesis, Crystal Structure and Electropolymerization

  • Lee, Kyeong-Jong;Yoon, Il;Lee, Shim-Sung;Lee, Bu-Yong
    • Bulletin of the Korean Chemical Society
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    • v.23 no.3
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    • pp.399-403
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    • 2002
  • The complex of iron(II) tris(3-Br-phen) (3-Br-phen; 3-bromo-1,10-phenanthroline) was prepared as a precursor of electropolymerization and the crystal structure of [Fe(3-Br-phen)3]($PF_6$)2${\cdot}$CH3CN with a distorted octahedral geometry has been investigated. The reductive electropolymerization of $>[Fe(3-Br-phen)3]^{2+}$ complex onto the surface of a glassy carbon electrode and indium tin oxide (ITO) optically transparent electrode were performed in acetonitrile at room temperature. Thin film of poly-$>[Fe(3-Br-phen)3]^{2+}$ formed was adherent, electroactive and stably deposited on a glassy carbon disk electrode. The thin metallopolymeric film formed was also confirmed by absorption spectroscopy.

A Fabrication Method of Blade Type Tip for Probe Unit Device (프르브유닛 소자용 블레이드형 팁 제조방법)

  • Lee, Keun-Woo;Lee, Jae-Hong;Kim, Chang-Kyo
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.56 no.8
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    • pp.1436-1440
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    • 2007
  • Beryllium copper has been known to be an important material for the various fields of industry because it can be used for mechanical and electrical/electronic components that are subjected to elevated temperatures (up to $400^{\circ}C$ for short times). Blade type tip for probing the cells of liquid crystal display(LCD) was fabricated using beryllium copper foil. The dry film resist was employed as a mask for patterning of the blade type tip. The beryllium copper foil was etched using hydrochloric acidic iron-chloride solution. The concentration, temperature, and composition ratio of hydrochloric acidic iron-chloride solution affect the etching characteristics of beryllium copper foil. Nickel with the thickness of $3{\mu}m$ was electroplated on the patterned copper beryllium foil for enhancing its hardness, followed by electroplating gold for increasing its electrical conductivity. Finally, the dry film resist on the bridge was removed and half of the nickel was etched to complete the blade type tip.

The Effects of Polyphosphate Corrosion Inhibitor and Lime Water to Reduce Red Water for Carbon Steel (탄소강의 녹물저감에 대한 인산염부식억제제와 석회수 효과 연구)

  • Park, Young-Bog;Kong, Sung-Ho
    • Journal of Korean Society of Water and Wastewater
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    • v.19 no.2
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    • pp.228-237
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    • 2005
  • The main purpose of this study was to investigate the red water reducing effects of phosphate based inhibitor when it was applied to water distribution system. The effects of pH, alkalinity, calcium concentration in the reduction of the red water also studied. The most finished water in Korea showed relatively high corrosiveness and was required to introduce some types of corrosion reducing methods such as addition of alkalinity. The precipitation of $CaCO_3$ by addition of $Ca(OH)_2$ formed porous film on the surface of the carbon steel pipes and was displaced easily from the surface of the pipes; on the other hand, addition of zinc phosphate (ZOP) formed reliable film on the surface and reduced iron release and color. Although the main function of ZOP was to suppress the release of Pb and Cu, it also reduced iron concentration released from water distribution pipes.

An Electrochemical and Optical Study on the Corrosion and Passivation of Metals. An Electrochemical and Optical Study on the Passivation Film of Electrolytic Iron (금속 부식과 부동화에 관한 전기화학적 및 광학적 연구. 순철의 부동화 피막에 관한 전기화학적 및 광학적 연구)

  • Park Byung So;Paik Woon-Kie;Yeo, In Hyeong
    • Journal of the Korean Chemical Society
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    • v.22 no.6
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    • pp.365-369
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    • 1978
  • Ellipsometric and reflectance measurements were made on an iron surface in a cathodically reduced state and in an anodically passivated state. From the differences in the optical parameters (${\Delta},\;{\psi}$, and reflectance) between the reduced (film-free) and passivated (film-covered) states the thickness and optical constants of the surface film were determined. In the passive state at -400 mV vs. SCE in borate-boric acid buffer solution the anodic film had a thickness of about 11${\AA}$ and optical constants of ${\tilde{n}}$= 2.8 - 0.8 i. This value indicates a substantial electronic conductivity of the anodic film.

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Diagnostic Value of the Cobalt($^{58}Co$) Excretion Test in Iron Deficiency Anemia (철결핍성빈혈(鐵缺乏性貧血)에서 Cobalt($^{58}Co$)배설율검사(排泄率檢査)의 진단적(診斷的) 가치(價値))

  • Sihn, Hyun-Chung;Hong, Kee-Suck;Cho, Kyung-Sam;Song, In-Kyung;Koh, Chang-Soon;Lee, Mun-Ho
    • The Korean Journal of Nuclear Medicine
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    • v.10 no.1
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    • pp.21-34
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    • 1976
  • The diagnosis of iron deficiency rests upon the correct evaluation of body iron stores. Morphological interpretation of blood film and the red cell indices are not reliable and often absent in mild iron deficiency. Serum iron levels and iron-binding capacity are more sensitive indices of iron deficiency, but they are often normal in iron depletion and mild iron deficiency anemia. They are also subject to many variables which may introduce substantial errors and influenced by many pathologic and physiologic states. Examination of the bone marrow aspirate for stainable iron has been regarded as one of the most sensitive and reliable diagnostic method for detecting iron deficiency, but this also has limitations. Thus, there is still need for a more practical, but sensitive and reliable substitute as a screening test of iron deficiency. Pollack et al. (1965) observed that the intestinal absorption of cobalt was raised in iron-deficient rats and Valberg et al. (1969) found that cobalt absorption was elevated in patients with iron deficiency. A direct correlation was demonstrated between the amounts of radioiron and radiocobalt absorbed. Unlike iron, excess cobalt was excreted by the kidney, the percentage of radioactivity in the urine being directly related to the percentage absorbed from the gastrointestinal tract. Recently a test based on the urinary excretion of an oral dose of $^{57}Co$ has been proposed as a method for detecting iron deficiency. To assess the diagnostic value of urinary cobalt excretion test cobaltous chloride labelled with $1{\mu}Ci\;of\;^{58}Co$ was given by mouth and the percentage of the test dose excreted in the urine was measured by a gamma counter. The mean 24 hour urinary cobalt excretion in control subjects with normal iron stores was 6.1% ($1.9{\sim}15.2%$). Cobalt excretion was markedly increased in patients with iron deficiency and excreted more than 29% of the dose. In contrast, patients with anemia due to causes other than iron deficiency excreted less than 27%. Hence, 24 hour urinary cobalt excretion of 27% or less in a patient with anemia suggets that the primary cause of the anemia is not iron deficiency. A value greater than 27% in an anemic subject suggests that the anemia is caused by iron deficiency. The cobalt excretion test is a simple, sensitive and accurate method for the assessment of body iron stores. It may be particularly valuable in the epidemiological studies of iron deficiency and repeated evaluations of the body iron stores.

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